留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 24 Issue 2
Feb.  2017
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  633
  • HTML全文浏览量:  107
  • PDF下载量:  9
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(2): 156-163
Jing-peng Wang, Yi-min Zhang, Jing Huang, and Tao Liu, Synergistic effect of microwave irradiation and CaF2 on vanadium leaching, Int. J. Miner. Metall. Mater., 24(2017), No. 2, pp. 156-163. https://doi.org/10.1007/s12613-017-1390-9
Cite this article as:
Jing-peng Wang, Yi-min Zhang, Jing Huang, and Tao Liu, Synergistic effect of microwave irradiation and CaF2 on vanadium leaching, Int. J. Miner. Metall. Mater., 24(2017), No. 2, pp. 156-163. https://doi.org/10.1007/s12613-017-1390-9
shu
引用本文 PDF XML SpringerLink
研究论文

Synergistic effect of microwave irradiation and CaF2 on vanadium leaching

  • School of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China

  • Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource, Wuhan 430081, China

  • Hubei Provincial Collaborative Innovation Center for High Efficient Utilization of Vanadium Resource, Wuhan 430081, China

  • 通讯作者:

    Yi-min Zhang    E-mail: zym126135@126.com

  • The effect and mechanism of microwave irradiation on vanadium leaching were studied via a comparison between microwave heating and conventional heating. The results show a synergistic effect of microwave irradiation and calcium fluoride (CaF2) on the vanadium leaching efficiency. It is confirmed that the vanadium leaching process can be improved by microwave irradiation when CaF2 is present. The leaching rate of vanadium under microwave irradiation is increased by 8%-15% when 5wt% CaF2 is added; by contrast, in the absence of CaF2, the leaching rate is almost unaffected compared to that by conventional heating. Morphological analysis reveals that the particles are gradually eroded by acid under microwave irradiation, whereas some of the fine particles in samples subjected to conventional heating are tightly covered by a flocculent silicate product. Moreover, a large amount of Al and V and a small amount of Si are dissolved from samples under microwave heating, as revealed by the elemental analysis of leachates. Fourier transform infrared spectroscopic analysis also indicates a higher mass transfer coefficient in the diffusion layer of the raw material by microwave irradiation. When CaF2 is present, the reaction energy barrier is lowered and the leaching process is controlled by the tightly covered product layer, resulting in a prominent effect of microwave irradiation.
    • Research Article

