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Volume 24 Issue 4
Apr.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(4): 401-409
Lei Zhang, Hui-xin Li, Feng-xian Shi, Jian-wei Yang, Li-hua Hu,  and Min-xu Lu, Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel, Int. J. Miner. Metall. Mater., 24(2017), No. 4, pp. 401-409. https://doi.org/10.1007/s12613-017-1420-7
Cite this article as:
Lei Zhang, Hui-xin Li, Feng-xian Shi, Jian-wei Yang, Li-hua Hu,  and Min-xu Lu, Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel, Int. J. Miner. Metall. Mater., 24(2017), No. 4, pp. 401-409. https://doi.org/10.1007/s12613-017-1420-7
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研究论文

Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel

  • Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

  • Aircraft Engine Corporation of China Shanghai Commercial Aircraft Engine Manufacturing Co., Ltd., Shanghai 201306, China

  • Shougang Research Institute of Technology, Beijing 100043, China

  • China National Offshore Oil Corporation Research Institute, Beijing 100027, China

  • 通讯作者:

    Lei Zhang    E-mail: zhanglei@ustb.edu.cn

  • To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry.
    • Research Article

    Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel

    + Author Affiliations
      Abstract
    • To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry.
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