留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 24 Issue 5
May  2017
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  638
  • HTML全文浏览量:  116
  • PDF下载量:  15
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(5): 574-583
Zhi-yuan Chen, Liu-zhen Bian, Li-jun Wang, Zi-you Yu, Hai-lei Zhao, Fu-shen Li,  and Kuo-chih Chou, Topography, structure, and formation kinetic mechanism of carbon deposited onto nickel in the temperature range from 400 to 850℃, Int. J. Miner. Metall. Mater., 24(2017), No. 5, pp. 574-583. https://doi.org/10.1007/s12613-017-1439-9
Cite this article as:
Zhi-yuan Chen, Liu-zhen Bian, Li-jun Wang, Zi-you Yu, Hai-lei Zhao, Fu-shen Li,  and Kuo-chih Chou, Topography, structure, and formation kinetic mechanism of carbon deposited onto nickel in the temperature range from 400 to 850℃, Int. J. Miner. Metall. Mater., 24(2017), No. 5, pp. 574-583. https://doi.org/10.1007/s12613-017-1439-9
shu
引用本文 PDF XML SpringerLink
研究论文

Topography, structure, and formation kinetic mechanism of carbon deposited onto nickel in the temperature range from 400 to 850℃

  • State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China

  • Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China

  • School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

  • 通讯作者:

    Li-jun Wang    E-mail: lijunwang@ustb.edu.cn

  • The carbon deposition behavior on nickel particles was observed within the temperature range from 400 to 800℃ in a pure methane atmosphere. The topography, properties, and molecular structure of the deposited carbon were investigated using field-emission scanning electron microscopy (FESEM), temperature-programmed oxidation (TPO) technology, X-ray diffraction (XRD), and Raman spectroscopy. The deposited carbon is present in the form of a film at 400-450℃, as fibers at 500-600℃, and as particles at 650-800℃. In addition, the structure of the deposited carbon becomes more ordered at higher temperatures because both the TPO peak temperature of deposited carbon and the Raman shift of the G band increase with the increase in experimental temperature, whereas the intensity ratio between the D bands and the G band decreases. An interesting observation is that the carbon deposition rate is suppressed in the medium-temperature range (M-T range) and the corresponding kinetic mechanism changes. Correspondingly, the FWHM of the G and D1 bands in the Raman spectrum reaches a maximum and the intensities of the D2, D3, and D4 bands decrease to low limits in the M-T range. These results indicate that carbon structure parameters exhibit two different tendencies with respect to varying temperature. Both of the two group parameters change dramatically as a peak function with increasing reaction temperature within the M-T range.
    • Research Article

    Topography, structure, and formation kinetic mechanism of carbon deposited onto nickel in the temperature range from 400 to 850℃

