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Volume 25 Issue 5
May  2018
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文章导航 >  矿物冶金与材料学报（英文）  > 2018  >  25(5): 489-497
Jin-sheng Yu, Run-qing Liu, Li Wang, Wei Sun, Hong Peng, and Yue-hua Hu, Selective depression mechanism of ferric chromium lignin sulfonate for chalcopyrite–galena flotation separation, Int. J. Miner. Metall. Mater., 25(2018), No. 5, pp. 489-497. https://doi.org/10.1007/s12613-018-1595-6
Cite this article as:
Jin-sheng Yu, Run-qing Liu, Li Wang, Wei Sun, Hong Peng, and Yue-hua Hu, Selective depression mechanism of ferric chromium lignin sulfonate for chalcopyrite–galena flotation separation, Int. J. Miner. Metall. Mater., 25(2018), No. 5, pp. 489-497. https://doi.org/10.1007/s12613-018-1595-6
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研究论文

Selective depression mechanism of ferric chromium lignin sulfonate for chalcopyrite–galena flotation separation

  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

  • School of Chemical Engineering, The University of Queensland, Brisbane 4072, Australia

  • 通讯作者:

    Run-qing Liu    E-mail: liurunqing@126.com

    Wei Sun    E-mail: sunmenghu@csu.edu.cn

  • Selective recovery of chalcopyrite–galena ore by flotation remains a challenging issue. The development of highly efficient, low-cost, and environmentally friendly depressants for this flotation is necessary because most of available reagents (e.g., K2Cr2O4) are expensive and adversely affect the environment. In this study, ferric chromium lignin sulfonate (FCLS), which is a waste-product from the paper and pulp industry, was introduced as a selective depressant for galena with butyl xanthate (BX) as a collector. Results show that the residue recovery of Pb in Cu concentrate was substantially reduced to 4.73% using FCLS compared with 10.71% using the common depressant K2Cr2O4. The underlying mechanisms were revealed using zeta-potential measurements and X-ray photoelectron spectroscopy (XPS). Zeta-potential measurements revealed that FCLS was more efficiently absorbed onto galena than onto chalcopyrite. XPS measurements further suggested that FCLS enhanced the surface oxidation of galena but prevented that of chalcopyrite. Thus, FCLS could be a potential candidate as a depressant for chalcopyrite–galena flotation because of its low cost and its lack of detrimental effects on the environment.
    • Research Article

    Selective depression mechanism of ferric chromium lignin sulfonate for chalcopyrite–galena flotation separation

