Phase transformation and crystal growth behavior of 8mol% (SmO1.5, GdO1.5, and YO1.5) stabilized ZrO2 powders

R. Mahendran; S. P. Kumaresh Babu; S. Natarajan; S. Manivannan; A. Vallimanalan

doi:10.1007/s12613-017-1468-4

Volume 24 Issue 7

Jul. 2017

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文章导航 > 矿物冶金与材料学报（英文） > 2017 > 24(7): 842-849

R. Mahendran, S. P. Kumaresh Babu, S. Natarajan, S. Manivannan, and A. Vallimanalan, Phase transformation and crystal growth behavior of 8mol% (SmO_1.5, GdO_1.5, and YO_1.5) stabilized ZrO₂ powders, Int. J. Miner. Metall. Mater., 24(2017), No. 7, pp. 842-849. https://doi.org/10.1007/s12613-017-1468-4

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R. Mahendran, S. P. Kumaresh Babu, S. Natarajan, S. Manivannan, and A. Vallimanalan, Phase transformation and crystal growth behavior of 8mol% (SmO1.5, GdO1.5, and YO1.5) stabilized ZrO2 powders, Int. J. Miner. Metall. Mater., 24(2017), No. 7, pp. 842-849. https://doi.org/10.1007/s12613-017-1468-4

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Phase transformation and crystal growth behavior of 8mol% (SmO_1.5, GdO_1.5, and YO_1.5) stabilized ZrO₂ powders

Department of Metallurgical and Materials Engineering, National Institute of Technology, Tirchirappalli 620015, Tamil Nadu, India

通讯作者:
R. Mahendran E-mail: mahendran.meta@gmail.com

中文摘要

Nanocrystalline powders of ZrO₂-8mol%SmO_1.5(8SmSZ), ZrO₂-8mol%GdO_1.5 (8GdSZ), and ZrO₂-8mol%YO_1.5(8YSZ) were prepared by a simple reverse-coprecipitation technique. Differential thermal analysis/thermogravimetry (DTA/TG), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM) were used to study the phase transformation and crystal growth behavior. The DTA results showed that the ZrO₂ freeze-dried precipitates crystallized at 529, 465, and 467℃ in the case of 8SmSZ, 8GdSZ, and 8YSZ, respectively. The XRD and Raman results confirmed the presence of tetragonal ZrO₂ when the dried precipitates were calcined in the temperature range from 600 to 1000℃ for 2 h. The crystallite size increased with increasing calcination temperature. The activation energies were calculated as 12.39, 12.45, and 16.59 kJ/mol for 8SmSZ, 8GdSZ, and 8YSZ respectively.

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Phase transformation and crystal growth behavior of 8mol% (SmO_1.5, GdO_1.5, and YO_1.5) stabilized ZrO₂ powders

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Abstract

Abstract

Nanocrystalline powders of ZrO₂-8mol%SmO_1.5(8SmSZ), ZrO₂-8mol%GdO_1.5 (8GdSZ), and ZrO₂-8mol%YO_1.5(8YSZ) were prepared by a simple reverse-coprecipitation technique. Differential thermal analysis/thermogravimetry (DTA/TG), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM) were used to study the phase transformation and crystal growth behavior. The DTA results showed that the ZrO₂ freeze-dried precipitates crystallized at 529, 465, and 467℃ in the case of 8SmSZ, 8GdSZ, and 8YSZ, respectively. The XRD and Raman results confirmed the presence of tetragonal ZrO₂ when the dried precipitates were calcined in the temperature range from 600 to 1000℃ for 2 h. The crystallite size increased with increasing calcination temperature. The activation energies were calculated as 12.39, 12.45, and 16.59 kJ/mol for 8SmSZ, 8GdSZ, and 8YSZ respectively.
- zirconia;
- thermal analysis;
- reverse coprecipitation;
- activation energy