    Synergistic effect of microwave irradiation and CaF2 on vanadium leaching

    + Author Affiliations
      Abstract
    • The effect and mechanism of microwave irradiation on vanadium leaching were studied via a comparison between microwave heating and conventional heating. The results show a synergistic effect of microwave irradiation and calcium fluoride (CaF2) on the vanadium leaching efficiency. It is confirmed that the vanadium leaching process can be improved by microwave irradiation when CaF2 is present. The leaching rate of vanadium under microwave irradiation is increased by 8%-15% when 5wt% CaF2 is added; by contrast, in the absence of CaF2, the leaching rate is almost unaffected compared to that by conventional heating. Morphological analysis reveals that the particles are gradually eroded by acid under microwave irradiation, whereas some of the fine particles in samples subjected to conventional heating are tightly covered by a flocculent silicate product. Moreover, a large amount of Al and V and a small amount of Si are dissolved from samples under microwave heating, as revealed by the elemental analysis of leachates. Fourier transform infrared spectroscopic analysis also indicates a higher mass transfer coefficient in the diffusion layer of the raw material by microwave irradiation. When CaF2 is present, the reaction energy barrier is lowered and the leaching process is controlled by the tightly covered product layer, resulting in a prominent effect of microwave irradiation.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(31)
    • [1]
      Y.M. Zhang, S.X. Bao, T. Liu, T.J. Chen, and J. Huang, The technology of extracting vanadium from stone coal in China:history, current status and future prospects, Hydrometallurgy, 109(2011), No. 1-2, p. 116.
      [2]
      G.Q. Zhang, T.A. Zhang, G.Z. Lü, Y. Zhang, Y. Liu, and Z.L. Liu, Extraction of vanadium from vanadium slag by high pressure oxidative acid leaching, Int. J. Miner. Metall. Mater., 22(2015), No. 1, p. 21.
      [3]
      Y.Z. Yuan, Y.M. Zhang, T. Liu, and T.J. Chen, Comparison of the mechanisms of microwave roasting and conventional roasting and of their effects on vanadium extraction from stone coal, Int. J. Miner. Metall. Mater., 22(2015), No. 5, p. 476.
      [4]
      X.J. Zhai, Y. Fu, X. Zhang, L.Z. Ma, and F. Xie, Intensification of sulphation and pressure acid leaching of nickel laterite by microwave radiation, Hydrometallurgy, 99(2009), No. 3-4, p. 189.
      [5]
      Y.J. Hu, Y.M. Zhang, S.X. Bao, and T. Liu, Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal, Int. J. Miner. Metall. Mater., 19(2012), No. 10, p. 893.
      [6]
      X.S. Li and B. Xie, Extraction of vanadium from high calcium vanadium slag using direct roasting and soda leaching, Int. J. Miner. Metall. Mater., 19(2012), No. 7, p. 595.
      [7]
      X.B. Zhu, Y.M. Zhang, J. Huang, T. Liu, and Y. Wang, A kinetics study of multi-stage counter-current circulation acid leaching of vanadium from stone coal, Int. J. Miner. Process., 114-117(2012), p. 1.
      [8]
      H.Y. Li, K. Wang, W.H. Hua, Z. Yang, W. Zhou, and B. Xie, Selective leaching of vanadium in calcification-roasted vanadium slag by ammonium carbonate, Hydrometallurgy, 160(2016), p. 18.
      [9]
      F. Wang, Y.M. Zhang, J. Huang, T. Liu, Y. Wang, X. Yang, and J. Zhao, Mechanisms of aid-leaching reagent calcium fluoride in the extracting vanadium processes from stone coal, Rare Met., 32(2013), No. 1, p. 57.
      [10]
      F. Wang, Y.M. Zhang, T. Liu, J. Huang, J. Zhao, G.B. Zhang, and J. Liu, Comparison of direct acid leaching process and blank roasting acid leaching process in extracting vanadium from stone coal, Int. J. Miner. Process., 128(2014), p. 40.
      [11]
      N.N. Xue, Y.M. Zhang, T. Liu, and J. Huang, Study of the dissolution behavior of muscovite in stone coal by oxygen pressure acid leaching, Metall. Mater. Trans. B, 47(2016), No. 1, p. 694.
      [12]
      B. Terry, The acid decomposition of silicate minerals:Part I. Reactivities and modes of dissolution of silicates, Hydrometallurgy, 10(1983), No. 2, p. 135.
      [13]
      G.Q. Zhang, T.A. Zhang, G.Z. Lü, Y. Zhang, Y. Liu, and W.G. Zhang, Effects of microwave roasting on the kinetics of extracting vanadium from vanadium slag, JOM, 68(2016), No. 2, p. 577.
      [14]
      M. Al-Harahsheh and S. Kingman, The influence of microwaves on the leaching of sphalerite in ferric chloride, Chem. Eng. Process., 46(2007), No. 10, p. 883.
      [15]
      S.U. Bayca, Microwave radiation leaching of colemanite in sulfuric acid solutions, Sep. Purif. Technol., 105(2013), p. 24.
      [16]
      S. Aydoğan, M. Erdemoğlu, G. Uçar, and A. Aras, Kinetics of galena dissolution in nitric acid solutions with hydrogen peroxide, Hydrometallurgy, 88(2007), No. 1-4, p. 52.
      [17]
      N.N. Wang and P. Wang, Study and application status of microwave in organic wastewater treatment:a review, Chem. Eng. J., 283(2016), No. 1, p. 193.
      [18]
      X.M. Shen, L.S. Li, Z.J. Wu, H.H. Lü, and J. Lü, Ultrasonic-assisted acid leaching of indium from blast furnace sludge, Metall. Mater. Trans. B, 44(2013), No. 6, p. 1324.
      [19]
      G. Chen, J. Chen, Z.Y. Zhang, S.H. Guo, Z.B. Zhang, and J.H. Peng, C. Srinivasakannan, X.Q. Li, Y.K. Zhuang, and Z.M. Xu, Leaching of refractory gold ores by microwave irradiation:comparison with conventional leaching, Metallurgist, 57(2013), No. 7, p. 647.
      [20]
      I.S.S. Pinto and H.M.V.M. Soares, Microwave-assisted selective leaching of nickel from spent hydrodesulphurization catalyst:a comparative study between sulphuric and organic acids, Hydrometallurgy, 140(2013), p. 20.
      [21]
      I.S.S. Pinto and H.M.V.M. Soares, Selective leaching of molybdenum from spent hydrodesulphurization catalysts using ultrasound and microwave methods, Hydrometallurgy, 129-130(2012), p. 19.
      [22]
      L.Y. Zhang, J.M. Mo, X.H. Li, L.P. Pan, X.Y. Liang, and G.T. Wei, A kinetics study of indium leaching from indium-bearing zinc ferrite under microwave heating, Metall. Mater. Trans. B, 44(2013), No. 6, p. 1329.
      [23]
      Z.Y. Ma, H.Y. Yang, S.T. Huang, Y. Lü, and L. Xiong, Ultra fast microwave-assisted leaching for the recovery of copper and tellurium from copper anode slime, Int. J. Miner. Metall. Mater., 22(2015), No. 6, p. 582.
      [24]
      J. Zhao, Y.M. Zhang, J. Huang, T. Liu, F. Wang, Y. Wang, and J. Liu, Study on the impact of F-contained leaching agent on acid leaching of vanadium from stone coal, Met Mine, 2013, No. 1, p. 90.
      [25]
      L. Wen, W.X. Liang, Z.G. Zhang, and J.C. Huang, The Infrared Spectroscopy of Minerals, Chongqing University Press, Chongqing, 1989, p. 89.
      [26]
      D. Kaufhold, M. Hein, R. Dohrmann, and K. Ufer, Quantification of the mineralogical composition of clays using FTIR spectroscopy, Vib. Spectrosc., 59(2012), p. 29.
      [27]
      M. Diaz, V. LaPerche, J. Harsh, and R. Prost, Far infrared spectra of K+ in the dioctahedral and trioctahedral mixed-layer minerals, Am. Miner., 87(2002), No. 8-9, p. 1207.
      [28]
      R. Prost and V. Laperche, Far-infrared study of potassium in micas, Clays Clay Miner., 38(1990), No. 4, p. 351.
      [29]
      V. Laperche and R. Prost, Assignment of the far-infrared absorption bands of K in micas, Clays Clay Miner., 39(1991), No. 3, p. 281.
      [30]
      F. Friedrich, B. Gasharova, Y.L. Mathis., R. Nüesch, and P.G. Weidler, Far-infrared spectroscopy of interlayer vibrations of Cu(Ⅱ), Mg(Ⅱ), Zn(Ⅱ), and Al(Ⅲ) intercalated muscovite, Appl. Spectrosc., 60(2006), No. 7, p. 723.
      [31]
      M. Ritz, L. Vaculíková, and E. Plevová, Identification of clay minerals by infrared spectroscopy and discriminant analysis, Appl. Spectrosc., 64(2010), No. 12, p. 1379.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计