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Volume 24 Issue 10
Oct.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(10): 1183-1191
Jian-zheng Song, Zi-yang Zhao, Xin Zhao, Rui-dong Fu, and Shu-min Han, Hydrogen storage properties of MgH2 co-catalyzed by LaH3 and NbH, Int. J. Miner. Metall. Mater., 24(2017), No. 10, pp. 1183-1191. https://doi.org/10.1007/s12613-017-1509-z
Cite this article as:
Jian-zheng Song, Zi-yang Zhao, Xin Zhao, Rui-dong Fu, and Shu-min Han, Hydrogen storage properties of MgH2 co-catalyzed by LaH3 and NbH, Int. J. Miner. Metall. Mater., 24(2017), No. 10, pp. 1183-1191. https://doi.org/10.1007/s12613-017-1509-z
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研究论文Open Access

Hydrogen storage properties of MgH2 co-catalyzed by LaH3 and NbH

  • State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China

  • College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China

  • 通讯作者:

    Shu-min Han    E-mail: hanshm@ysu.edu.cn

  • To improve the hydrogen storage properties of Mg-based alloys, a composite material of MgH2 + 10wt%LaH3 + 10wt%NbH was prepared by a mechanical milling method. The composite exhibited favorable hydrogen desorption properties, releasing 0.67wt% H2 within 20 min at 548 K, which was ascribed to the co-catalytic effect of LaH3 and NbH upon dehydriding of MgH2. By contrast, pure MgH2, an MgH2 + 20wt%LaH3 composite, and an MgH2 + 20wt%NbH composite only released 0.1wt%, 0.28wt%, and 0.57wt% H2, respectively, under the same conditions. Analyses by X-ray diffraction and scanning electron microscopy showed that the composite particle size was small. Energy-dispersive X-ray spectroscopic mapping demonstrated that La and Nb were distributed homogeneously in the matrix. Differential thermal analysis revealed that the dehydriding peak temperature of the MgH2 + 10wt%LaH3 + 10wt%NbH composite was 595.03 K, which was 94.26 K lower than that of pure MgH2. The introduction of LaH3 and NbH was beneficial to the hydrogen storage performance of MgH2.
    • Research ArticleOpen Access

