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Volume 22 Issue 10
Oct.  2015
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Fei Zhao, Han-dong Jiao,  and Shi-qiang Zhao, Wire-like nano-polyaniline deposited electrochemically in a reverse micelle electrolyte as a pH sensor, Int. J. Miner. Metall. Mater., 22(2015), No. 10, pp. 1115-1119. https://doi.org/10.1007/s12613-015-1175-y
Cite this article as:
Fei Zhao, Han-dong Jiao,  and Shi-qiang Zhao, Wire-like nano-polyaniline deposited electrochemically in a reverse micelle electrolyte as a pH sensor, Int. J. Miner. Metall. Mater., 22(2015), No. 10, pp. 1115-1119. https://doi.org/10.1007/s12613-015-1175-y
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Wire-like nano-polyaniline deposited electrochemically in a reverse micelle electrolyte as a pH sensor

  • 通讯作者:

    Fei Zhao    E-mail: zhaofei556688@163.com

  • Wire-like polyaniline (PANI) films were successfully electrodeposited onto an indium tin oxide (ITO) substrate using a pulse galvanostatic method (PGM) in a reverse micelle electrolyte. The as-prepared PANI films were electrochemically analyzed by cyclic voltammetry and electrochemical impedance spectroscopy in 1 mol·L-1 HClO4 solution. It is found that the as-prepared PANI films are highly porous, exhibit the diameters of approximately 100 nm and the lengths exceeding 3 μm, and have favorable electrochemical activities. Furthermore, the as-prepared wire-like PANI films show a good linear relationship of the potentiometric response curve over the pH value range of 3–10 with a slope of 74.13 mV·pH-1 in 0.5 mol·L-1 K2HPO4 basal solutions. The results demonstrate that the prepared wire-like PANI films are promising pH sensors.
  • Wire-like nano-polyaniline deposited electrochemically in a reverse micelle electrolyte as a pH sensor

    + Author Affiliations
    • Wire-like polyaniline (PANI) films were successfully electrodeposited onto an indium tin oxide (ITO) substrate using a pulse galvanostatic method (PGM) in a reverse micelle electrolyte. The as-prepared PANI films were electrochemically analyzed by cyclic voltammetry and electrochemical impedance spectroscopy in 1 mol·L-1 HClO4 solution. It is found that the as-prepared PANI films are highly porous, exhibit the diameters of approximately 100 nm and the lengths exceeding 3 μm, and have favorable electrochemical activities. Furthermore, the as-prepared wire-like PANI films show a good linear relationship of the potentiometric response curve over the pH value range of 3–10 with a slope of 74.13 mV·pH-1 in 0.5 mol·L-1 K2HPO4 basal solutions. The results demonstrate that the prepared wire-like PANI films are promising pH sensors.
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