    + Author Affiliations
      Abstract
    • Selective recovery of chalcopyrite–galena ore by flotation remains a challenging issue. The development of highly efficient, low-cost, and environmentally friendly depressants for this flotation is necessary because most of available reagents (e.g., K2Cr2O4) are expensive and adversely affect the environment. In this study, ferric chromium lignin sulfonate (FCLS), which is a waste-product from the paper and pulp industry, was introduced as a selective depressant for galena with butyl xanthate (BX) as a collector. Results show that the residue recovery of Pb in Cu concentrate was substantially reduced to 4.73% using FCLS compared with 10.71% using the common depressant K2Cr2O4. The underlying mechanisms were revealed using zeta-potential measurements and X-ray photoelectron spectroscopy (XPS). Zeta-potential measurements revealed that FCLS was more efficiently absorbed onto galena than onto chalcopyrite. XPS measurements further suggested that FCLS enhanced the surface oxidation of galena but prevented that of chalcopyrite. Thus, FCLS could be a potential candidate as a depressant for chalcopyrite–galena flotation because of its low cost and its lack of detrimental effects on the environment.
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    • [1]
      W.Q. Qin, Q. Wei, F. Jiao, N. Ling, P.P. Wang, and L.F. Ke, Effect of sodium pyrophosphate on the flotation separation of chalcopyrite from galena, Int. J. Min. Sci. Technol., 22(2012), No. 3, p. 345.
      [2]
      C.A. Prestidge, J. Ralston, and R.S.C. Smart, The role of cyanide in the interaction of ethyl xanthate with galena, Colloids Surf. A, 81(1993), No. 93, p. 103.
      [3]
      Z.J. Piao, D.Z. Wei, and Z.L. Liu, Influence of sodium 2,3-dihydroxypropyl dithiocarbonate on floatability of chalcopyrite and galena, Trans. Nonferrous Met. Soc. China, 24(2014), No. 10, p. 3343.
      [4]
      Z.J. Piao, D.Z. Wei, Z.L. Liu, W.G. Liu, S.L. Gao, and M.Y. Li, Selective depression of galena and chalcopyrite by O,O-bis(2,3-dihydroxypropyl) dithiophosphate, Trans. Nonferrous Met. Soc. China, 23(2013), No. 10, p. 3063.
      [5]
      R.Z. Liu, W.Q. Qin, F. Jiao, X.J. Wang, B. Pei, Y.J. Yang, and C.H. Lai, Flotation separation of chalcopyrite from galena by sodium humate and ammonium persulfate, Trans. Nonferrous Met. Soc. China, 26(2016), No. 1, p. 265.
      [6]
      P. Huang, L. Wang, and Q. Liu, Depressant function of high molecular weight polyacrylamide in the xanthate flotation of chalcopyrite and galena, Int. J. Miner. Process., 128(2014), p. 6.
      [7]
      Q. Liu and Y.H Zhang, Effect of calcium ions and citric acid on the flotation separation of chalcopyrite from galena using dextrin, Miner. Eng., 13(2000), No. 13, p. 1405.
      [8]
      J. Drzymala, J. Kapusniak, and P. Tomasik, Removal of lead minerals from copper industrial flotation concentrates by xanthate flotation in the presence of dextrin, Int. J. Miner. Process., 70(2003), No. 1-4, p. 147.
      [9]
      P. Huang, M.L. Cao, and Q. Liu, Using chitosan as a selective depressant in the differential flotation of Cu–Pb sulfides, Int. J. Miner. Process., 106-109(2012), p. 8.
      [10]
      J.J. Huang, P.X. Lin, L.J. Bo, and L.C. Xia, Viscosity reducer thin for water base drilling fluids used at temperatures up to 220℃, Oilfield Chem., 20(2003), No. 3, p. 197.
      [11]
      C.X. Huang, Y.X. Leng, C.T. Xu, L.F. Xu, and L.J. Jia, A preliminary study on polyaspartic acid as viscosity reducer for water base drilling fluids, Oilfield Chem., 23(2006), No. 3, p. 193.
      [12]
      H.A. Zhou, Calcium salt of polyacrylic acid (CPA) as performance improver for KHm/FCLS/CMC anti-caving drilling fluids, Oilfield Chem., 8(1991), No. 4, p. 276.
      [13]
      A. Ansari and M. Pawlik, Floatability of chalcopyrite and molybdenite in the presence of lignosulfonates. Part I. Adsorption studies, Miner. Eng., 20(2007), No. 6, p. 600.
      [14]
      J.G. Zhu and Y.S. Zhu, The Chemical Principle of Flotation Reagent, Central South University of Technology Press, Changsha, 1987, p. 284.
      [15]
      R.Q. Liu, W. Sun, Y.H. Hu, and D.Z. Wang, Surface chemical study of the selective separation of chalcopyrite and marmatite, Min. Sci. Technol. China, 20(2010), No. 4, p. 542.
      [16]
      G.Y. Liu, Z.H. Qiu, J.Y. Wang, Q.X. Liu, J.J. Xiao, H.B. Zeng, and H. Zhong, Study of N-isopropoxypropyl-N'-ethoxycarbonyl thiourea adsorption on chalcopyrite using in situ SECM, ToF-SIMS and XPS, J. Colloid Interface Sci., 437(2015), p. 42.
      [17]
      L.K. Bailey and E. Peters, Decomposition of pyrite in acids by pressure leaching and anodization: the case for an electrochemical mechanism, Can. Metall. Q., 15(1976), No. 4, p. 333.
      [18]
      Z. Wang, Y.L. Qian, L.H. Xu, B. Dai, J.H. Xiao, and K.B. Fu, Selective chalcopyrite flotation from pyrite with glycerine-xanthate as depressant, Miner. Eng., 74(2015), p. 86.
      [19]
      H.S. Altundogan, Cr(VI) removal from aqueous solution by iron(Ⅲ) hydroxide-loaded sugar beet pulp, Process Biochem., 40(2005), No. 3-4, p. 1443.
      [20]