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[1]	N.P. Padture, M. Gell, and E.H. Jordan, Thermal barrier coatings for gas-turbine engine applications, Science, 296(2002), No. 5566, p. 280.
[2]	D.R. Clarke, M. Oechsner, and N.P. Padture, Thermal-barrier coatings for more efficient gas-turbine engines, MRS Bull., 37(2012), No. 10, p. 891.
[3]	Y.L. Zhang, L. Guo, Y.P. Yang, H.B. Guo, H.J. Zhang, and S.K. Gong, Influence of Gd₂O₃ and Yb₂O₃ Co-doping on phase stability, thermo-physical properties and sintering of 8YSZ, Chin. J. Aeronaut., 25(2012), No. 6, p. 948.
[4]	J. Feng, X.R. Ren, X.Y. Wang, R. Zhou, and W. Pan, Thermal conductivity of ytterbia-stabilized zirconia, Scripta Mater., 66(2012), No. 1, p. 41.
[5]	L.L. Sun, H.B. Guo, H. Peng, S.K. Gong, and H.B. Xu, Influence of partial substitution of Sc₂O₃ with Gd₂O₃ on the phase stability and thermal conductivity of Sc₂O₃-doped ZrO₂, Ceram. Int., 39(2013), No. 3, p. 3447.
[6]	H.F. Liu, S.L. Li, Q.L. Li, and Y.M. Li, Investigation on the phase stability, sintering and thermal conductivity of Sc₂O₃-Y₂O₃-ZrO₂ for thermal barrier coating application, Mater. Des., 31(2010), No. 6, p. 2972.
[7]	Q.L. Li, X.Z. Cui, S.Q. Li, W.H. Yang, C. Wang, and Q. Cao, Synthesis and phase stability of scandia, gadolinia, and ytterbia Co-doped zirconia for thermal barrier coating application, J. Therm. Spray Technol., 24(2015), No. 1, p. 136.
[8]	D.M. Zhu, Y.L. Chen, and R.A. Miller, Defect clustering and nanophase structure characterization of multi-component rare earth-oxide-doped zirconia-yttria thermal barrier coatings, Ceram. Eng. Sci. Proc., 24(2003), No. 3, p. 525.
[9]	M.B. Ponnuchamy and A.S. Gandhi, Phase and fracture toughness evolution during isothermal annealing of spark plasma sintered zirconia co-doped with Yb, Gd and Nd oxides, J. Eur. Ceram. Soc., 35(2015), No. 6, p. 1879.
[10]	Y.J. Zhou, W.H. Yuan, Q.L. Huang, W.Z. Huang, H.F. Cheng, and H.T. Liu, Effect of Y₂O₃ addition on the phase composition and crystal growth behavior of YSZ nanocrystals prepared via coprecipitation process, Ceram. Int., 41(2015), No. 9, p. 10702.
[11]	C.W. Kuo, Y.H. Shen, I.M. Hung, S.B. Wen, H.E. Lee, and M.C. Wang, Effect of Y₂O₃ addition on the crystal growth and sintering behavior of YSZ nanopowders prepared by a sol-gel process, J. Alloys Compd., 472(2009), No. 1-2, p. 186.
[12]	S.G. Chen, Y.S. Yin, D.P. Wang, and J. Li, Reduced activation energy and crystalline size for yttria-stabilized zirconia nano-crystals:an experimental and theoretical study, J. Cryst. Growth, 267(2004), No. 1-2, p. 100.
[13]	Y.H. Lee, C.W. Kuo, I.M. Hung, K.Z. Fung, and M.C. Wang, The thermal behavior of 8mol% yttria-stabilized zirconia nanocrystallites prepared by a sol-gel process, J. Non-Cryst. Solids, 351(2005), No. 49, p. 3709.
[14]	H.L. Chu, W.S. Hwang, J.K. Du, K.K. Chen, and M.C. Wang, Effect of SrO addition on the growth behavior of ZrO₂-3Y₂O₃ precursor powders synthesized by a coprecipitation process, Ceram. Int., 42(2016), No. 8, p. 10251.
[15]	A. Loganathan and A.S. Gandhi, Fracture toughness of t' ZrO₂ stabilised with MO_1.5(M=Y, Yb&Gd) for thermal barrier application, Trans. Indian Inst. Met., 64(2011), No. 1, p. 71.
[16]	Y.B. Khollam, A.S. Deshpande, A.J. Patil, H.S. Potdar, S.B. Deshpande, and S.K. Date, Synthesis of yttria stabilized cubic zirconia (YSZ) powders by microwave-hydrothermal route, Mater. Chem. Phys., 71(2001), No. 3, p. 235.
[17]	Isabel Gonzalo, B. Ferrari, and M.T. Colomer, Influence of the urea content on the YSZ hydrothermal synthesis under dilute conditions and its role as dispersant agent in the post-reaction medium, J. Eur. Ceram. Soc., 29(2009), No. 15, p. 3185.
[18]	Q.L. Huang, W.H. Yuan, W.Z. Huang, H.F. Cheng, Y.J. Zhou, and H.T. Liu, Effect of organic additions on the phase composition and crystal growth behavior of 8wt% yttria-stabilized zirconia nanocrystals prepared via sol-gel process, J. Sol-Gel Sci. Technol., 74(2015), No. 2, p. 432.