    + Author Affiliations
      Abstract
    • The carbon deposition behavior on nickel particles was observed within the temperature range from 400 to 800℃ in a pure methane atmosphere. The topography, properties, and molecular structure of the deposited carbon were investigated using field-emission scanning electron microscopy (FESEM), temperature-programmed oxidation (TPO) technology, X-ray diffraction (XRD), and Raman spectroscopy. The deposited carbon is present in the form of a film at 400-450℃, as fibers at 500-600℃, and as particles at 650-800℃. In addition, the structure of the deposited carbon becomes more ordered at higher temperatures because both the TPO peak temperature of deposited carbon and the Raman shift of the G band increase with the increase in experimental temperature, whereas the intensity ratio between the D bands and the G band decreases. An interesting observation is that the carbon deposition rate is suppressed in the medium-temperature range (M-T range) and the corresponding kinetic mechanism changes. Correspondingly, the FWHM of the G and D1 bands in the Raman spectrum reaches a maximum and the intensities of the D2, D3, and D4 bands decrease to low limits in the M-T range. These results indicate that carbon structure parameters exhibit two different tendencies with respect to varying temperature. Both of the two group parameters change dramatically as a peak function with increasing reaction temperature within the M-T range.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(48)
    • [1]
      M.N. Pérez-Camacho, J. Abu-Dahrieh, A. Goguet, K.N. Sun, and D. Rooney, Self-cleaning perovskite type catalysts for the dry reforming of methane, Chin. J. Catal., 35(2014), No.8, p. 1337.
      [2]
      J. Kuhn and O. Kesler, Method for in situ carbon deposition measurement for solid oxide fuel cells, J. Power Sources, 246(2014),p. 430.
      [3]
      M. Yoshinaga, H. Kishimoto, M.E. Brito, K. Yamaji, T. Horita, and H. Yokokawa, Carbon deposition map for nickel particles onto oxide substrates analyzed by micro-Raman spectroscopy, J. Ceram. Soc. Jpn., 119(2011), No.1388, p. 307.
      [4]
      T. Chen, W.G. Wang, H. Miao, T.S. Li, and C. Xu, Evaluation of carbon deposition behavior on the nickel/yttrium-stabilized zirconia anode-supported fuel cell fueled with simulated syngas, J. Power Sources, 196(2011), No.5, p. 2461.
      [5]
      E.D. German and M. Sheintuch, Predicting CH4 dissociation kinetics on metals:trends, sticking coefficients, H tunneling, and kinetic isotope effect, J. Phys. Chem. C, 117(2013), No.44, p. 22811.
      [6]
      W.W. Ma, Z.P. Zhou, G. Li, and P. Li, Effect of catalyst film thickness on growth morphology, surface wettability and drag reduction property of carbon nanotubes, High Temp. Mater. Processes, 35(2016), No. 9, p. 857.
      [7]
      C.M. Finnerty, N.J. Coe, R.H. Cunningham, and R.M. Ormerod, Carbon formation on and deactivation of nickel-based/zirconia anodes in solid oxide fuel cells running on methane, Catal. Today, 46(1998), No.2-3, p. 137.
      [8]
      I. Alstrup, M.T. Tavares, C.A. Bernardo, O. Sørensen, and J.R. Rostrup-Nielsen, Carbon formation on nickel and nickel-copper alloy catalysts, Mater. Corros., 49(1998), No. 5, p. 367.
      [9]
      P.E. Nolan, D.C. Lynch, and A.H. Cutler, Carbon deposition and hydrocarbon formation on group VⅢ metal catalysts, J. Phys. Chem. B, 102(1998), No. 21, p. 4165.
      [10]
      M.L. Toebes, J.H. Bitter, A.J.V. Dillen, and K.P.D. Jong, Impact of the structure and reactivity of nickel particles on the catalytic growth of carbon nanofibers, Catal. Today, 76(2002), No.1, p. 33.
