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Volume 24 Issue 4
Apr.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(4): 401-409
Lei Zhang, Hui-xin Li, Feng-xian Shi, Jian-wei Yang, Li-hua Hu, and Min-xu Lu, Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel, Int. J. Miner. Metall. Mater., 24(2017), No. 4, pp. 401-409. https://doi.org/10.1007/s12613-017-1420-7
Cite this article as:
Lei Zhang, Hui-xin Li, Feng-xian Shi, Jian-wei Yang, Li-hua Hu, and Min-xu Lu, Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel, Int. J. Miner. Metall. Mater., 24(2017), No. 4, pp. 401-409. https://doi.org/10.1007/s12613-017-1420-7
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研究论文

Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel

  • Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

  • Aircraft Engine Corporation of China Shanghai Commercial Aircraft Engine Manufacturing Co., Ltd., Shanghai 201306, China

  • Shougang Research Institute of Technology, Beijing 100043, China

  • China National Offshore Oil Corporation Research Institute, Beijing 100027, China

  • 通讯作者:

    Lei Zhang    E-mail: zhanglei@ustb.edu.cn

  • To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry.
    • Research Article

    Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel

    + Author Affiliations
      Abstract
    • To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry.
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    • [1]
      E. Abelev, J. Sellberg, T. A. Ramanarayanan, and S. L. Bernsek, Effect of H2S on Fe corrosion in CO2-saturated brine, J. Mater. Sci., 44(2009), No. 22, p. 6167.
      [2]
      B. Tribollet, J. Kittel, A. Meroufel, F. Ropital, F. Grosjean, and E. M. M. Sutter, Corrosion mechanisms in aqueous solutions containing dissolved H2S:Part 2. Model of the cathodic reactions on a 316L stainless steel rotating disc electrode, Electrochim. Acta, 124(2014), p. 46.
      [3]
      Y. G. Zheng, J. Ning, B. Brown, and S. Nesic, Electrochemical model of mild steel corrosion in a mixed H2S/CO2 aqueous environment in the absence of protective corrosion product layers, Corrosion, 71(2015), No. 3, p. 316.
      [4]
      D. Masouri, M. Zafari, and A. M. Araghi, Sulfide stress cracking of pipeline-case history,[in] Corrosion 2008, New Orleans, 2008, NACE-08480.
      [5]
      M. Singer, B. Brown, A. Camacho, and S. Nesic, Combined effect of CO2, H2S and acetic acid on bottom of the line corrosion,[in] Corrosion 2007, Nashville, 2007, NACE-07661.
      [6]
      S. Nesic, S. Wang, H. Fang, W. Sun, and J. K. L. Lee, A new updated model of CO2/H2S corrosion in multiphase flow,[in] Corrosion 2008, New Orleans, 2008, NACE-08535.
      [7]
      M. X. Lu, Z. Q. Bai, X. W. Zhao, G. X. Zhao, J. H. Luo, and C. F. Chen, Actuality and typical cases for corrosion in the process of extraction, gathering, storage and transmission for oil and gas, Corros. Prot., 3(2002), No. 23, p. 105.
      [8]
      W. Sun, S. Nesic, D. Young, and R. C. Woollam, Equilibrium expressions related to the solubility of the sour corrosion product mackinawite, Ind. Eng. Chem. Res., 47(2008), No. 5, p. 1738.
      [9]
      S. N. Smith, B. Brown, and W. Sun, Corrosion at higher H2S concentrations and moderate temperatures,[in] Corrosion 2011, Huston, 2011, NACE-11081.
      [10]
      H. Y. Ma, X. L. Cheng, G. Q. Li, S. H. Chen, Z. L. Quan, S. Y. Zhao, and L. Niu, The influence of hydrogen sulfide on corrosion of iron under different conditions, Corros. Sci., 42(2000), No. 10, p. 1669.
      [11]
      J. Ning, Y. G. Zheng, D. Young, B. Brown, and S. Nešić, Thermodynamic study of hydrogen sulfide corrosion of mild steel, Corrosion, 70(2014), No. 4, p. 375.
      [12]
      S. Nešić, Key issues related to modeling of internal corrosion of oil and gas pipelines:a review, Corros. Sci., 49(2007), No. 12, p. 4308.
      [13]
      Z. F. Yin, W. Z. Zhao, Z. Q. Bai, Y. R. Feng, and W. J. Zhou, Corrosion behavior of SM 80SS tube steel in stimulant solution containing H2S and CO2, Electrochim. Acta, 53(2008), No. 10, p. 3690.
      [14]
      A. Davoodi, M. Pakshir, M. Babaiee, and G. R. Ebrahimi, A comparative H2S corrosion study of 304L and 316L stainless steels in acidic media, Corros. Sci., 53(2011), No. 1, p. 399.
      [15]
      J. W. Tang, Y. W. Shao, J. B. Guo, T. Zhang, G. Z. Meng, and F. H. Wang, The effect of H2S concentration on the corrosion behavior of carbon steel at 90℃, Corros. Sci., 52(2010), No. 6, p. 2050.
