留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 21 Issue 4
Apr.  2014
数据统计

分享

计量
  • 文章访问数:  235
  • HTML全文浏览量:  61
  • PDF下载量:  14
  • 被引次数: 0
Da-peng Li, Lei Zhang, Jian-wei Yang, Min-xu Lu, Jin-hui Ding, and Ming-liang Liu, Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2, Int. J. Miner. Metall. Mater., 21(2014), No. 4, pp. 388-394. https://doi.org/10.1007/s12613-014-0920-y
Cite this article as:
Da-peng Li, Lei Zhang, Jian-wei Yang, Min-xu Lu, Jin-hui Ding, and Ming-liang Liu, Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2, Int. J. Miner. Metall. Mater., 21(2014), No. 4, pp. 388-394. https://doi.org/10.1007/s12613-014-0920-y
引用本文 PDF XML SpringerLink

Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2

  • 通讯作者:

    Lei Zhang    E-mail: zhanglei@ustb.edu.cn

  • The effect of H2S concentration on H2S/CO2 corrosion of API-X60 steel was studied by scanning electron microscopy, a weight-loss method, potentiodynamic polarization tests, and the electrochemical impedance spectroscopy technique. It is found that the corrosion process of the steel in an environment where H2S and CO2 coexist at different H2S concentrations is related to the morphological structure and stability of the corrosion product film. With the addition of a small amount of H2S, the size of the anode reaction region is decreased due to constant adsorption and separation of more FeS sediment or more FeHS+ ions on the surface of the steel. Meanwhile, the double-layer capacitance is diminished with increasing anion adsorption capacity. Therefore, the corrosion process is inhibited. The general corrosion rate of the steel rapidly decreases after the addition of a small amount of H2S under the coexistence of H2S and CO2. With a further increase in H2S concentration, certain parts of the corrosion product film become loose and even fall off. Thus, the protection provided by the corrosion product film worsens, and the corrosion rate tends to increase.
  • Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2

    + Author Affiliations
    • The effect of H2S concentration on H2S/CO2 corrosion of API-X60 steel was studied by scanning electron microscopy, a weight-loss method, potentiodynamic polarization tests, and the electrochemical impedance spectroscopy technique. It is found that the corrosion process of the steel in an environment where H2S and CO2 coexist at different H2S concentrations is related to the morphological structure and stability of the corrosion product film. With the addition of a small amount of H2S, the size of the anode reaction region is decreased due to constant adsorption and separation of more FeS sediment or more FeHS+ ions on the surface of the steel. Meanwhile, the double-layer capacitance is diminished with increasing anion adsorption capacity. Therefore, the corrosion process is inhibited. The general corrosion rate of the steel rapidly decreases after the addition of a small amount of H2S under the coexistence of H2S and CO2. With a further increase in H2S concentration, certain parts of the corrosion product film become loose and even fall off. Thus, the protection provided by the corrosion product film worsens, and the corrosion rate tends to increase.
    • loading

    Catalog


    • /

      返回文章
      返回