      E. Leese, J. Morton, P.H.E. Gardiner, and V.A. Carolan, The simultaneous detection of trivalent & hexavalent chromium in exhaled breath condensate: A feasibility study comparing workers and controls, Int. J. Hyg. Environ. Health, 220(2016), No. 2, p. 415.
      [21]
      D. Mohan, U. Charles, and C.U. Pittman Jr., Activated carbons and low cost adsorbents for remediation of tri-and hexavalent chromium from water, J. Hazard. Mater., 137(2006), No. 2, p. 762.
      [22]
      Y.B. Song and D.T. Chin, Current efficiency and polarization behavior of trivalent chromium electrodeposition process, Electrochim. Acta, 48(2002), No. 4, p. 349.
      [23]
      J.H.O.J. Wijenberg, M. Steegh, M.P. Aarnts, K.R. Lammers, and J.M.C. Mol, Electrodeposition of mixed chromium metal-carbide-oxide coatings from a trivalent chromium-formate electrolyte without a buffering agent, Electrochim. Acta, 173(2015), p. 819.
      [24]
      D. Fornasiero, F.S. Li, and J. Ralston, Oxidation of galena: Ⅱ. Electrokinetic study, J. Colloid Interface Sci., 164(1994), No. 2, p. 345.
      [25]
      D. Fullston, D. Fornasiero, and J. Ralston, Zeta potential study of the oxidation of copper sulfide minerals, Colloids Surf. A, 146(1999), No. 1-3, p. 113.
      [26]
      F. Ikumapayi, M. Makitalo, B. Johansson, and K.H. Rao, Recycling of process water in sulphide flotation: Effect of calcium and sulphate ions on flotation of galena, Miner. Eng., 39(2012), No. 12, p. 77.
      [27]
      A.V. Shchukarev, I.M. Kravets, A.N. Buckley, and R. Woods, Submonolayer adsorption of alkyl xanthates on galena, Int. J. Miner. Process., 41(1994), No. 1-2, p. 99.
      [28]
      K. Laajalehto, P. Nowak, A. Pomianowski, and E. Suoninen, Xanthate adsorption at PbS/aqueous interfaces: Comparison of XPS, infrared and electrochemical results, Colloids Surf., 57(1991), No. 2, p. 319.
      [29]
      G.D. Giudici, A. Rossi, L. Fanfani, and P. Lattanzi, Mechanisms of galena dissolution in oxygen-saturated solutions: Evaluation of pH effect on apparent activation energies and mineral-water interface, Geochim. Cosmochim. Acta, 69(2005), No. 9, p. 2321.
      [30]
      M.L. Farquhar, P.L. Wincott, R.A. Wogelius, and D.J. Vaughan, Electrochemical oxidation of the chalcopyrite surface: an XPS and AFM study in solution at pH 4, Appl. Surf. Sci., 218(2003), No. 1-4, p. 34.
      [31]
      Z. He, G. Liu, X. Yang, and W. Liu, A novel surfactant, N, N-diethyl-N'-cyclohexylthiourea: Synthesis, flotation and adsorption on chalcopyrite, J. Ind. Eng. Chem., 37(2016), p. 107.
      [32]
      G. Fairthorne, D. Fornasiero, and J. Ralston, Effect of oxidation on the collectorless flotation of chalcopyrite, Int. J. Miner. Process., 49(1997), No. 1-2, p. 31.
      [33]
      N.H. Turner, J.S. Murday, and D.E. Ramaker, Quantitative determination of surface composition of sulfur-bearing anion mixtures by Auger electron spectroscopy, J. Vac. Sci. Technol., 17(1980), No. 1, p. 84.
      [34]
      R.V. Siriwardane and J.M. Cook, Interactions of NO and SO2 with iron deposited on silca, J. Colloid Interface Sci., 104(1985), No. 1, p. 250.
      [35]
      M. Volmer, M. Stratmann, and H. Viefhaus, Electrochemical and electron spectroscopic investigations of iron surfaces modified with thiols, Surf. Interface Anal., 16(1990), No. 1-12, p. 278.
      [36]
      B.J. Lindberg, K. Hamrin, G. Johansson, U. Gelius, A. Fahlman, C. Nordling, and K. Siegbahn, Molecular spectroscopyby means of ESCA Ⅱ. sulfur compounds. Correlation of electron binding energy with structure, Phys. Scr., 1(1970), No. 5-6, p. 286.
      [37]
      Y.I. Kim and W.E. Hatfield, Electrical, magnetic and spectroscopic properties of tetrathiafulvalene charge transfer compounds with iron, ruthenium, rhodium and iridium halides, Inorg. Chim. Acta, 188(1991), No. 1, p. 15.
      [38]
      A.R. Pratt, H.W. Nesbitt, and I.J. Muir, Generation of acids from mine waste: Oxidative leaching of pyrrhotite in dilute H2SO4, solutions at pH 3.0, Geochim. Cosmochim. Acta, 58(1994), No. 23, p. 5147.
      [39]
      D. Brion, Etude par spectroscopie de photoelectrons de la degradation superficielle de FeS2, CuFeS2, ZnS et PbS a I'air et dans I'eau, Appl. Surf. Sci., 5(1980), No. 2, p. 133.
      [40]
      A.N. Buckley and R.Woods, An X-ray photoelectron spectroscopic study of the oxidation of galena, Appl. Surf. Sci., 17(1984), No. 4, p. 401.
      [41]
      K. Laajalehto, I. Kartio, and P. Nowak, XPS study of clean metal sulfide surfaces, Appl. Surf. Sci., 81(1994), No. 1, p. 11.
      [42]
      H. Konno, K. Sasaki, M. Tsunekawa, T. Takamori, and R. Furuichi, X-ray photoelectron spectroscopic analysis of surface products on pyrite formed by baterial leaching, Bunseki Kagaku, 40(1991), No. 11, p. 609.
      [43]
      R.V. Siriwardane and J.M. Cook, Interactions of SO2 with sodium deposited on silica, J. Colloid Interface Sci., 108(1985), No. 2, p. 414.
      [44]
      X.R. Yu, F. Liu, Z.Y. Wang, and Y. Chen, Auger parameters for sulfur-containing compounds using a mixed aluminum-silver excitation source, J. Electron Spectrosc. Relat. Phenom., 50(1990), No. 2, p. 159.
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