      [16]
      D. Rickard and G. W. Luther, Chemistry of iron sulfides, Chem. Rev., 107(2007), No. 2, p. 514.
      [17]
      F. X. Shi, L. Zhang, J. W. Yang, M. X. Lu, J. H. Ding, and H. Li, Polymorphous FeS corrosion products of pipeline steel under highly sour conditions, Corros. Sci. 102(2016), p. 103.
      [18]
      D. T. Rickard, The chemistry of iron sulphide formation at low temperatures, Acta Univ. Stockholm. Stockholm Contrib. Geol., 20(1969), p. 67.
      [19]
      C. Li, S. Ling, F. Cao, J. Pacheco, and S. Desai, Effect of sodium chloride concentration on carbon steel sour corrosion,[in] Corrosion 2013, Orlando, 2013, NACE-2486.
      [20]
      M. Ueda, Effect of alloying elements and microstructure on stability of corrosion product in CO2 and/or H2S environments, Chem. Eng. Oil Gas, 34(2005), No. 1, p. 43.
      [21]
      P. P. Bai, S. Q. Zheng, H. Zhao, Y. Ding, J. Wu, and C. F. Chen, Investigations of the diverse corrosion products on steel in a hydrogen sulfide environment, Corros. Sci., 87(2014), No. 5, p. 397.
      [22]
      M. Alizadeh and S. Bordbar, The influence of microstructure on the protective properties of the corrosion product layer generated on the welded API X70 steel in chloride solution, Corros. Sci., 70(2013), No. 3, p. 170.
      [23]
      S. N. Smith and J. L. Pacheco, Prediction of corrosion in slightly sour environments,[in] Corrosion 2002, Denver, 2002, NACE-02241.
      [24]
      C. S. Zhou, S. Q. Zheng, C. F. Chen, and G. W. Lu, The effect of partial pressure of H2S on the permeation of hydrogen in low carbon pipeline steel, Corrs. Sci., 67(2013), p. 184.
      [25]
      S. N. Smith, Current understanding of corrosion mechanisms due to H2S in oil and gas production environments,[in] Corrosion 2015, Texas, 2015, NACE-5485.
      [26]
      M. singer, J. A. Khamis, and S. Nešić, Experimental study of sour top-of-the-line corrosion using a novel experimental setup, Corros. Eng., 69(2013), No. 6, p. 624.
      [27]
      R. Rihan, M. N. Zafar, and L. AI-Hadhrami, A novel emulsion flow loop for investigating the corrosion of X65 steel in emulsions with H2S/CO2, J. Mater. Eng. Perform., 25(2016), No. 7, p. 3065.
      [28]
      Y. S. Choi, S. Nesic, and S. Ling, Effect of H2S on the CO2 corrosion of carbon steel in acidic solutions, Electrochim. Acta, 56(2011), No. 4, p. 1752.
      [29]
      M. Liu, J. Q. Wang, W. Ke, and E. H. Han, Corrosion behavior of X52 anti-H2S pipeline steel exposed to high H2S concentration solutions at 90℃, J. Mater. Sci. Technol., 30(2014), No. 5, p. 504.
      [30]
      P. P. Bai, H. Zhao, S. Q. Zheng, and C. F. Chen, Initiation and developmental stages of steel corrosion in wet H2S environments, Corros. Sci., 93(2015), p. 109.
      [31]
      J. S. Smith and J. D. A. Miller, Nature of sulfides and their corrosive effect on ferrous metals:a review, Br. Corros. J., 10(1975), No. 3, p. 136.
      [32]
      J. W. Morse, F. J. Millero, J. C. Cornwell, and D. Rickard, The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters, Earth Sci. Rev., 24(1987), No. 1, p. 1.
      [33]
      J. W. Yang, Corrosion and Hydrogen Permeation Behavior of Pipeline Steels under High H2S/CO2 Pressure[Dissertation], University of Science and Technology Beijing, Beijing, 2009, p. 12.
      [34]
      A. G. Wikjord, T. E. Rummery, F. E. Doern, and D. G. Owen, Corrosion and deposition during the exposure of carbon steel to hydrogen sulphide-water solutions, Corros. Sci., 20(1980), No. 5, p. 651.
      [35]
      W. H. Thomason, Formation rates of protective iron sulfide films on mild steel in H2S saturated brine as a function of temperature,[in] Corrosion 1978, Huston, 1978, NACE-41.
      [36]
      C. Q. Ren, D. X. Liu, Z. Q. Bai, and T. H. Li, Corrosion behavior of oil tube steel in stimulant solution with hydrogen sulfide and carbon dioxide, Mater. Chem. Phys., 93(2005), No. 2-3, p. 305.
      [37]
      H. J. Choi, N. S. Al-Bannai, F. I. Al-Beheiri, and D. Warnken, Field corrosion assessment of L80 carbon steel downhole production tubing in Khuff Gas Wells,[in] Corrosion 2006, San Diego, 2006, NACE-06653.
      [38]
      J. Kvarekval, R. Nyborg, H. Choi, and J. Kvarekval, Formation of multilayer iron sulfide films during high temperature CO2/H2S corrosion of carbon steel,[in] Corrosion 2003, San Diego, 2003, NACE-03339.
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