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Volume 25 Issue 4
Apr.  2018
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文章导航 >  矿物冶金与材料学报（英文）  > 2018  >  25(4): 472-479
Revanna Kullaiah, Liju Elias,  and Ampar Chitharanjan Hegde, Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 472-479. https://doi.org/10.1007/s12613-018-1593-8
Cite this article as:
Revanna Kullaiah, Liju Elias,  and Ampar Chitharanjan Hegde, Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 472-479. https://doi.org/10.1007/s12613-018-1593-8
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研究论文

Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings

  • Electrochemistry Research Lab, Department of Chemistry, National Institute of Technology Karnataka, Srinivasnagar P. O., Surathkal, Mangalore-575025, India

  • 通讯作者:

    Ampar Chitharanjan Hegde    E-mail: acrhegde@gmail.com

  • The electrocatalytic activity of electrodeposited Ni and Ni-TiO2 coatings with regard to the alkaline hydrogen evolution reaction (HER) was investigated. The Ni coatings were electrodeposited from an acid chloride bath at different current densities, and their HER activities were examined in a 1.0-mol·L-1 KOH medium. The variations in the HER activity of the Ni coatings with changes in surface morphology and composition were examined via the electrochemical dissolution and incorporation of nanoparticles. Electrochemical analysis methods were used to monitor the HER activity of the test electrodes; this activity was confirmed via the quantification of gases that evolved during the analysis. The obtained results demonstrated that the Ni-TiO2 nanocomposite test electrode exhibited maximum activity toward the alkaline HER. The surface appearance, composition, and the phase structure of all developed coatings were analyzed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), respectively. The improvement in the electrocatalytic activity of Ni-TiO2 nanocomposite coating toward HER was attributed to the variation in surface morphology and increased number of active sites.
    • Research Article

    Effect of TiO2 nanoparticles on hydrogen evolution reaction activity of Ni coatings

    + Author Affiliations
      Abstract
    • The electrocatalytic activity of electrodeposited Ni and Ni-TiO2 coatings with regard to the alkaline hydrogen evolution reaction (HER) was investigated. The Ni coatings were electrodeposited from an acid chloride bath at different current densities, and their HER activities were examined in a 1.0-mol·L-1 KOH medium. The variations in the HER activity of the Ni coatings with changes in surface morphology and composition were examined via the electrochemical dissolution and incorporation of nanoparticles. Electrochemical analysis methods were used to monitor the HER activity of the test electrodes; this activity was confirmed via the quantification of gases that evolved during the analysis. The obtained results demonstrated that the Ni-TiO2 nanocomposite test electrode exhibited maximum activity toward the alkaline HER. The surface appearance, composition, and the phase structure of all developed coatings were analyzed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), respectively. The improvement in the electrocatalytic activity of Ni-TiO2 nanocomposite coating toward HER was attributed to the variation in surface morphology and increased number of active sites.
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