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Volume 24 Issue 8
Aug.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(8): 876-883
Lei Tian, Yan Liu, Jun-jie Tang, Guo-zhi Lü,  and Ting-an Zhang, Variation law of gas holdup in an autoclave during the pressure leaching process by using a mixed-flow agitator, Int. J. Miner. Metall. Mater., 24(2017), No. 8, pp. 876-883. https://doi.org/10.1007/s12613-017-1473-7
Cite this article as:
Lei Tian, Yan Liu, Jun-jie Tang, Guo-zhi Lü,  and Ting-an Zhang, Variation law of gas holdup in an autoclave during the pressure leaching process by using a mixed-flow agitator, Int. J. Miner. Metall. Mater., 24(2017), No. 8, pp. 876-883. https://doi.org/10.1007/s12613-017-1473-7
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研究论文

Variation law of gas holdup in an autoclave during the pressure leaching process by using a mixed-flow agitator

  • Key Laboratory of Ecological Utilization of Multi-Metal Intergrown Ores of the Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China

  • School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

  • 通讯作者:

    Ting-an Zhang    E-mail: zta2000@163.net

  • The multiphase reaction process of pressure leaching is mainly carried out in the liquid phase. Therefore, gas holdup is essential for the gas-liquid-solid phase reaction and the extraction rate of valuable metals. In this paper, a transparent quartz autoclave, a six blades disc turbine-type agitator, and a high-speed camera were used to investigate the gas holdup of the pressure leaching process. Furthermore, experiments determining the effects of agitation rate, temperature, and oxygen partial pressure on gas holdup were carried out. The results showed that when the agitation rate increased from 350 to 600 r/min, the gas holdup increased from 0.10% to 0.64%. When the temperature increased from 363 to 423 K, the gas holdup increased from 0.14% to 0.20%. When the oxygen partial pressure increased from 0.1 to 0.8 MPa, the gas holdup increased from 0.13% to 0.19%. A similar criteria relationship was established by Homogeneous Principle and Buckingham's theorem. Comprehensively, empirical equation of gas holdup was deduced on the basis of experimental data and the similarity theory, where the criterion equation was determined as ε=4.54×10-11n3.65Pg0.18. It can be seen from the formula that agitation rate made the most important impact on gas holdup in the pressure leaching process using the mixed-flow agitator.
    • Research Article

    Variation law of gas holdup in an autoclave during the pressure leaching process by using a mixed-flow agitator