      [11]
      C. Su, R. Ran, W. Wang, and Z.P. Shao, Coke formation and performance of an intermediate-temperature solid oxide fuel cell operating on dimethyl ether fuel, J. Power Sources, 196(2011), No.4, p. 1967.
      [12]
      G.G. Kuvshinov, Y.I. Mogilnykh, D.G. Kuvshinov, V.I. Zaikovskii, and L.B. Avdeeva, Peculiarities of filamentous carbon formation in methane decomposition on Ni-containing catalysts, Carbon, 36(1998), No.1-12, p. 87.
      [13]
      Y.D. Li, J.L. Chen, Y.N. Qin, and L. Chang, Simultaneous production of hydrogen and nanocarbon from decomposition of methane on a nickel-based catalyst, Energy Fuels, 14(2000), No.6, p. 1188.
      [14]
      K. Asai, Y. Nagayasu, K. Takane, S. Iwamoto, E. Yagasaki, K.I. Ishii, and M. Inoue, Mechanisms of methane decomposition over Ni catalysts at high temperatures, J. Jpn. Pet. Inst., 51(2008), No.1,p. 42.
      [15]
      J.L. Figueiredo, Carbon deposition leading to filament growth on metals, Mater. Corros., 49(1998), No.5, p. 373.
      [16]
      M. Inoue, K. Asai, Y. Nagayasu, K. Takane, S. Iwamoto, E. Yagasaki, and K.I. Ishii, Formation of multi-walled carbon nanotubes by Ni-catalyzed decomposition of methane at 600-750℃, Diamond Relat. Mater., 17(2008), No.7-10, p. 1471.
      [17]
      J. Rostrup-Nielsen and D.L. Trimm, Mechanisms of carbon formation on nickel-containing catalysts, J. Catal., 48(1977), No.1-3, p. 155.
      [18]
      Y.Z. Wang, F. Yoshiba, M. Kawase, and T. Watanabe, Performance and effective kinetic models of methane steam reforming over Ni/YSZ anode of planar SOFC, Int. J. Hydrogen Energy, 34(2009), No.9, p. 3885.
      [19]
      K.H. Hou and R. Hughes, The kinetics of methane steam reforming over a Ni/α-Al2O3 catalyst, Chem. Eng. J., 82(2001), No.1-3, p. 311.
      [20]
      J.G. Xu and G.F. Froment, Methane steam reforming, methanation and water-gas shift:I. Intrinsic kinetics, AIChE J., 35(1989), No.1, p. 88.
      [21]
      H.S. Bengaard, J.K. Nørskov, J. Sehested, B.S. Clausen, L.P. Nielsen, A.M. Molenbroek, and J.R. Rostrup-Nielsen, Steam reforming and graphite formation on Ni catalysts, J. Catal., 209(2002), No.2, p. 365.
      [22]
      N.M. Rodriguez, M.S. Kim, F. Fortin, I. Mochida, and R.T.K. Baker, Carbon deposition on iron-nickel alloy particles, Appl. Catal. A, 148(1997), No.2, p. 265.
      [23]
      C. Su, Y.Z. Wu, W. Wang, Y. Zheng, R. Ran, and Z.P. Shao, Assessment of nickel cermets and La0.8Sr0.2Sc0.2Mn0.8O3 as solid-oxide fuel cell anodes operating on carbon monoxide fuel, J. Power Sources, 195(2010), No.5, p. 1333.
      [24]
      J. Shi and O. Nittono, Formation of Ni3C nanocrystallites in codeposited Ni-C films, J. Mater. Sci. Lett., 15(1996), No.11, p. 928.
      [25]
      R.P.W.J. Struis, D. Bachelin, C. Ludwig, and A. Wokaun, Studying the formation of Ni3C from Co and metallic Ni at T=265℃ in situ using Ni K-edge X-ray absorption spectroscopy, J. Phys. Chem. C, 113(2009), No.6, p. 2443.
      [26]
      F. Banhart, Interactions between metals and carbon nanotubes:at the interface between old and new materials, Nanoscale, 1(2009), No.2, p. 201.
      [27]
      K.P.D. Jong and J.W. Geus, Carbon nanofibers:catalytic synthesis and applications, Catal. Rev., 2(2000), No.4, p. 481.
      [28]
      C.D. Sheng, Char structure characterised by Raman spectroscopy and its correlations with combustion reactivity, Fuel, 86(2007), No.15, p. 2316.
      [29]
      H. Bakhshi, A. Shokuhfar, and N. Vahdati, Synthesis and characterization of carbon-coated cobalt ferrite nanoparticles, Int. J. Miner. Metall. Mater., 23(2016), No.9, p. 1104.
      [30]
