留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 24 Issue 1
Jan.  2017
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  587
  • HTML全文浏览量:  99
  • PDF下载量:  23
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(1): 64-74
Jin-jie Shiand Jing Ming, Influence of mill scale and rust layer on the corrosion resistance of low-alloy steel in simulated concrete pore solution, Int. J. Miner. Metall. Mater., 24(2017), No. 1, pp. 64-74. https://doi.org/10.1007/s12613-017-1379-4
Cite this article as:
Jin-jie Shiand Jing Ming, Influence of mill scale and rust layer on the corrosion resistance of low-alloy steel in simulated concrete pore solution, Int. J. Miner. Metall. Mater., 24(2017), No. 1, pp. 64-74. https://doi.org/10.1007/s12613-017-1379-4
shu
引用本文 PDF XML SpringerLink
研究论文

Influence of mill scale and rust layer on the corrosion resistance of low-alloy steel in simulated concrete pore solution

  • Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

  • 通讯作者:

    Jin-jie Shi    E-mail: jinjies@126.com

  • Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influence of mill scale and rust layer on the passivation capability and chloride-induced corrosion behaviors of conventional low-carbon (LC) steel and low-alloy (LA) steel in simulated concrete pore solution. The results show that mill scale exerts different influences on the corrosion resistance of both steels at various electrochemical stages. We propose that the high long-term corrosion resistance of LA steel is mainly achieved through the synergistic effect of a gradually formed compact, adherent and well-distributed Cr-enriched inner rust layer and the physical barrier protection effect of mill scale.
    • Research Article

    Influence of mill scale and rust layer on the corrosion resistance of low-alloy steel in simulated concrete pore solution

