Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel

Prashant Huilgol; K. Rajendra Udupa; K. Udaya Bhat

doi:10.1007/s12613-018-1562-2

Volume 25 Issue 2

Feb. 2018

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文章导航 > 矿物冶金与材料学报（英文） > 2018 > 25(2): 190-198

Prashant Huilgol, K. Rajendra Udupa, and K. Udaya Bhat, Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 190-198. https://doi.org/10.1007/s12613-018-1562-2

Cite this article as:

Prashant Huilgol, K. Rajendra Udupa, and K. Udaya Bhat, Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 190-198. https://doi.org/10.1007/s12613-018-1562-2

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研究论文

Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel

Department of Metallurgical & Materials Engineering, National Institute of Technology Karnataka, Surathkal, Mangalore-575025, India

通讯作者:
Prashant Huilgol E-mail: prashanthuilgol@gmail.com

中文摘要

Hot-dip aluminizing (HDA) is a proven surface coating technique for improving the oxidation and corrosion resistance of ferrous substrates. Although extensive studies on the HDA of plain carbon steels have been reported, studies on the HDA of stainless steels are limited. Because of the technological importance of stainless steels in high-temperature applications, studies of their microstructural development during HDA are needed. In the present investigation, the HDA of AISI 321 stainless steel was carried out in a pure Al bath. The microstructural features of the coating were studied using scanning electron microscopy and transmission electron microscopy. These studies revealed that the coating consists of two regions:an Al top coat and an aluminide layer at the interface between the steel and Al. The Al top coat was found to consist of intermetallic phases such as Al₇Cr and Al₃Fe dispersed in an Al matrix. Twinning was observed in both the Al₇Cr and the Al₃Fe phases. Furthermore, the aluminide layer comprised a mixture of nanocrystalline Fe₂Al₅, Al₇Cr, and Al. Details of the microstructural features are presented, and their formation mechanisms are discussed.

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Research Article

Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel

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Abstract

Abstract

Hot-dip aluminizing (HDA) is a proven surface coating technique for improving the oxidation and corrosion resistance of ferrous substrates. Although extensive studies on the HDA of plain carbon steels have been reported, studies on the HDA of stainless steels are limited. Because of the technological importance of stainless steels in high-temperature applications, studies of their microstructural development during HDA are needed. In the present investigation, the HDA of AISI 321 stainless steel was carried out in a pure Al bath. The microstructural features of the coating were studied using scanning electron microscopy and transmission electron microscopy. These studies revealed that the coating consists of two regions:an Al top coat and an aluminide layer at the interface between the steel and Al. The Al top coat was found to consist of intermetallic phases such as Al₇Cr and Al₃Fe dispersed in an Al matrix. Twinning was observed in both the Al₇Cr and the Al₃Fe phases. Furthermore, the aluminide layer comprised a mixture of nanocrystalline Fe₂Al₅, Al₇Cr, and Al. Details of the microstructural features are presented, and their formation mechanisms are discussed.
- hot-dip aluminizing;
- aluminide layer;
- intermetallic phases;
- microstructural features;
- stainless steel