[19]	C. Suciu, A.C. Hoffmann, A. Vik, and F. Goga, Effect of calcination conditions and precursor proportions on the properties of YSZ nanoparticles obtained by modified sol-gel route, Chem. Eng. J., 138(2008), No. 1-3, p. 608.
[20]	J.A. Wang, M.A. Valenzuela, J. Salmones, A. Vázquez, A. Garcia-Ruiz, and X. Bokhimi, Comparative study of nanocrystalline zirconia prepared by precipitation and sol-gel methods, Catal. Today, 68(2001), No. 1-3, p. 21.
[21]	P.K. Sharma, R. Nass, and H. Schmidt, Effect of solvent, host precursor, dopant concentration and crystallite size on the fluorescence properties of Eu (Ⅲ) doped yttria, Opt. Mater., 10(1998), No. 2, p. 161.
[22]	K. Richardson and M. Akinc, Preparation of spherical yttrium oxide powders using emulsion evaporation, Ceram. Int., 13(1987), No. 4, p. 253.
[23]	T. Lopez, E. Sanchez, P. Bosch, Y. Meas, and R. Gomez, FTIR and UV-Vis (diffuse reflectance) spectroscopic characterization of TiO₂ sol-gel, Mater. Chem. Phys., 32(1992), No. 2, p. 141.
[24]	H.E. Lee, J.K. Du, Y.Y. Sie, C.H. Wang, J.H. Wu, C.L. Wang, W.S. Hwang, H.H. Huang, W.L. Li, and M.C. Wang, Thermal properties and phase transformation of 2mol% Y₂O₃-PSZ nanopowders prepared by a Co-precipitation process, J. Non-Cryst. Solids, 357(2011), No. 10, p. 2103.
[25]	S. Shukla, S. Seal, R. Vij, and S. Bandyopadhyay, Reduced activation energy for grain growth in nanocrystalline yttria-stabilized zirconia, Nano Lett., 3(2003), No. 3, p. 397.
[26]	S.M. Ho, On the structural chemistry of zirconium oxide, Mater. Sci. Eng., 54(1982), No. 1, p. 23.
[27]	Y.W. Hsu, K.H. Yang, K.M. Chang, S.W. Yeh, and M.C. Wang, Synthesis and crystallization behavior of 3mol% yttria stabilized tetragonal zirconia polycrystals (3Y-TZP) nanosized powders prepared using a simple co-precipitation process, J. Alloys Compd., 509(2011), No. 24, p. 6864.
[28]	T. Chraska, A.H. King, and C.C. Berndt, On the size-dependent phase transformation in nanoparticulate zirconia, Mater. Sci. Eng. A, 286(2000), No. 1, p. 169.
[29]	R.C. Garvie, R.H. Hannink, and R.T. Pascoe, Ceramic steel?, Nature, 258(1975), p. 703.
[30]	D.J. Kim, H.J. Jung, and I.S. Yang, Raman spectroscopy of tetragonal zirconia solid solution, J. Am. Ceram. Soc., 76(1993), No. 8, p. 2106.
[31]	L. Qu and K.L. Choy, Thermophysical and thermochemical properties of new thermal barrier materials based on Dy₂O₃-Y₂O₃ co-doped zirconia, Ceram. Int., 40(2014), No. 8, p. 11593.
[32]	X.Q. Niu, M. Xie, F. Zhou, R.D. Mu, X.W. Song, and S.L. An, Substituent influence of yttria by gadolinia on the tetragonal phase stability for Y₂O₃-Ta₂O₅-ZrO₂ ceramics at 1300℃, J. Mater. Sci. Technol., 30(2014), No. 4, p. 381.
[33]	A.M. Limarga, J. Iveland, M. Gentleman, D.M. Lipkin, and D.R. Clarke, The use of Larson-Miller parameters to monitor the evolution of Raman lines of tetragonal zirconia with high temperature aging, Acta Mater., 59(2011), No. 3, p. 1162.
[34]	C.H. Wang, M.C. Wang, J.K. Du, Y.Y. Sie, C.S. Hsi, and H.E. Lee, Phase transformation and nanocrystallite growth behavior of 2mol% yttria-partially stabilized zirconia (2Y-PSZ) powders, Ceram. Int., 39(2013), No. 5, p. 5165.
[35]	C.W. Kuo, K.C. Lee, F.L. Yen, Y.H. Shen, H.E. Lee, S.B. Wen, M.C. Wang, and M.M. Stack, Growth kinetics of tetragonal and monoclinic ZrO₂ crystallites in 3mol% yttria partially stabilized ZrO₂(3Y-PSZ) precursor powder, J. Alloys Compd., 592(2014), p. 288.

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Phase transformation and crystal growth behavior of 8mol% (SmO_1.5, GdO_1.5, and YO_1.5) stabilized ZrO₂ powders

中文摘要

Phase transformation and crystal growth behavior of 8mol% (SmO_1.5, GdO_1.5, and YO_1.5) stabilized ZrO₂ powders

Abstract

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