Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity

Bing-wei Luo, Jie Zhou, Peng-peng Bai, Shu-qi Zheng, Teng An, Xiang-li Wen

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Bing-wei Luo, Jie Zhou, Peng-peng Bai, Shu-qi Zheng, Teng An, and Xiang-li Wen, Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity, Int. J. Miner. Metall. Mater., 24(2017), No. 6, pp.646-656. https://dx.doi.org/10.1007/s12613-017-1447-9
Bing-wei Luo, Jie Zhou, Peng-peng Bai, Shu-qi Zheng, Teng An, and Xiang-li Wen, Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity, Int. J. Miner. Metall. Mater., 24(2017), No. 6, pp.646-656. https://dx.doi.org/10.1007/s12613-017-1447-9
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Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity

基金项目: 

This work was financially supported by the National Natural Science Foundation of China (No. 51671215), the Science Foundation of China University of Petroleum, Beijing (No. LLYJ-2011-41), and the Ph.D Basic Research Innovation Foundation of China University of Petroleum, Beijing (No. 2462016YXBS06).

The corrosion behaviors of X52, 3Cr low-alloy steel, and 13Cr stainless steel were investigated in an O2-H2O-CO2 environment at various temperatures and O2-CO2 partial-pressure ratios. The results showed that the corrosion rates of X52, 3Cr, and 13Cr steels increased with increasing temperature. The corrosion rates slowly increased at temperatures less than 100℃ and increased sharply when the temperature exceeded 100℃. In the absence of O2, X52, 3Cr, and 13Cr exhibited uniform corrosion morphology and FeCO3 was the main corrosion product. When O2 was introduced into the system, various forms of Fe2O3 appeared on the surface of the samples. The Cr content strongly influenced the corrosion resistance. The 3Cr steel with a low Cr content was more sensitive to pitting than the X52 or 13Cr steel. Thus, pitting occurred on the surface of 3Cr when 1.25 MPa of O2 was added; this phenomenon is related to the non-uniform distribution of Cr in 3Cr.

 

Research Article Open Access

Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity

Author Affilications
  • Funds: 

    This work was financially supported by the National Natural Science Foundation of China (No. 51671215), the Science Foundation of China University of Petroleum, Beijing (No. LLYJ-2011-41), and the Ph.D Basic Research Innovation Foundation of China University of Petroleum, Beijing (No. 2462016YXBS06).

  • Received: 16 November 2016; Revised: 28 February 2017; Accepted: 02 March 2017;
The corrosion behaviors of X52, 3Cr low-alloy steel, and 13Cr stainless steel were investigated in an O2-H2O-CO2 environment at various temperatures and O2-CO2 partial-pressure ratios. The results showed that the corrosion rates of X52, 3Cr, and 13Cr steels increased with increasing temperature. The corrosion rates slowly increased at temperatures less than 100℃ and increased sharply when the temperature exceeded 100℃. In the absence of O2, X52, 3Cr, and 13Cr exhibited uniform corrosion morphology and FeCO3 was the main corrosion product. When O2 was introduced into the system, various forms of Fe2O3 appeared on the surface of the samples. The Cr content strongly influenced the corrosion resistance. The 3Cr steel with a low Cr content was more sensitive to pitting than the X52 or 13Cr steel. Thus, pitting occurred on the surface of 3Cr when 1.25 MPa of O2 was added; this phenomenon is related to the non-uniform distribution of Cr in 3Cr.

 

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