Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

Zhi-yuan Chen; Liu-zhen Bian; Zi-you Yu; Li-jun Wang; Fu-shen Li; Kuo-Chih Chou

doi:10.1007/s12613-018-1565-z

Volume 25 Issue 2

Feb. 2018

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文章导航 > 矿物冶金与材料学报（英文） > 2018 > 25(2): 226-235

Zhi-yuan Chen, Liu-zhen Bian, Zi-you Yu, Li-jun Wang, Fu-shen Li, and Kuo-Chih Chou, Effects of specific surface area of metallic nickel particles on carbon deposition kinetics, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 226-235. https://doi.org/10.1007/s12613-018-1565-z

Cite this article as:

Zhi-yuan Chen, Liu-zhen Bian, Zi-you Yu, Li-jun Wang, Fu-shen Li, and Kuo-Chih Chou, Effects of specific surface area of metallic nickel particles on carbon deposition kinetics, Int. J. Miner. Metall. Mater., 25(2018), No. 2, pp. 226-235. https://doi.org/10.1007/s12613-018-1565-z

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研究论文

Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China
State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China
Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherland
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

通讯作者:
Li-jun Wang E-mail: lijunwang@ustb.edu.cn

中文摘要

Carbon deposition on nickel powders in methane involves three stages in different reaction temperature ranges. Temperature programing oxidation test and Raman spectrum results indicated the formation of complex and ordered carbon structures at high deposition temperatures. The values of I(D)/I(G) of the deposited carbon reached 1.86, 1.30, and 1.22 in the first, second, and third stages, respectively. The structure of carbon in the second stage was similar to that in the third stage. Carbon deposited in the first stage rarely contained homogeneous pyrolytic deposit layers. A kinetic model was developed to analyze the carbon deposition behavior in the first stage. The rate-determining step of the first stage is supposed to be interfacial reaction. Based on the investigation of carbon deposition kinetics on nickel powders from different resources, carbon deposition rate is suggested to have a linear relation with the square of specific surface area of nickel particles.

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Research Article

Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

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Abstract

Abstract

Carbon deposition on nickel powders in methane involves three stages in different reaction temperature ranges. Temperature programing oxidation test and Raman spectrum results indicated the formation of complex and ordered carbon structures at high deposition temperatures. The values of I(D)/I(G) of the deposited carbon reached 1.86, 1.30, and 1.22 in the first, second, and third stages, respectively. The structure of carbon in the second stage was similar to that in the third stage. Carbon deposited in the first stage rarely contained homogeneous pyrolytic deposit layers. A kinetic model was developed to analyze the carbon deposition behavior in the first stage. The rate-determining step of the first stage is supposed to be interfacial reaction. Based on the investigation of carbon deposition kinetics on nickel powders from different resources, carbon deposition rate is suggested to have a linear relation with the square of specific surface area of nickel particles.
- metallic nickel;
- carbon deposition;
- coking;
- specific surface area;
- methane;
- kinetics

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Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

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Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

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