留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 25 Issue 2
Feb.  2018
数据统计

分享

计量
  • 文章访问数:  643
  • HTML全文浏览量:  117
  • PDF下载量:  18
  • 被引次数: 0
Long Meng, Zhe Wang, Yi-wei Zhong, Kui-yuan Chen,  and Zhan-cheng Guo, Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 173-180. https://doi.org/10.1007/s12613-018-1560-4
Cite this article as:
Long Meng, Zhe Wang, Yi-wei Zhong, Kui-yuan Chen,  and Zhan-cheng Guo, Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 173-180. https://doi.org/10.1007/s12613-018-1560-4
引用本文 PDF XML SpringerLink
研究论文

Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures

  • 通讯作者:

    Zhan-cheng Guo    E-mail: zcguo@ustb.edu.cn

  • Printed circuit boards (PCBs) contain many toxic substances as well as valuable metals, e.g., lead (Pb) and tin (Sn). In this study, a novel technology, named supergravity, was used to separate different mass ratios of Pb and Sn from Pb-Sn alloys in PCBs. In a supergravity field, the liquid metal phase can permeate from solid particles. Hence, temperatures of 200, 280, and 400℃ were chosen to separate Pb and Sn from PCBs. The results depicted that gravity coefficient only affected the recovery rates of Pb and Sn, whereas it had little effect on the mass ratios of Pb and Sn in the obtained alloys. With an increase in gravity coefficient, the recovery values of Pb and Sn in each step of the separation process increased. In the single-step separation process, the mass ratios of Pb and Sn in Pb-Sn alloys were 0.55, 0.40, and 0.64 at 200, 280, and 400℃, respectively. In the two-step separation process, the mass ratios were 0.12 and 0.55 at 280 and 400℃, respectively. Further, the mass ratio was observed to be 0.76 at 400℃ in the three-step separation process. This process provides an innovative approach to the recycling mechanism of Pb and Sn from PCBs.
  • Research Article

    Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures

    + Author Affiliations
    • Printed circuit boards (PCBs) contain many toxic substances as well as valuable metals, e.g., lead (Pb) and tin (Sn). In this study, a novel technology, named supergravity, was used to separate different mass ratios of Pb and Sn from Pb-Sn alloys in PCBs. In a supergravity field, the liquid metal phase can permeate from solid particles. Hence, temperatures of 200, 280, and 400℃ were chosen to separate Pb and Sn from PCBs. The results depicted that gravity coefficient only affected the recovery rates of Pb and Sn, whereas it had little effect on the mass ratios of Pb and Sn in the obtained alloys. With an increase in gravity coefficient, the recovery values of Pb and Sn in each step of the separation process increased. In the single-step separation process, the mass ratios of Pb and Sn in Pb-Sn alloys were 0.55, 0.40, and 0.64 at 200, 280, and 400℃, respectively. In the two-step separation process, the mass ratios were 0.12 and 0.55 at 280 and 400℃, respectively. Further, the mass ratio was observed to be 0.76 at 400℃ in the three-step separation process. This process provides an innovative approach to the recycling mechanism of Pb and Sn from PCBs.
    • loading
    • [1]
      P.K. Choubey, R. Panda, M.K. Jha, J.C. Lee, and D.D. Pathak, Recovery of copper and recycling of acid from the leach liquor of discarded Printed Circuit Boards (PCBs), Sep. Purif. Technol.,156(2015), p. 269.
      [2]
      M.K. Jha, A. Kumari, P.K. Choubey, J.C. Lee, V. Kumar, and J. Jeong, Leaching of lead from solder material of waste printed circuit boards (PCBs), Hydrometallurgy, 121-124(2012), p. 28.
      [3]
      L.S. Long, S.Y. Sun, S. Zhong, W.C. Dai, J.Y. Liu, and W.F. Song, Using vacuum pyrolysis and mechanical processing for recycling waste printed circuit boards, J. Hazard. Mater., 177(2010), No. 1-3, p. 626.
      [4]
      Y.H. Zhou and K.Q. Qiu, A new technology for recycling materials from waste printed circuit boards, J. Hazard. Mater., 175(2010), No. 1-3, p. 823.
      [5]
      G. Bidini, F. Fantozzi, P. Bartocci, B. D'Alessandro, M. D'Amico, P. Laranci, E. Scozza, and M. Zagaroli, Recovery of precious metals from scrap printed circuit boards through pyrolysis, J. Anal. Appl. Pyrolysis, 111(2015), p. 140.
      [6]
      A. Kumari, M.K. Jha, J.C. Lee, and R.P. Singh, Clean process for recovery of metals and recycling of acid from the leach liquor of PCBs, J. Cleaner Prod., 112(2016), p. 4826.
      [7]
      M.J. Chen, J.X. Huang, O.A. Ogunseitan, N.M. Zhu, and Y.M. Wang, Comparative study on copper leaching from waste printed circuit boards by typical ionic liquid acids, Waste Manage., 41(2015), p. 142.
      [8]
      J.G. Yang, Y.T. Wu, and J. Li, Recovery of ultrafine copper particles from metal components of waste printed circuit boards, Hydrometallurgy, 121-124(2012), p. 1.
      [9]
      Y.K. Yang, S. Chen, S.C. Li, M.J. Chen, H.Y. Chen, and B.J. Liu, Bioleaching waste printed circuit boards by Acidithiobacillus ferrooxidans and its kinetics aspect, J. Biotechnol., 173(2014), p. 24.
      [10]
      T. Yang, Z. Xu, J.K. Wen, and L.M. Yang, Factors influencing bioleaching copper from waste printed circuit boards by acidithiobacillus ferrooxidans, Hydrometallurgy, 97(2009), No. 1, p. 29.
      [11]
      G.B. Liang, Y.W. Mo, and Q.F. Zhou, Novel strategies of bioleaching metals from printed circuit boards (PCBs) in mixed cultivation of two acidophiles, Enzyme Microb. Technol., 47(2010), No. 7, p. 322.
      [12]
      H.M. Veit, T.R. Diehl, A.P. Salami, J.S. Rodrigues, A.M. Bernardes, and J.A.S. Tenório, Utilization of magnetic and electrostatic separation in the recycling of printed circuit boards scrap, Waste Manage., 25(2005), No. 1, p. 67.
      [13]
      C. Eswaraiah, T. Kavitha, S. Vidyasagar, and S.S. Narayanan, Classification of metals and plastics from printed circuit boards (PCB) using air classifier, Chem. Eng. Process., 47(2008), No. 4, p. 565.
      [14]
      J. Wu, J. Li, and Z.M. Xu, A new two-roll electrostatic separator for recycling of metals and nonmetals from waste printed circuit board, J. Hazard. Mater., 161(2009), No. 1, p. 257.
      [15]
      Y.H. Zhou, W.B. Wu, and K.Q. Qiu, Recovery of materials from waste printed circuit boards by vacuum pyrolysis and vacuum centrifugal separation, Waste Manage., 30(2010), No. 11, p. 2299.
      [16]
      J.C. Li, Z.C. Guo, and J.T. Gao, Assessment of super-gravity concentrating V-containing spinel phase from vanadium slag, High Temp. Mater. Processes, 34(2015), No. 1, p. 61.
      [17]
      J.C. Li and Z.C. Guo, Innovative methodology to enrich britholite (Ca3Ce2[(Si,P)O4]3F) phase from rare-earth-rich slag by super gravity, Metall. Mater. Trans. B, 45(2014), No. 4, p. 1272.
      [18]
      J.C. Li, Z.C. Guo, and J.T. Gao, Isothermal enriching perovskite phase from CaO-TiO2-SiO2-Al2O3-MgO melt by super gravity, ISIJ Int., 54(2014), No. 4, p. 743.
      [19]
      Y. Xie, C.M. Liu, Y.B. Zhai, K. Wang, and X.D. Ling, Centrifugal casting processes of manufacturing in situ functionally gradient composite materials of Al-19Si-5Mg alloy, Rare Met., 28(2009), No. 4, p. 405.
      [20]
      M.R. Rahimipour and M. Sobhani, Evaluation of centrifugal casting process parameters for in situ fabricated functionally gradient Fe-TiC composite, Metall. Mater. Trans. B, 44(2013), No. 5, p. 1120.
      [21]
      Y. Watanabe, M. Kurahashi, I.S. Kim, S. Miyazaki, S. Kumai, A. Sato, and S.I. Tanaka, Fabrication of fiber-reinforced functionally graded materials by a centrifugal in situ method from Al-Cu-Fe ternary alloy, Composites Part A, 37(2006), No. 12, p. 2186.
      [22]
      J.W. Li, Z.C. Guo, H.Q. Tang, Z. Wang, and S.T. Sun, Si purification by solidification of Al-Si melt with super gravity, Trans. Nonferrous Met. Soc. China, 22(2012), No. 4, p. 958.
      [23]
      G.Y. Song, B. Song, Y.H. Yang, Z.B. Yang, and W.B. Xin, Separating behavior of nonmetallic inclusions in molten aluminum under super-gravity field, Metall. Mater. Trans. B, 46(2015), No. 5, p. 2190.
      [24]
      J.W. Li, Z.C. Guo, J.C. Li, and L.Z. Yu, Super gravity separation of purified Si from solvent refining with the Al-Si alloy system for solar grade silicon, Silicon, 7(2015), No. 3, p. 239.
      [25]
      X.L. Zeng, J.H. Li, H.H. Xie, and L.L. Liu, A novel dismantling process of waste printed circuit boards using water-soluble ionic liquid, Chemosphere, 93(2013), No. 7, p. 1288.
      [26]
      T. Havlik, D. Orac, M. Petranikova, A. Miskufova, F. Kukurugya, and Z. Takacova, Leaching of copper and tin from used printed circuit boards after thermal treatment, J. Hazard. Mater., 183(2010), No. 1-3, p. 866.
      [27]
      C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, Thermodynamic assessment of the Cu-Ni-Pb system, Calphad, 24(2000), No. 2, p. 149.

    Catalog


    • /

      返回文章
      返回