    + Author Affiliations
      Abstract
    • The multiphase reaction process of pressure leaching is mainly carried out in the liquid phase. Therefore, gas holdup is essential for the gas-liquid-solid phase reaction and the extraction rate of valuable metals. In this paper, a transparent quartz autoclave, a six blades disc turbine-type agitator, and a high-speed camera were used to investigate the gas holdup of the pressure leaching process. Furthermore, experiments determining the effects of agitation rate, temperature, and oxygen partial pressure on gas holdup were carried out. The results showed that when the agitation rate increased from 350 to 600 r/min, the gas holdup increased from 0.10% to 0.64%. When the temperature increased from 363 to 423 K, the gas holdup increased from 0.14% to 0.20%. When the oxygen partial pressure increased from 0.1 to 0.8 MPa, the gas holdup increased from 0.13% to 0.19%. A similar criteria relationship was established by Homogeneous Principle and Buckingham's theorem. Comprehensively, empirical equation of gas holdup was deduced on the basis of experimental data and the similarity theory, where the criterion equation was determined as ε=4.54×10-11n3.65Pg0.18. It can be seen from the formula that agitation rate made the most important impact on gas holdup in the pressure leaching process using the mixed-flow agitator.
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      • References(22)
    • [1]
      W.E. Cooper and D.B. Dreisinger, Hydrometallurgy:Theory and Practice, Elsevier Science Publishers, Amsterdam, 1992, p. 52.
      [2]
      R.J. Ma, New development of hydrometallurgy, Hydrometall. China, 26(2007), No. 1, p. 1.
      [3]
      F. Haboxi, Pressure hydrometallurgy, Metallic Ore Dressing Abroad, 2006, No. 11, p. 10.
      [4]
      Y. Liu, T.A. Zhang, Q.Y. Zhao, S.C. Wang, X.D. Ren, Z.H. Dou, and J.C. He, Experimental research on gas holdup in bubble disintegration process, Chin. J. Process Eng., 9(2009), Suppl. 1, p. 97.
      [5]
      Y.C. Chen, Design of Mixing Equipment, Shanghai Science and Technology Press, Shanghai, 1985, p. 19.
      [6]
      J.Y. Oldshue, Fluid Mixing Technology, Chemical Industry Press, Beijing, 1991, p. 45.
      [7]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Mechanism of bubble disintegration and dispersion by mechanical stirring in gas injection refining,[in] ISIJ Meeting, Tokyo, 2009, p. 54.
      [8]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Calculation and analysis on volumetric mass transfer coefficient in cold water model of refining process,[in] The 5th International Conference on Hydrometallurgy, Zhangjiajie, 2009, p. 65.
      [9]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Bubble disintegrationand dispersion by eccentric mechanical stirring in gas injection refining for iron and steel making,[in] The Third Baosteel Academic Conference, Shanghai, 2008, p. 65.
      [10]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Eccentric mechanical stirring for bubble disintegration,[in] ISIJ Meeting, Hokkaido, 2008, p. 7.
      [11]
      A.H. Gadallah and K. Siddiqui, Bubble breakup in co-current upward flowing liquid using honeycomb monolith breaker, Chem. Eng. Sci., 131(2015), p. 22.
      [12]
      K. Fukushi and M. Iguchi, Wettability effect on a single bubble rising in stagnant water contained in a vertical circular pipe, ISIJ Int., 46(2006), No.5, p. 647.
      [13]
      M. Iguchi, M. Kaji, and Z. Morita, Effects of pore diameter, bath surface pressure, and nozzle diameter on the bubble formation from a porous nozzle, Metall. Mater. Trans. B, 29(1998), No. 6, p. 1209.
      [14]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Perforated blade impeller for bubble disintegration and dispersion,[in] ISIJ Meeting, Osaka, 2008, p. 8.
      [15]
      Y. Liu, T.A. Zhang, S. Masamichi, and J.C. He, Gas holdupunder mechanical stirring in gas injection refining process,[in] ISIJ Meeting, Fukuoka, 2009, p. 98.
      [16]
      H.M. Letzel, J.C. Schouten, C.M. van den Bleek, and R. Kshna, Influence of elevated pressure on the stability of bubbly flows, Chem. Eng. Sci., 52(1997), No. 21-22, p. 3733.
      [17]
      Y. Liu, M. Sano, T.A. Zhang, Q. Wang, and J.C. He, Intensification of bubble disintegration and dispersion by mechanical stirring in gas injection refining, ISIJ Int., 49(2009), No. 1, p. 17.
      [18]
      D. Tromans, Temperature and pressure dependent solubility of oxygen in water:a thermodynamic analysis, Hydrometallurgy, 48(1998), No. 3, p. 327.
      [19]
      T. Kaskiala, Determination of oxygen solubility in aqueous sulphuric acid media, Miner. Eng., 15(2002), No. 11, p. 853.
      [20]
      Y. Liu, Y.D. Li, T.A. Zhang, and N.X. Feng, Research on the penetration depth in aluminum reduction cell with new type of anode and cathode structures, JOM, 66(2014), No.7, p.1202.
      [21]
      Z. Zhang, The Principle of Dimensional Analysis, People's Railway Press, Beijing, 1979, p. 157.
      [22]
      Y. Liu, T.A. Zhang, Q. Wang, W.M. Yao, M. Sano, and J.C. He, Dimension analysis theory in the application of fluid mechanics, Ind. Furnace, 29(2007), No. 6, p. 9.
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