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Volume 25 Issue 3
Mar.  2018
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文章导航 >  矿物冶金与材料学报（英文）  > 2018  >  25(3): 288-299
Yun-long He, Rui-dong Xu, Shi-wei He, Han-sen Chen, Kuo Li, Yun Zhu, and Qing-feng Shen, Effect of NaNO3 concentration on anodic electrochemical behavior on the Sb surface in NaOH solution, Int. J. Miner. Metall. Mater., 25(2018), No. 3, pp. 288-299. https://doi.org/10.1007/s12613-018-1572-0
Cite this article as:
Yun-long He, Rui-dong Xu, Shi-wei He, Han-sen Chen, Kuo Li, Yun Zhu, and Qing-feng Shen, Effect of NaNO3 concentration on anodic electrochemical behavior on the Sb surface in NaOH solution, Int. J. Miner. Metall. Mater., 25(2018), No. 3, pp. 288-299. https://doi.org/10.1007/s12613-018-1572-0
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研究论文

Effect of NaNO3 concentration on anodic electrochemical behavior on the Sb surface in NaOH solution

  • Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China;

  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093, China

  • 通讯作者:

    Rui-dong Xu    E-mail: rdxupaper@aliyun.com

  • The effect of NaNO3 concentration on the anodic electrochemical behavior of antimony in 4 M NaOH solution was investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analyses. The mechanism of NO3- concentration effect on the anodic electrochemical behavior of antimony was proposed, and its availability was confirmed by experimental results. The effect of NaNO3 on the anodic behavior of antimony in NaOH solution can be interpreted as a stepwise formation of different antimony compounds with different NaNO3 concentrations. Metallic antimony is apt to be oxidized into Sb2O3 within the NaNO3 concentration range of 0-0.48 M. NaSbO3 can be found on the antimony surface when the NaNO3 concentration increases gradually. Insoluable NaSbO3 inhibits the anodic oxidation of antimony due to its shielding effect on the mass transport of the reactants and products. Surface morphology and composition were analyzed by X-ray photoelectron spectroscopy (XPS), scanning electronic microscopy (SEM), and electron dispersion spectroscopy (EDS) analyses. Results indicate that the anodic oxidation layer is composed of Sb2O3, NaSbO3, and Sb. The atomic proportion of antimony in the form of NaSbO3 increases with increasing NaNO3 concentration due to the powerful oxidizing property of NaNO3.
    • Research Article

    Effect of NaNO3 concentration on anodic electrochemical behavior on the Sb surface in NaOH solution

    + Author Affiliations
      Abstract
    • The effect of NaNO3 concentration on the anodic electrochemical behavior of antimony in 4 M NaOH solution was investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analyses. The mechanism of NO3- concentration effect on the anodic electrochemical behavior of antimony was proposed, and its availability was confirmed by experimental results. The effect of NaNO3 on the anodic behavior of antimony in NaOH solution can be interpreted as a stepwise formation of different antimony compounds with different NaNO3 concentrations. Metallic antimony is apt to be oxidized into Sb2O3 within the NaNO3 concentration range of 0-0.48 M. NaSbO3 can be found on the antimony surface when the NaNO3 concentration increases gradually. Insoluable NaSbO3 inhibits the anodic oxidation of antimony due to its shielding effect on the mass transport of the reactants and products. Surface morphology and composition were analyzed by X-ray photoelectron spectroscopy (XPS), scanning electronic microscopy (SEM), and electron dispersion spectroscopy (EDS) analyses. Results indicate that the anodic oxidation layer is composed of Sb2O3, NaSbO3, and Sb. The atomic proportion of antimony in the form of NaSbO3 increases with increasing NaNO3 concentration due to the powerful oxidizing property of NaNO3.
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