    Hydrogen storage properties of MgH2 co-catalyzed by LaH3 and NbH

    + Author Affiliations
      Abstract
    • To improve the hydrogen storage properties of Mg-based alloys, a composite material of MgH2 + 10wt%LaH3 + 10wt%NbH was prepared by a mechanical milling method. The composite exhibited favorable hydrogen desorption properties, releasing 0.67wt% H2 within 20 min at 548 K, which was ascribed to the co-catalytic effect of LaH3 and NbH upon dehydriding of MgH2. By contrast, pure MgH2, an MgH2 + 20wt%LaH3 composite, and an MgH2 + 20wt%NbH composite only released 0.1wt%, 0.28wt%, and 0.57wt% H2, respectively, under the same conditions. Analyses by X-ray diffraction and scanning electron microscopy showed that the composite particle size was small. Energy-dispersive X-ray spectroscopic mapping demonstrated that La and Nb were distributed homogeneously in the matrix. Differential thermal analysis revealed that the dehydriding peak temperature of the MgH2 + 10wt%LaH3 + 10wt%NbH composite was 595.03 K, which was 94.26 K lower than that of pure MgH2. The introduction of LaH3 and NbH was beneficial to the hydrogen storage performance of MgH2.
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    • [1]
      D. Mori and K. Hirose, Recent challenges of hydrogen storage technologies for fuel cell vehicles, Int. J. Hydrogen Energy, 34(2009), No. 10, p. 4569.
      [2]
      L.C. Pei, S.M. Han, J.S. Wang, L. Hu, X. Zhao, and B.Z. Liu, Hydrogen storage properties and phase structures of RMg2Ni (R=La, Ce, Pr, Nd) alloys, Mater. Sci. Eng. B, 177(2012), No. 18, p. 1589.
      [3]
      B. Sakintuna, F. Lamari-Darkrim, and M. Hirscher, Metal hydride materials for solid hydrogen storage:A review, Int. J. Hydrogen Energy, 32(2007), No. 9, p. 1121.
      [4]
      W. Zhao, V. Fierro, N. Fernández-Huerta, M.T. Izquierdo, and A. Celzard, Impact of synthesis conditions of KOH activated carbons on their hydrogen storage capacities, Int. J. Hydrogen Energy, 37(2012), No. 19, p. 14278.
      [5]
      M. Au, Hydrogen storage properties of magnesium based nanostructured composite materials, Mater. Sci. Eng. B, 117(2005), No. 1, p. 37.
      [6]
      H.W. Dong, L.Z. Ou Yang, T. Sun, and M. Zhu, Effect of ball milling on hydrogen storage of Mg3La alloy, J. Rare Earths, 26(2008), No. 2, p. 303.
      [7]
      M. Abdellatief, R. Campostrini, M. Leoni, and P. Scardi, Effects of SnO2 on hydrogen desorption of MgH2, Int. J. Hydrogen Energy, 38(2013), No. 11, p. 4664.
      [8]
      P. Pei, X.P. Song, J. Liu, A.N. Song, P.L. Zhang, and G.L. Chen, Study on the hydrogen desorption mechanism of a Mg-V composite prepared by SPS, Int. J. Hydrogen Energy, 37(2012), No. 1, p. 984.
      [9]
      J.R. Ares, F. Leardini, P. Díaz-Chao, J. Bodega, D.W. Koon, I.J. Ferrer, J.F. Fernández, and C. Sánchez, Hydrogen desorption in nanocrystalline MgH2 thin films at room temperature, J. Alloys Compd., 495(2010), No. 2, p. 650.
      [10]
      L.P. Ma, P. Wang, and H.M. Cheng, Improving hydrogen sorption kinetics of MgH2 by mechanical milling with TiF3, J. Alloys Compd., 432(2007), No. 1-2, p. 1.
      [11]
      M. Zhu, Y.S. Lu, L.Z. Ouyang, and H. Wang, Thermodynamic tuning of Mg-based hydrogen storage alloys:a review, Materials, 6(2013), No. 10, p. 4654.
      [12]
      M. Tian and C.X. Shang, Effect of TiC and Mo2C on hydrogen desorption of mechanically milled MgH2, J. Chem. Sci. Technol., 1(2012), p. 54.
      [13]
      H. Wang, S.F. Zhang, J.W. Liu, L.Z. Ou Yang, and M. Zhu, Enhanced dehydrogenation of nanoscale MgH2 confined by ordered mesoporous silica, Mater. Chem. Phys., 136(2012), No. 1, p. 146.
      [14]
      D.W. Zhou, P. Peng, J.S. Liu, L. Chen, and Y.J. Hu, First-principles study on structural stability of 3d transition metal alloying magnesium hydride, Trans. Nonferrous Met. Soc. China, 16(2006), No. 1, p. 23.
      [15]
      M.D. Riktor, S. Deledda, M. Herrich, O. Gutfleisch, H. Fjellvåg, and B.C. Hauback, Hydride formation in ball-milled and cryomilled Mg-Fe powder mixtures, Mater. Sci. Eng. B, 158(2009), No. 1-3, p. 19.
      [16]
      S. Milošević, Z. Rašković-Lovre, S. Kurko, R. Vujasin, N. Cvjetićanin, L. Matović, and J.G. Novaković, Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride, Ceram. Int., 39(2013), No. 1, p. 51.
