留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 25 Issue 4
Apr.  2018
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  610
  • HTML全文浏览量:  120
  • PDF下载量:  15
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2018  >  25(4): 472-479
Revanna Kullaiah, Liju Elias,  and Ampar Chitharanjan Hegde, Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 472-479. https://doi.org/10.1007/s12613-018-1593-8
Cite this article as:
Revanna Kullaiah, Liju Elias,  and Ampar Chitharanjan Hegde, Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 472-479. https://doi.org/10.1007/s12613-018-1593-8
shu
引用本文 PDF XML SpringerLink
研究论文

Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings

  • Electrochemistry Research Lab, Department of Chemistry, National Institute of Technology Karnataka, Srinivasnagar P. O., Surathkal, Mangalore-575025, India

  • 通讯作者:

    Ampar Chitharanjan Hegde    E-mail: acrhegde@gmail.com

  • The electrocatalytic activity of electrodeposited Ni and Ni-TiO2 coatings with regard to the alkaline hydrogen evolution reaction (HER) was investigated. The Ni coatings were electrodeposited from an acid chloride bath at different current densities, and their HER activities were examined in a 1.0-mol·L-1 KOH medium. The variations in the HER activity of the Ni coatings with changes in surface morphology and composition were examined via the electrochemical dissolution and incorporation of nanoparticles. Electrochemical analysis methods were used to monitor the HER activity of the test electrodes; this activity was confirmed via the quantification of gases that evolved during the analysis. The obtained results demonstrated that the Ni-TiO2 nanocomposite test electrode exhibited maximum activity toward the alkaline HER. The surface appearance, composition, and the phase structure of all developed coatings were analyzed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), respectively. The improvement in the electrocatalytic activity of Ni-TiO2 nanocomposite coating toward HER was attributed to the variation in surface morphology and increased number of active sites.
    • Research Article

    Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings

    + Author Affiliations
      Abstract
    • The electrocatalytic activity of electrodeposited Ni and Ni-TiO2 coatings with regard to the alkaline hydrogen evolution reaction (HER) was investigated. The Ni coatings were electrodeposited from an acid chloride bath at different current densities, and their HER activities were examined in a 1.0-mol·L-1 KOH medium. The variations in the HER activity of the Ni coatings with changes in surface morphology and composition were examined via the electrochemical dissolution and incorporation of nanoparticles. Electrochemical analysis methods were used to monitor the HER activity of the test electrodes; this activity was confirmed via the quantification of gases that evolved during the analysis. The obtained results demonstrated that the Ni-TiO2 nanocomposite test electrode exhibited maximum activity toward the alkaline HER. The surface appearance, composition, and the phase structure of all developed coatings were analyzed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), respectively. The improvement in the electrocatalytic activity of Ni-TiO2 nanocomposite coating toward HER was attributed to the variation in surface morphology and increased number of active sites.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(26)
    • [1]
      T.N. Veziroğlu and S. Şahin, 21st century's energy:hydrogen energy system, Energy Convers. Manage., 49(2008), No. 7, p. 1820.
      [2]
      T.N. Veziro⋗ lu and F. Barbir, Hydrogen:the wonder fuel, Int. J. Hydrogen Energy, 17(1992), No. 6, p. 391.
      [3]
      X.X. Zou and Y. Zhang, Noble metal-free hydrogen evolution catalysts for water splitting, Chem. Soc. Rev., 44(2015), No. 15, p. 5148.
      [4]
      D. Pletcher, Electrocatalysis:present and future, J. Appl. Electrochem., 14(1984), No. 4, p. 403.
      [5]
      F. Safizadeh, E. Ghali, and G. Houlachi, Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions-A review, Int. J. Hydrogen Energy, 40(2015), No. 1, p. 256.
      [6]
      D. Pletcher and X.H. Li, Prospects for alkaline zero gap water electrolysers for hydrogen production, Int. J. Hydrogen Energy. 36(2011), No. 23, p. 15089.
      [7]
      B.V. Tilak, A.C. Ramamurthy, and B.E. Conway, High performance electrode materials for the hydrogen evolution reaction from alkaline media, J. Chem. Sci., 97(1986), No. 3-4, p. 359.
      [8]
      D.S.P. Cardoso, L. Amaral, D.M.F. Santos, B. Šljukić, C.A.C. Sequeira, D. Macciò, and A. Saccone, Enhancement of hydrogen evolution in alkaline water electrolysis by using nickel-rare earth alloys, Int. J. Hydrogen Energy, 40(2015), No. 12, p. 4295.
      [9]
      L.J. Elias, K. Scott, and A.C. Hegde, Electrolytic synthesis and characterization of electrocatalytic Ni-W alloy, J. Mater. Eng. Perform., 24(2015), No. 11, p. 4182.
      [10]
      L. Elias, P. Cao, and A.C. Hegde, Magnetoelectrodeposition of Ni-W alloy coatings for enhanced hydrogen evolution reaction, RSC Adv., 6(2016), No. 112, p. 111358.
      [11]
      L. Elias and A.C. Hegde, Modification of Ni-P alloy coatings for better hydrogen production by electrochemical dissolution and TiO2 nanoparticles, RSC Adv., 6(2016), No. 70, p. 66204.
      [12]
      N. Kanani, Electroplating:Basic Principles, Processes and Practice, Elsevier, Germany, 2004, p. 5.
      [13]
      L. Beneaand and A.I. Pavlov, Ni-TiO2 nanocomposite coatings as cathode material for hydrogen evolution reaction, J. Optoelectron. Adv. Mater., 7(2013), No. 11-12, p. 895.
      [14]
      P. Baghery, M. Farzam, A.B. Mousavi, and M. Hosseini, Ni-TiO2 nanocomposite coating with high resistance to corrosion and wear, Surf. Coat. Technol., 204(2010), No. 23, p. 3804.
      [15]
      L. Elias and A.C. Hegde, Synthesis and characterization of Ni-P-Ag composite coating as efficient electrocatalyst for alkaline hydrogen evolution reaction, Electrochim. Acta, 219(2016), p. 377.
      [16]
      C.T.J. Low, R.G.A. Wills, and F.C. Walsh, Electrodeposition of composite coatings containing nanoparticles in a metal deposit, Surf. Coat. Technol., 201(2006), No. 1-2, p. 371.
      [17]
      A.A. Aal and H.B. Hassan, Electrodeposited nanocomposite coatings for fuel cell application, J. Alloys Compd., 477(2009), No. 1-2, p. 652.
      [18]
      I.A. Raj, Nickel-based, binary-composite electrocatalysts for the cathodes in the energy-efficient industrial production of hydrogen from alkaline-water electrolytic cells, J. Mater. Sci., 28(1993), No. 16, p. 4375.
      [19]
      C.Q. Li, X.H. Li, Z.X. Wang, and H.J. Guo, Nickel electrodeposition from novel citrate bath, Trans. Nonferrous Met. Soc. China, 17(2007), No. 6, p. 1300.
      [20]
      E. Rudnik, M. Wojnicki, and G. Włoch, Effect of gluconate addition on the electrodeposition of nickel from acidic baths, Surf. Coat. Technol., 207(2012) 375.
      [21]
      D. Gierlotka, E. Rówinski, A. Budniok, and E.L. Giewka, Production and properties of electrolytic Ni-P-TiO2 composite layers, J. Appl. Electrochem., 27(1997), No. 12, p. 1349.
      [22]
      I. Ruzybayev, E. Yassitepe, A. Ali, A.S. Bhatti, R.M. Mohamed, M. Islam, and S.I. Shah, Reactive pulsed laser deposited N-C codoped TiO2 thin films, Mater. Sci. Semicond. Process., 39(2015), p. 371.
      [23]
      S. Javed, M. Mujahid, M. Islam, and U. Manzoor, Morphological effects of reflux condensation on nanocrystalline anatase gel and thin films, Mater. Chem. Phys., 132(2012), No. 2-3, p. 509.
      [24]
      M. Islam and T. Shehbaz, Effect of synthesis conditions and post-deposition treatments on composition and structural morphology of medium-phosphorus electroless Ni-P films, Surf. Coat. Technol., 205(2011), No. 19, p. 4397.
      [25]
      L. Elias and A.C. Hegde, Effect of including the carbon nanotube and graphene oxide on the electrocatalytic behavior of the Ni-W alloy for the hydrogen evolution reaction, New J. Chem., 41(2017), No. 22, p. 13912.
      [26]
      M. Islam, M.R. Azhar, N. Fredj, and T.D. Burleigh, Electrochemical impedance spectroscopy and indentation studies of pure and composite electroless Ni-P coatings, Surf. Coat. Technol., 236(2013), p. 262.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计