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Volume 24 Issue 3
Mar.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(3): 316-323
Hong-pan Liu, Xiao-feng Huang, Li-ping Ma, Dan-li Chen, Zhi-biao Shang, and Ming Jiang, Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 316-323. https://doi.org/10.1007/s12613-017-1410-9
Cite this article as:
Hong-pan Liu, Xiao-feng Huang, Li-ping Ma, Dan-li Chen, Zhi-biao Shang, and Ming Jiang, Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 316-323. https://doi.org/10.1007/s12613-017-1410-9
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研究论文

Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag

  • Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

  • College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, China

  • 通讯作者:

    Xiao-feng Huang    E-mail: hxfkmust@163.com

  • CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.
    • Research Article

    Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag

    + Author Affiliations
      Abstract
    • CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.
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