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Volume 24 Issue 2
Feb.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(2): 194-201
Mohamed Reda Boudchicha, Fausto Rubio, and Slimane Achour, Synthesis of glass ceramics from kaolin and dolomite mixture, Int. J. Miner. Metall. Mater., 24(2017), No. 2, pp. 194-201. https://doi.org/10.1007/s12613-017-1395-4
Cite this article as:
Mohamed Reda Boudchicha, Fausto Rubio, and Slimane Achour, Synthesis of glass ceramics from kaolin and dolomite mixture, Int. J. Miner. Metall. Mater., 24(2017), No. 2, pp. 194-201. https://doi.org/10.1007/s12613-017-1395-4
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研究论文

Synthesis of glass ceramics from kaolin and dolomite mixture

  • Engineering Mechanics and Materials Laboratory, Mechanical Engineering Department, Faculty of Technology, Université 20 Août 1955 de Skikda, Skikda 21000, Algeria

  • Ceramics and Glass Institute, Consejo Superior de Investigaciones Cientificas, Madrid 28049, Spain

  • National Polytechnic School, Constantine 25000, Algeria

  • 通讯作者:

    Mohamed Reda Boudchicha    E-mail: boudred72@gmail.com

  • Cordierite-and anorthite-based binary glass ceramics of the CaO-MgO-Al2O3-SiO2 (CMAS) system were synthesized by mixing local and abundant raw minerals (kaolin and doloma by mass ratio of 82/18). A kinetics study reveals that the activation energy of crystallization (Ea) calculated by the methods of Kissinger and Marotta are 438 kJ·mol-1 and 459 kJ·mol-1, respectively. The Avrami parameter (n) is estimated to be approximately equal to 1, corresponding to the surface crystallization mechanism. X-ray diffraction (XRD) analysis shows that the anorthite and cordierite crystals are precipitated from the parent glass as major phases. Anorthite crystals first form at 850℃, whereas the µ-cordierite phase appears after heat treatment at 950℃. Thereafter, the cordierite allotropically transforms to α-cordierite at 1000℃. Complete densification is achieved at 950℃; however, the density slightly decreases at higher temperatures, reaching a stable value of 2.63 kg·m-3 between 1000℃ and 1100℃. The highest Vickers hardness of 6 GPa is also obtained at 950℃. However, a substantial decrease in hardness is recorded at 1000℃; at higher sintering temperatures, it slightly increases with increasing temperature as the α-cordierite crystallizes.
    • Research Article

    Synthesis of glass ceramics from kaolin and dolomite mixture

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      Abstract
    • Cordierite-and anorthite-based binary glass ceramics of the CaO-MgO-Al2O3-SiO2 (CMAS) system were synthesized by mixing local and abundant raw minerals (kaolin and doloma by mass ratio of 82/18). A kinetics study reveals that the activation energy of crystallization (Ea) calculated by the methods of Kissinger and Marotta are 438 kJ·mol-1 and 459 kJ·mol-1, respectively. The Avrami parameter (n) is estimated to be approximately equal to 1, corresponding to the surface crystallization mechanism. X-ray diffraction (XRD) analysis shows that the anorthite and cordierite crystals are precipitated from the parent glass as major phases. Anorthite crystals first form at 850℃, whereas the µ-cordierite phase appears after heat treatment at 950℃. Thereafter, the cordierite allotropically transforms to α-cordierite at 1000℃. Complete densification is achieved at 950℃; however, the density slightly decreases at higher temperatures, reaching a stable value of 2.63 kg·m-3 between 1000℃ and 1100℃. The highest Vickers hardness of 6 GPa is also obtained at 950℃. However, a substantial decrease in hardness is recorded at 1000℃; at higher sintering temperatures, it slightly increases with increasing temperature as the α-cordierite crystallizes.
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