      Y.G. Shi, Y. Hao, D. Wang, J.C. Zhang, P. Zhang, X.F. Shi, D. Han, Z. Chai, and J.D. Yan, Effects of the flow rate of hydrogen on the growth of graphene, Int. J. Miner. Metall. Mater., 22(2015), No.1, p. 102.
      [31]
      R.C. Maher, V. Duboviks, G.J. Offer, M. Kishimoto, N.P. Brandon, and L.F. Cohen, Raman spectroscopy of solid oxide fuel cells:technique overview and application to carbon deposition analysis, Fuel Cells, 13(2013), No.4, p. 455.
      [32]
      Z.Y. Wu, S.Q. Hu, and Z.Q. Wang, Simple method to rapidly fabricate chain-like carbon nanotube films and its field emission properties, Int. J. Miner. Metall. Mater., 17(2010), No.3, p. 371.
      [33]
      A. Sadezky, H. Muckenhuber, H. Grothe, R. Niessner, and U. Pöschl, Raman microspectroscopy of soot and related carbonaceous materials:spectral analysis and structural information, Carbon, 43(2005), No.8, p. 1731.
      [34]
      A. Zaida, E. Bar-Ziv, L.R. Radovic, and Y.J. Lee, Further development of Raman microprobe spectroscopy for characterization of char reactivity, Proc. Combust. Inst., 31(2007), No. 2, p. 1881.
      [35]
      R.J. Nemanich and S.A. Solin, First- and second-order Raman scattering from finite-size crystals of graphite, Phys. Rev. B, 20(1979), No.2, p. 392.
      [36]
      F. Li and J.S. Lannin, Disorder induced Raman scattering of nanocrystalline carbon, Appl. Phys. Lett., 61(1992), No.17, p. 2116.
      [37]
      W.S. Bacsa, J.S. Lannin, D.L. Pappas, and J.J. Cuomo, Raman scattering of laser-deposited amorphous carbon, Phys. Rev. B, 47(1993), No.16, p. 10931.
      [38]
      X.F. Li, A. Dhanabalan, and C.L. Wang, Enhanced electrochemical performance of porous NiO-Ni nanocomposite anode for lithium ion batteries, J. Power Sources, 196(2011), No.22, p. 9625.
      [39]
      J. Pérez-Ramı́rez, G. Mul, and J.A. Moulijn, In situ Fourier transform infrared and laser Raman spectroscopic study of the thermal decomposition of Co-Al and Ni-Al hydrotalcites, Vib. Spectrosc., 27(2001), No.1, p. 75.
      [40]
      A.L. Pinheiro, A.N. Pinheiro, A. Valentini, J.M. Filho, F.F.D. Sousa, J.R.D. Sousa, M.D.G.C. Rocha, P. Bargiela, and A.C. Oliveira, Analysis of coke deposition and study of the structural features of MAl2O4 catalysts for the dry reforming of methane, Catal. Commun., 11(2009), No.1, p. 11.
      [41]
      M.S. Dresselhaus, G. Dresselhaus, R. Saito, and A. Jorio, Raman spectroscopy of carbon nanotubes, Phys. Rep., 409(2005), No.2, p. 47.
      [42]
      Y. Wang, D.C. Alsmeyer, and R.L. McCreery, Raman spectroscopy of carbon materials:structural basis of observed spectra, Chem. Mater., 2(1990), No.5, p. 557.
      [43]
      A.C. Ferrari and J. Robertson, Interpretation of Raman spectra of disordered and amorphous carbon, Phys. Rev. B, 61(2000), No. 20, p. 14095.
      [44]
      S. Reich and C. Thomsen, Raman spectroscopy of graphite, Philos. Trans. R. Soc. London Ser. A, 362(2004), No. 1824, p. 2271.
      [45]
      D.S. Knight and W.B. White, Characterization of diamond films by Raman spectroscopy, J. Mater. Res., 4(1989), No. 2, p. 385.
      [46]
      C. Casiraghi, A.C. Ferrari, and J. Robertson, Raman spectroscopy of hydrogenated amorphous carbons, Phys. Rev. B, 72(2005), No. 8, p. 085401.
      [47]
      T.C. Chieu, M.S. Dresselhaus, and M. Endo, Raman studies of benzene-derived graphite fibers, Phys. Rev. B, 26(1982), No. 10, p. 5867.
      [48]
      B. Manoj and A.G. Kunjomana, Chemical leaching of an Indian bituminous coal and characterization of the products by vibrational spectroscopic techniques, Int. J. Miner. Metall. Mater., 19(2012), No. 4, p. 279.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计