留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 25 Issue 10
Oct.  2018
数据统计

分享

计量
  • 文章访问数:  553
  • HTML全文浏览量:  91
  • PDF下载量:  16
  • 被引次数: 0
Ya-feng Fu, Wan-zhong Yin, Bin Yang, Chuang Li, Zhang-lei Zhu, and Dong Li, Effect of sodium alginate on reverse flotation of hematite and its mechanism, Int. J. Miner. Metall. Mater., 25(2018), No. 10, pp. 1113-1122. https://doi.org/10.1007/s12613-018-1662-z
Cite this article as:
Ya-feng Fu, Wan-zhong Yin, Bin Yang, Chuang Li, Zhang-lei Zhu, and Dong Li, Effect of sodium alginate on reverse flotation of hematite and its mechanism, Int. J. Miner. Metall. Mater., 25(2018), No. 10, pp. 1113-1122. https://doi.org/10.1007/s12613-018-1662-z
引用本文 PDF XML SpringerLink
研究论文

Effect of sodium alginate on reverse flotation of hematite and its mechanism

  • 通讯作者:

    Wan-zhong Yin    E-mail: yinwanzhong@mail.neu.edu.cn

  • Given the gradual increase in the chlorite content of hematite ores, pulp properties seriously deteriorate during flotation. The traditional anion reverse flotation of hematite cannot effectively eliminate the effects of chlorite, leading to a significant decrease in the total Fe (TFe) grade of the concentrate. In this work, the effect of sodium alginate on the reverse flotation of hematite was systematically investigated. Flotation tests of artificially mixed ores were conducted, and the results showed that sodium alginate can significantly improve the removal rates of quartz and chlorite. The adsorption measurements, infrared spectroscopy, and contact angle tests demonstrated that sodium alginate adsorbs on the quartz surface by chelating with calcium ions, thereby weakening the steric hindrance of oleate ions and increasing the adsorption capacity of sodium oleate to ultimately improve the removal rate of quartz. Furthermore, owing to its lower density and fine particle size, chlorite is easily entrained into the foam layer. Sodium alginate dramatically increases the liquid-to-gas ratio of the foam layer by increasing pulp viscosity, thereby increasing the entrainment rate of chlorite and finally improving its removal rate. The core content of this thesis bears significance in improving the Fe grade in the reverse flotation of chlorite-containing hematite.
  • Research Article

