Qing-chun Yu, Yong Deng, Fei Wang, Yue-bin Feng, Xiu-min Chen, Bin Yang, and Da-chun Liu, Preparation of activated ceria and its desulfurization performance, Int. J. Miner. Metall. Mater., 22(2015), No. 9, pp. 992-997. https://doi.org/10.1007/s12613-015-1160-5
Cite this article as:
Qing-chun Yu, Yong Deng, Fei Wang, Yue-bin Feng, Xiu-min Chen, Bin Yang, and Da-chun Liu, Preparation of activated ceria and its desulfurization performance, Int. J. Miner. Metall. Mater., 22(2015), No. 9, pp. 992-997. https://doi.org/10.1007/s12613-015-1160-5
Qing-chun Yu, Yong Deng, Fei Wang, Yue-bin Feng, Xiu-min Chen, Bin Yang, and Da-chun Liu, Preparation of activated ceria and its desulfurization performance, Int. J. Miner. Metall. Mater., 22(2015), No. 9, pp. 992-997. https://doi.org/10.1007/s12613-015-1160-5
Citation:
Qing-chun Yu, Yong Deng, Fei Wang, Yue-bin Feng, Xiu-min Chen, Bin Yang, and Da-chun Liu, Preparation of activated ceria and its desulfurization performance, Int. J. Miner. Metall. Mater., 22(2015), No. 9, pp. 992-997. https://doi.org/10.1007/s12613-015-1160-5
National Engineering Laboratory for Vacuum Metallurgy, Key Laboratory of Vacuum Metallurgy for Non-ferrous Metal of Yunnan Province, State Key Laboratory of Complex Non-ferrous Metal Resources Clear Utilization, Kunming, 650093, China
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, China
Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, China
Activated ceria (CeO2/γ-Al2O3) prepared by impregnation was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and hydrogen temperature-programmed reduction (TPR). The desulfurization of the activated ceria was investigated by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TG). The results showed that ceria could be highly dispersed or crystallized on the surface of γ-alumina. The reduction temperatures of 0.1CeO2/γ-Al2O3, 0.45CeO2/γ-Al2O3, and CeO2 ranged from 250℃ to 470℃, 330℃ to 550℃, and 350℃ to 550℃, respectively. The reduction peak temperature of 0.45CeO2/γ-Al2O3 was higher than that of 0.1CeO2/γ-Al2O3, which was consistent with the reduction temperature of CeO2. O2 participated in the reaction between ceria and sulfur dioxide. The desulfurization product was cerium(Ⅲ) sulfate. The intensity of the hydroxyl band decreased with the formation of sulfate species.
National Engineering Laboratory for Vacuum Metallurgy, Key Laboratory of Vacuum Metallurgy for Non-ferrous Metal of Yunnan Province, State Key Laboratory of Complex Non-ferrous Metal Resources Clear Utilization, Kunming, 650093, China
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, China
Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, China
Activated ceria (CeO2/γ-Al2O3) prepared by impregnation was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and hydrogen temperature-programmed reduction (TPR). The desulfurization of the activated ceria was investigated by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TG). The results showed that ceria could be highly dispersed or crystallized on the surface of γ-alumina. The reduction temperatures of 0.1CeO2/γ-Al2O3, 0.45CeO2/γ-Al2O3, and CeO2 ranged from 250℃ to 470℃, 330℃ to 550℃, and 350℃ to 550℃, respectively. The reduction peak temperature of 0.45CeO2/γ-Al2O3 was higher than that of 0.1CeO2/γ-Al2O3, which was consistent with the reduction temperature of CeO2. O2 participated in the reaction between ceria and sulfur dioxide. The desulfurization product was cerium(Ⅲ) sulfate. The intensity of the hydroxyl band decreased with the formation of sulfate species.
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