      [17]
      Y.H. Jia, S.M. Han, W. Zhang, X. Zhao, P.F. Sun, Y.Q. Liu, H. Shi, and J.S. Wang, Hydrogen absorption and desorption kinetics of MgH2 catalyzed by MoS2 and MoO2, Int. J. Hydrogen Energy, 38(2013), No. 5, p. 2352.
      [18]
      S.A. Jin, J.H. Shim, Y.W. Cho, and K.W. Yi, Dehydrogenation and hydrogenation characteristics of MgH2 with transition metal fluoride, J. Power Sources, 172(2007), No. 2, p. 859.
      [19]
      I.E. Malka, M. Pisarek, T. Czujko, and J. Bystrzycki, A study of the ZrF4, NbF5, TaF5, and TiCl3 influences on the MgH2 sorption properties, Int. J. Hydrogen Energy, 36(2011), No. 20, p. 12909.
      [20]
      R.K. Singh, T. Sadhasivam, G.I. Sheeja, P. Singh, and O.N. Srivastava, Effect of different sized CeO2 nano particles on decomposition and hydrogen absorption kinetics of magnesium hydride, Int. J. Hydrogen Energy, 38(2013), No. 14, p. 6221.
      [21]
      R. Gupta, F. Agresti, S.L. Russo, A. Maddalena, P. Palade, and G. Principi, Structure and hydrogen storage properties of MgH2 catalysed with La2O3, J. Alloys Compd., 450(2008), No. 1-2, p. 310.
      [22]
      R.R. Shahi, A.P. Tiwari, M.A. Shaz, and O.N. Srivastava, Studies on de/rehydrogenation characteristics of nanocrystalline MgH2 co-catalyzed with Ti, Fe and Ni, Int. J. Hydrogen Energy, 38(2013), No. 6, p. 2778.
      [23]
      H. Wang, H.J. Lin, W.T. Cai, L.Z. Ou Yang, and M.S. Zhu, Tuning kinetics and thermodynamics of hydrogen storage in light metal element based systems-a review of recent progress, J. Alloys Compd., 658(2016), p. 280.
      [24]
      X.Z. Xiao, C.C. Xu, J. Shao, L.T. Zhang, T. Qin, S.Q. Li, H.W. Ge, Q.D. Wang, and L.X. Chen, Remarkable hydrogen desorption properties and mechanisms of the Mg2FeH6@MgH2 core-shell nanostructure, J. Mater. Chem. A, 3(2015), No. 10, p. 5517.
      [25]
      H. Xue, X.Z. Xiao, J. Shao, B. Zhai, X.L. Fan, C.J. Cheng, S.Q. Li, H.W. Ge, Q.D. Wang, and L.X. Chen, Building robust architectures of carbon wrapped transition metal nanoparticles toward high-catalytic enhancement of 2LiBH4-MgH2 system for hydrogen storage cycling performances, Nanoscale, 8(2016), p. 14898.
      [26]
      K. Wang, H.F. Du, Z.Y. Wang, M.X. Gao, H.G. Pan, and Y.F. Liu, Novel MAX-phase Ti3AlC2 catalyst for improving the reversible hydrogen storage properties of MgH2, Int. J. Hydrogen Energy, 42(2017), p. 4244.
      [27]
      Y.F. Liu, H.F. Du, X. Zhang, Y.X. Yang, M.X. Gao, and H.G. Pan, Superior catalytic activity derived from a two-dimensional Ti3C2 precursor towards the hydrogen storage reaction of magnesium hydride, Chem. Commun., 52(2016), No. 4, p. 705.
      [28]
      X.Z. Xiao, Z. Liu, S.S. Yarahmadi, and D.H. Gregory, Facile preparation of β-/γ-MgH2 nanocomposites under mild conditions and pathways to rapid dehydrogenation, Phys. Chem. Chem. Phys., 18(2016), No. 15, p. 10492.
      [29]
      Y. Li, Y. Tao, and Q. Huo, Effect of stoichiometry and Cu-substitution on the phase structure and hydrogen storage properties of Ml-Mg-Ni-based alloys, Int. J. Miner. Metall. Mater., 22(2015), No. 1, p. 86.
      [30]
      X.L. Zhu, L.C. Pei, Z.Y. Zhao, B.Z. Liu, S.M. Han, and R.B. Wang, The catalysis mechanism of La hydrides on hydrogen storage properties of MgH2 in MgH2+xwt% LaH3(x=0, 10, 20, and 30) composites, J. Alloys Compd., 577(2013), p. 64.
      [31]
      X. Zhao, S.M. Han, Y. Li, X.C. Chen, and D.D. Ke, Effect of CeH2.29 on the microstructures and hydrogen properties of LiBH4-Mg2NiH4 composites, Int. J. Miner. Metall. Mater., 22(2015), No. 4, p. 423.
      [32]
      M.O.T. da Conceição, M.C. Brum, D.S. dos Santos, and M.L. Dias, Hydrogen sorption enhancement by Nb2O5 and Nb catalysts combined with MgH2, J. Alloys Compd., 550(2013), p. 179.
      [33]
      S.A. Jin, J.H. Shim, J.P. Ahn, Y.W. Cho, and K.W. Yi, Improvement in hydrogen sorption kinetics of MgH2 with Nb hydride catalyst, Acta Mater., 55(2007), No. 15, p. 5073.
      [34]
      L.T. Zhang, X.Z. Xiao, C.C. Xu, J.G. Zheng, X.L. Fan, J. Shao, S.Q. Li, H.W. Ge, Q.D. Wang, and L.X. Chen, Remarkably improved hydrogen storage performance of MgH2 catalyzed by multi-valence NbHx nanoparticles, J. Phys. Chem. C, 119(2015), No. 16, p. 8554.
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