Electrochemical performance of a nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries under different cut-off voltages

Kai-lin Cheng; Dao-bin Mu; Bo-rong Wu; Lei Wang; Ying Jiang; Rui Wang

doi:10.1007/s12613-017-1413-6

Volume 24 Issue 3

Mar. 2017

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文章导航 > 矿物冶金与材料学报（英文版） > 2017 > 24(3) : 342-351. > DOI: 10.1007/s12613-017-1413-6

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Kai-lin Cheng, Dao-bin Mu, Bo-rong Wu, Lei Wang, Ying Jiang, and Rui Wang, Electrochemical performance of a nickel-rich LiNi_0.6Co_0.2Mn_0.2O₂ cathode material for lithium-ion batteries under different cut-off voltages, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp.342-351. https://dx.doi.org/10.1007/s12613-017-1413-6

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研究论文

Electrochemical performance of a nickel-rich LiNi_0.6Co_0.2Mn_0.2O₂ cathode material for lithium-ion batteries under different cut-off voltages

Kai-lin Cheng¹⁾,
Dao-bin Mu^1), ,,
Bo-rong Wu^1,2),
Lei Wang¹⁾,
Ying Jiang¹⁾,
Rui Wang¹⁾

Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China

基金项目:

This project was financially supported by NSAF (No. U1530155), Ministry of Science and Technology (MOST) of China, US-China Collaboration on Cutting-edge Technology Development of Electric Vehicle, the Nation Key Basic Research Program of China (No. 2015CB251100), and Beijing Key Laboratory of Environmental Science and Engineering (No. 20131039031).

通信作者:
Dao-bin Mu E-mail: mudb@bit.edu.cn

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中文摘要

A spherical-like Ni_0.6Co_0.2Mn_0.2(OH)₂ precursor was tuned homogeneously to synthesize LiNi_0.6Co_0.2Mn_0.2O₂ as a cathode material for lithium-ion batteries. The effects of calcination temperature on the crystal structure, morphology, and the electrochemical performance of the as-prepared LiNi_0.6Co_0.2Mn_0.2O₂ were investigated in detail. The as-prepared material was characterized by X-ray diffraction, scanning electron microscopy, laser particle size analysis, charge-discharge tests, and cyclic voltammetry measurements. The results show that the spherical-like LiNi_0.6Co_0.2Mn_0.2O₂ material obtained by calcination at 900℃ displayed the most significant layered structure among samples calcined at various temperatures, with a particle size of approximately 10 μm. It delivered an initial discharge capacity of 189.2 mAh·g^-1 at 0.2C with a capacity retention of 94.0% after 100 cycles between 2.7 and 4.3 V. The as-prepared cathode material also exhibited good rate performance, with a discharge capacity of 119.6 mAh·g^-1 at 5C. Furthermore, within the cut-off voltage ranges from 2.7 to 4.3, 4.4, and 4.5 V, the initial discharge capacities of the calcined samples were 170.7, 180.9, and 192.8 mAh·g^-1, respectively, at a rate of 1C. The corresponding retentions were 86.8%, 80.3%, and 74.4% after 200 cycles, respectively.

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Research Article

Electrochemical performance of a nickel-rich LiNi_0.6Co_0.2Mn_0.2O₂ cathode material for lithium-ion batteries under different cut-off voltages

Kai-lin Cheng¹⁾,
Dao-bin Mu^1), ,,
Bo-rong Wu^1,2),
Lei Wang¹⁾,
Ying Jiang¹⁾,
Rui Wang¹⁾

Author Affilications

Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China

Funds:
This project was financially supported by NSAF (No. U1530155), Ministry of Science and Technology (MOST) of China, US-China Collaboration on Cutting-edge Technology Development of Electric Vehicle, the Nation Key Basic Research Program of China (No. 2015CB251100), and Beijing Key Laboratory of Environmental Science and Engineering (No. 20131039031).
Received: 11 October 2016; Revised: 30 October 2016; Accepted: 01 November 2016;

Abstract:

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Comparative study of LiNiO₂, LiNi_0.8Co_0.2O₂ and LiNi_0.75Al_0.25O₂ for lithium-ion batteries

Int. J. Miner. Metall. Mater., 2002, 9(6): 448-452.

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Chuangang Lin, Weihua Qiu, Zhimin Li, Jialing Hong, Huanyu Hu, Zhongqin Lu. Comparative study of LiNiO₂, LiNi_0.8Co_0.2O₂ and LiNi_0.75Al_0.25O₂ for lithium-ion batteries [J]. 矿物冶金与材料学报（英文版）.

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Electrochemical Studies of Lithium Intercalation into Graphite Film Electrode for Li⁺-ion Batteries

Int. J. Miner. Metall. Mater., 2000, 7(1): 48-50.

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Chuangang Lin, Weihua Qiu, Qingguo Liu. Electrochemical Studies of Lithium Intercalation into Graphite Film Electrode for Li⁺-ion Batteries [J]. 矿物冶金与材料学报（英文版）.

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