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[1]	F.L. Yang, X. Xiang, G.D. Lu, G.K. Zhang, T. Tang, Y. Shi, and X.L. Wang, Tritium permeation characterization of Al₂O₃/FeAl coatings as tritium permeation barriers on 321 type stainless steel containers, J. Nucl. Mater., 478(2016), p. 144.
[2]	W. Cao, S. Ge, J.F. Song, C.A. Chen, and D.L. Luo, Deuterium permeation barrier by hot-dipping aluminizing on AISI321 steel, Int. J. Hydrogen Energy, 41(2016), No. 48, p. 23125.
[3]	K. Udaya Bhat, Mild Steel Plates:Aluminizing,[in] R. Colás and G. E. Totten Eds. Encyclopedia of Iron, Steel and Their Alloys (Five volume set), CRC Press, Boca Raton, 2016, p. 2274.
[4]	K. Bouché, F. Barbier, and A. Coulet, Intermetallic compound layer growth between solid iron and molten aluminium, Mater. Sci. Eng. A, 249(1998), No. 1-2, p. 167.
[5]	D.Q. Wang and Z.Y. Shi, Aluminizing and oxidation treatment of 1Cr18Ni9 stainless steel, Appl. Surf. Sci., 227(2004), No. 1-4, p. 255.
[6]	W.J. Cheng and C.J. Wang, Growth of intermetallic layer in the aluminide mild steel during hot-dipping, Surf. Coat. Technol., 204(2009), No. 6-7, p. 824.
[7]	W.J. Cheng and C.J. Wang, Microstructural evolution of intermetallic layer in hot-dipped aluminide mild steel with silicon addition, Surf. Coat. Technol., 205(2011), No. 19, p. 4726.
[8]	A. Bouayad, C. Gerometta, A. Belkebir, and A. Ambari, Kinetic interactions between solid iron and molten aluminium, Mater. Sci. Eng. A, 363(2003), No. 1-2, p. 53.
[9]	S. Kobayashi and T. Yakou, Control of intermetallic compound layers at interface between steel and aluminum by diffusion-treatment, Mater. Sci. Eng. A, 338(2002), No. 1-2, p. 44.
[10]	V.I. Dybkov, Solid State Reaction Kinetics, IPMS Publications, Kiev, 2013, p. 311.
[11]	P. Budberg and A. Prince, Aluminium-Iron-Nickel:Ternary Alloys, Edited by G. Petzow and G. Effenberg, VCH, Weinheim, 1991, p. 309.
[12]	M. Palm, The Al-Cr-Fe system-phases and phase equilibria in the Al-rich corner, J. Alloys Compd., 252(1997), No. 1-2, p. 192.
[13]	M.J. Cooper, The structure of the intermetallic phase θ (Cr-Al), Acta Crystallogr., 13(1960), No. 3, p. 257.
[14]	T. Ohnishi, Y. Nakatani, and K. Okabayashi, Crystal structures of intermetallic θ, η and ε phases in Al-Cr system, Bull. Univ. Osaka Prefecture Ser. A, 24(1976), No. 2, p. 183.
[15]	H. Baker and H. Okamoto, ASM Handbook, Vol. 3:Alloy Phase Diagrams, ASM International, Materials Park, Ohio, 1992, p. 2.
[16]	G. Ghosh, K. Korniyenko, T. Velikanova, and V. Sidorko, Aluminium-Chromium-Iron (Iron Systems, Part 1), Springer, Berlin, 2008, p. 1.
[17]	S. Chatterjee T.A. Abinandanan, and K. Chattopadhyay, Phase-field simulation of fusion interface events during solidification of dissimilar welds:effect of composition inhomogeneity, Metall. Mater. Trans. A, 39(2008), No. 7, p. 1638.
[18]	H.R. Shahverdi, M.R. Ghomashchi, S. Shabestari, and J. Hejazi, Microstructural analysis of interfacial reaction between molten aluminium and solid iron, J. Mater. Process. Technol., 124(2002), No. 3, p. 345.
[19]	R.M. Walser and R.W. Bené, First phase nucleation in silicon-transitionmetal planar interfaces, Appl. Phys. Lett., 28(1976), No. 10, p. 624.
[20]	F.M. d'Heurle, Interface reactions with formation of a solid phase on a solid substrate:A short overview, Mater. Sci. Forum, 155-156(1994), p. 1.
[21]	J. Philibert, Interplay of diffusion and interface processes in multiphase diffusion, Defect Diffus. Forum, 95-98(1993), p. 493.
[22]	V.N. Yeremenko, Y.V. Natanzon, and V.I. Dybkov, The effect of dissolution on the growth of the Fe₂Al₅, interlayer in the solid iron-liquid aluminium system, J. Mater. Sci., 16(1981), No. 7, p. 1748.
[23]	N.J.E. Adkins, N. Saunders, and P. Tsakiropoulos, Rapid solidification of peritectic aluminium alloys, Mater. Sci. Eng., 98(1988), p. 217.
[24]	S. Sharafi and M.R. Farhang, Effect of aluminizing on surface microstructure of an HH309 stainless steel, Surf. Coat. Technol., 200(2006), No. 16-17, p. 5048.

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Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel

中文摘要

Formation of microstructural features in hot-dip aluminized AISI 321 stainless steel

Abstract

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