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Volume 20 Issue 5
May  2013
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Mohammad Sadegh Shakeri, Effect of Y2O3 on the crystallization kinetics of TiO2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics, Int. J. Miner. Metall. Mater., 20(2013), No. 5, pp. 450-455. https://doi.org/10.1007/s12613-013-0750-3
Cite this article as:
Mohammad Sadegh Shakeri, Effect of Y2O3 on the crystallization kinetics of TiO2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics, Int. J. Miner. Metall. Mater., 20(2013), No. 5, pp. 450-455. https://doi.org/10.1007/s12613-013-0750-3
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Effect of Y2O3 on the crystallization kinetics of TiO2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics

  • 通讯作者:

    Mohammad Sadegh Shakeri    E-mail: ms.shakeri@merc.ac.ir

  • Crystallization kinetics of metastable β-quartz solid solution as a desirable phase for the production of transparent lithium aluminosilicate (LAS) glass ceramics was investigated in the presence of Y2O3. Accordingly, differential thermal analysis scans were performed thoroughly to study the mechanism of crystallization kinetics. The aim of this investigation is to discover the complicated mechanism of crystallization process in the presence of co-additives and accordingly find a way for increasing the transparency of glass ceramics. It is shown that the bulk (3D) growth is intensively increased by the enhancement of Y2O3. Then again, reducing nucleation and increasing growth mechanisms were recognized for the LAS system in the presence of Y2O3. Results of the investigation illustrate that when co-additives are added to glasses, it is necessary to nucleate the optical component separately before the growth process.
  • Effect of Y2O3 on the crystallization kinetics of TiO2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics

    + Author Affiliations
    • Crystallization kinetics of metastable β-quartz solid solution as a desirable phase for the production of transparent lithium aluminosilicate (LAS) glass ceramics was investigated in the presence of Y2O3. Accordingly, differential thermal analysis scans were performed thoroughly to study the mechanism of crystallization kinetics. The aim of this investigation is to discover the complicated mechanism of crystallization process in the presence of co-additives and accordingly find a way for increasing the transparency of glass ceramics. It is shown that the bulk (3D) growth is intensively increased by the enhancement of Y2O3. Then again, reducing nucleation and increasing growth mechanisms were recognized for the LAS system in the presence of Y2O3. Results of the investigation illustrate that when co-additives are added to glasses, it is necessary to nucleate the optical component separately before the growth process.
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