    + Author Affiliations
      Abstract
    • Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influence of mill scale and rust layer on the passivation capability and chloride-induced corrosion behaviors of conventional low-carbon (LC) steel and low-alloy (LA) steel in simulated concrete pore solution. The results show that mill scale exerts different influences on the corrosion resistance of both steels at various electrochemical stages. We propose that the high long-term corrosion resistance of LA steel is mainly achieved through the synergistic effect of a gradually formed compact, adherent and well-distributed Cr-enriched inner rust layer and the physical barrier protection effect of mill scale.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(34)
    • [1]
      R. Vera, M. Villarroel, A. M. Carvajal, E. Vera, and C. Ortiz, Corrosion products of reinforcement in concrete in marine and industrial environments, Mater. Chem. Phys., 114(2009), No. 1, p. 467.
      [2]
      S. A. Alghamdi and S. Ahmad, Service life prediction of RC structures based on correlation between electrochemical and gravimetric reinforcement corrosion rates, Cem. Concr. Compos., 47(2014), p. 64.
      [3]
      F. Presuel-Moreno, J. R. Scully, and S. R. Sharp, Literature review of commercially available alloys that have potential as low-cost, corrosion-resistant concrete reinforcement, Corrosion, 66(2010), No. 8, p. 086001.
      [4]
      J. Y. Zhong, M. Sun, D. B. Liu, X. G. Li, and T. Q. Liu, Effects of chromium on the corrosion and electrochemical behaviors of ultra high strength steels, Int. J. Miner. Metall. Mater., 17(2010), No. 3, p. 282.
      [5]
      Q. H. Zhao, W. Liu, J. W. Yang, Y. C. Zhu, B. L. Zhang, and M. X. Lu, Corrosion behavior of low alloy steels in a wet-dry acid humid environment, Int. J. Miner. Metall. Mater., 23(2016), No. 9, p. 1076.
      [6]
      S. T. Wang, S. W. Yang, K. W. Gao, and X. L. He, Corrosion behavior and corrosion products of a low-alloy weathering steel in Qingdao and Wanning, Int. J. Miner. Metall. Mater., 16(2009), No. 1, p. 58.
      [7]
      S. H. Tae and T. Ujiro, Corrosion resistance of Cr-bearing rebar in simulated concrete pore solutions, ISIJ Int., 47(2007), No. 9, p. 1324
      [8]
      J. K. Singh and D. D. N. Singh, The nature of rusts and corrosion characteristics of low alloy and plain carbon steels in three kinds of concrete pore solution with salinity and different pH, Corros. Sci., 56(2012), p. 129.
      [9]
      J. J. Shi, W. Sun, J. Y. Jiang, and Y. M. Zhang, Influence of chloride concentration and pre-passivation on the pitting corrosion resistance of low-alloy reinforcing steel in simulated concrete pore solution, Constr. Build. Mater., 111(2016), No. 5, p. 805.
      [10]
      P. Ghods, O. B. Isgor, G. A. McRae, and G. P. Gu, Electrochemical investigation of chloride-induced depassivation of black steel rebar under simulated service conditions, Corros. Sci., 52(2010), No. 5, p. 1649.
      [11]
      L. T. Mammoliti, L. C. Brown, C. M. Hansson, and B. B. Hope, The influence of surface finish of reinforcing steel and pH of the test solution on the chloride threshold concentration for corrosion initiation in synthetic pore solutions, Cem. Concr. Res., 26(1996), No. 4, p. 545.
      [12]
      M. Kouřil, P. Novák, and M. Bojko, Threshold chloride concentration for stainless steels activation in concrete pore solutions, Cem. Concr. Res., 40(2010), No. 3, p. 431.
      [13]
      E. Mahallati and M. Saremi, An assessment on the mill scale effects on the electrochemical characteristics of steel bars in concrete under DC-polarization, Cem. Concr. Res., 36(2006), No. 7, p. 1324.
      [14]
      L. Li and A. A. Sagüés, Chloride corrosion threshold of reinforcing steel in alkaline solutions:open-circuit immersion tests, Corrosion, 57(2001), No. 1, p. 19.
      [15]
      T. U. Mohammed and H. Hamada, Corrosion of steel bars in concrete with various steel surface conditions, ACI Mater. J., 103(2006), No. 4, p. 233.
      [16]
      P. Ghods, O. B. Isgor, G. A. McRae, J. Li, and G. P. Gu, Microscopic investigation of mill scale and its proposed effect on the variability of chloride-induced depassivation of carbon steel rebar, Corros. Sci., 53(2011), No. 3, p. 946.
      [17]
      R. G. Pillai and D. Trejo, Surface condition effects on critical chloride threshold of steel reinforcement, ACI Mater. J., 102(2005), No. 2, p. 103.
      [18]
      A. Poursaee and C. Hansson, Reinforcing steel passivation in mortar and pore solution, Cem. Concr. Res., 37(2007), No. 7, p. 1127.
      [19]
      M. Manera,Ø. Vennesland, and L. Bertolini, Chloride threshold for rebar corrosion in concrete with addition of silica fume, Corros. Sci., 50(2008), No. 2, p. 554.
      [20]
      A. Demoulin, C. Trigance, D. Neff, E. Foy, P. Dillmann, and V. L'Hostis, The evolution of the corrosion of iron in hydraulic binders analysed from 46-and 260-year-old buildings, Corros. Sci., 52(2010), No. 10, p. 3168.
      [21]
      S. J. Jaffer and C. M. Hansson, Chloride-induced corrosion products of steel in cracked-concrete subjected to different loading conditions, Cem. Concr. Res., 39(2009), No. 2, p. 116.
      [22]
      Y. X. Zhao, Y. Y. Wu, and W. L. Jin, Distribution of millscale on corroded steel bars and penetration of steel corrosion products in concrete, Corros. Sci., 66(2013), p. 160.
      [23]
      M. A. Islam, B. P. Bergsma, and C. M. Hansson, Chloride-induced corrosion behavior of stainless steel and carbon steel reinforcing bars in sound and cracked concrete, Corrosion, 69(2013), No. 3, p. 303.
      [24]
      F. Zhang, J. S. Pan, and C. J. Lin, Localized corrosion behaviour of reinforcement steel in simulated concrete pore solution, Corros. Sci., 51(2009), No. 9, p. 2130.
      [25]
      L. Li and A. A. Sagüés, Chloride corrosion threshold of reinforcing steel in alkaline solutions:effect of specimen size, Corrosion, 60(2004), No. 2, p. 195.
      [26]
      R. D. Moser, P. M. Singh, L. F. Kahn, and K. E. Kurtis, Chloride-induced corrosion resistance of high-strength stainless steels in simulated alkaline and carbonated concrete pore solutions, Corros. Sci., 57(2012), No. 4, p. 241.
      [27]
      L. Freire, M. J. Carmezim, M. G. S. Ferreira, and M. F. Montemor, The electrochemical behaviour of stainless steel AISI 304 in alkaline solutions with different pH in the presence of chlorides, Electrochim. Acta, 56(2011), No. 14, p. 5280.
      [28]
      H. E. Jamil, A. Shriri, R. Boulif, M. F. Montemor, and M. G. S. Ferreira, Corrosion behaviour of reinforcing steel exposed to an amino alcohol based corrosion inhibitor, Cem. Concr. Compos., 27(2005), No. 6, p. 671.
      [29]
      D. A. Koleva, J. H. W. De Wit, K. Van Breugel, Z. F. Lodhi, and E. Van Westing, Investigation of corrosion and cathodic protection in reinforced concrete:I. Application of electrochemical techniques, J. Electrochem. Soc., 154(2007), No. 4, p. P52.
      [30]
      M. Saremi and E. Mahallati, A study on chloride-induced depassivation of mild steel in simulated concrete pore solution, Cem. Concr. Res., 32(2002), No. 12, p. 1915.
      [31]
      Q. C. Zhang, J. S. Wu, J. J. Wang, W. L. Zheng, J. G. Chen, and A. B. Li, Corrosion behavior of weathering steel in marine atmosphere, Mater. Chem. Phys., 77(2003), No. 2, p. 603.
      [32]
      S. T. Wang, S. W. Yang, K. W. Gao, X. A. Shen, and X. L. He, Corrosion behavior and variation of apparent mechanical property of a novel low carbon bainitic steel in environment containing chloride ions, Acta Metall. Sin., 44(2008), No. 9, p. 1116.
      [33]
      M. C. García-Alonso, J. A. González, J. Miranda, M. L. Escudero, M. J. Correia, M. Salta, and A. Bennani, Corrosion behaviour of innovative stainless steels in mortar, Cem. Concr. Res., 37(2007), No. 11, p. 1562.
      [34]
      Y. Qian, C. Ma, D. Niu, J. Xu, and M. Li, Influence of alloyed chromium on the atmospheric corrosion resistance of weathering steels, Corros. Sci., 74(2013), No. 9, p. 424.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计