    Effect of sodium alginate on reverse flotation of hematite and its mechanism

    + Author Affiliations
    • Given the gradual increase in the chlorite content of hematite ores, pulp properties seriously deteriorate during flotation. The traditional anion reverse flotation of hematite cannot effectively eliminate the effects of chlorite, leading to a significant decrease in the total Fe (TFe) grade of the concentrate. In this work, the effect of sodium alginate on the reverse flotation of hematite was systematically investigated. Flotation tests of artificially mixed ores were conducted, and the results showed that sodium alginate can significantly improve the removal rates of quartz and chlorite. The adsorption measurements, infrared spectroscopy, and contact angle tests demonstrated that sodium alginate adsorbs on the quartz surface by chelating with calcium ions, thereby weakening the steric hindrance of oleate ions and increasing the adsorption capacity of sodium oleate to ultimately improve the removal rate of quartz. Furthermore, owing to its lower density and fine particle size, chlorite is easily entrained into the foam layer. Sodium alginate dramatically increases the liquid-to-gas ratio of the foam layer by increasing pulp viscosity, thereby increasing the entrainment rate of chlorite and finally improving its removal rate. The core content of this thesis bears significance in improving the Fe grade in the reverse flotation of chlorite-containing hematite.
    • loading
    • [1]
      D.Z. Wang and Y.H. Hu, Solution Chemistry of Flotation, Hunan Science and Technology Press, Changsha, 1988.
      [2]
      S. Ata, Phenomena in the froth phase of flotation-A review, Int. J. Miner. Process., 102-103(2012), No. 2, p. 1.
      [3]
      Z.Y. Gao, W. Sun, and Y.H. Hu, New insights into the dodecylamine adsorption on scheelite and calcite:An adsorption model, Miner. Eng., 79(2015), p. 54.
      [4]
      L. Wang, Y. Peng, K. Runge, and D. Bradshaw, A review of entrainment:Mechanisms, contributing factors and modelling in flotation, Miner. Eng., 70(2015), p. 77.
      [5]
      J.J. Bikerman, Foams:Theory and Industrial Applications, Reinhold Publishing Corporation, New York, 1953.
      [6]
      H. Kursun, Effect of fine particles' entrainment on conventional and column flotation, Part. Sci. Technol., 32(2014), No. 3, p. 251.
      [7]
      Y.J. Peng and S.L. Zhao, The effect of surface oxidation of copper sulfide minerals on clay slime coating in flotation, Miner. Eng., 24(2011), No. 15, p. 1687.
      [8]
      Q. Liu, D. Wannas, and Y. Peng, Exploiting the dual functions of polymer depressants in fine particle flotation, Int. J. Miner. Process., 80(2006), No. 2-4, p. 244.
      [9]
      F. Melo and J.S. Laskowski, Fundamental properties of flotation frothers and their effect on flotation, Miner. Eng., 19(2006), No. 6-8, p. 766.
      [10]
      P. George, A.V. Nguyen, and G.J. Jameson, Assessment of true flotation and entrainment in the flotation of submicron particles by fine bubbles, Miner. Eng., 17(2004), No. 7-8, p. 847.
      [11]
      Y.P. Zhang, K.L. Huang, and S.Q. Liu, Separation of clinochlore from powder quartz by reverse flotation and its mechanism, J. Cent. South Univ. Sci. Technol., 38(2007), No. 2, p. 285.
      [12]
      M. Alvarez-Silva, A. Uribe-Salas, M. Mirnezami, and J.A. Finch, The point of zero charge of phyllosilicate minerals using the mular-roberts titration technique, Miner. Eng., 23(2010), No. 5, p. 383.
      [13]
      Z. Cao, Y.H. Zhang, and Y.D. Cao, Reverse flotation of quartz from magnetite ore with modified sodium oleate, Miner. Process. Extr. Metall. Rev., 34(2013), No. 5, p. 320.
      [14]
      Y.J. Xian, S.M. Wen, S.J. Bai, and C.Y. Chen, Metal ions released from fluid inclusions of quartz associated with sulfides, Miner. Eng., 50-51(2013), p. 1.
      [15]
      J.R. Zhang, F.J. Li, F.P. Li, W.Z. Wang, Q.M. Jia, and L.B. Zhao, Mineral Processing Technology of Hematite Containing Chlorite, Chinese Patent, Appl. 201210138169, 2012.
      [16]
      D. Fornasiero and J. Ralston, Cu(Ⅱ) and Ni(Ⅱ) activation in the flotation of quartz, lizardite and chlorite, Int. J. Miner. Process., 76(2005), No. 1-2, p. 75.
      [17]
      K.Y. Lee and D.J. Mooney, Alginate:Properties and biomedical applications, Prog. Polym. Sci., 37(2012), No. 1, p. 106.
      [18]
      S.N. Pawar and K.J. Edgar, Alginate derivatization:A review of chemistry, properties and applications, Biomaterials, 33(2012), No. 11, p. 3279.
      [19]
      K.I. Draget and C. Taylor, Chemical, physical and biological properties of alginates and their biomedical implications, Food Hydrocolloids, 25(2011), No. 2, p. 251.
      [20]
      A.G. Corpuz, P. Pal, F. Banat, and M.A. Haija, Enhanced removal of mixed metal ions from aqueous solutions using flotation by colloidal gas aphrons stabilized with sodium alginate, Sep. Purif. Technol., 202(2018), p. 103.
      [21]
      T. Sasaki, I. Machida, and S. Ishiwata, Macromolecular ion flotation of Fe3+, Cu2+, and Ni2+ ions by combined use of macromolecular anions and cationic surfactant, Bull. Chem. Soc. Jpn., 55(1982), No. 10, p. 3109.
      [22]
      C. Wei, Q.M. Feng, G.F. Zhang, Q. Yang, and C. Zhang, The effect of sodium alginate on the flotation separation of scheelite from calcite and fluorite, Miner. Eng., 113(2017), p. 1.
      [23]
      T. Matsumoto, M. Kawai, and T. Masuda, Influence of concentration and mannuronate/guluronate ratio on steady flow properties of alginate aqueous systems, Biorheology, 29(1992), No. 4, p. 411.
      [24]
      Y. Lu, H.Q. Li, and Q.M. Feng, Entrainment behavior and control of sericite, J. Cent. South Univ. Sci. Technol., 46(2015), No. 1, p. 20.
      [25]
      X. Luo, Y.F. Wang, S.M. Wen, M.Z. Ma, C.Y. Sun, W.Z. Yin, and Y.Q. Ma, Effect of carbonate minerals on quartz flotation behavior under conditions of reverse anionic flotation of iron ores, Int. J. Miner. Process., 152(2016), p. 1.
      [26]
      A. Ambari, B. Gauthier-Manuel, and E. Guyon, Direct measurement of tube wall effect on the stokes force, Phys. Fluids, 28(1985), No.5, p. 1559.
      [27]
      H.S. Chen, Z.Y. Sun, and J.C. Shao, Investigation on FT-IR spectroscopy for eight different sources of SiO2, Bull. Chin. Ceram. Soc., 30(2011), No. 4, p. 934.
      [28]
      Q. Wan, F. Rao, S.X. Song, D.F. Cholico-González, and N.L. Ortiz, Combination formation in the reinforcement of metakaolin geopolymers with quartz sand, Cem. Concr. Compos., 80(2017), p. 115.
      [29]
      Y. Fukami, Y. Maeda, and K. Awazu, Raman and FT-IR studies of photodynamic processes of cholesteryl oleate using IRFELs, Nucl. Instrum. Methods Phys. Res. Sect. B, 144(1998), No. 1-4, p. 229.
      [30]
      W.W. Simons, The Sadtler Handbook of Infrared Spectra, Sadtler Research Laboratories, Inc., Philadelphia, 1978.
      [31]
      P. Roonasi, X.F. Yang, and A. Holmgren, Competition between sodium oleate and sodium silicate for a silicate/oleate modified magnetite surface studied by in situ ATR-FTIR spectroscopy, J. Colloid Interface Sci., 343(2009), No. 2, p. 546.
      [32]
      B. Janczuk and A. Zdziennicka, A study on the components of surface free energy of quartz from contact angle measurements, J. Mater. Sci., 29(1994), No. 13, p. 3559.
      [33]
      W.Z. Yin, D. Li, X.M. Luo, J. Yao, and Q.Y. Sun, Effect and mechanism of siderite on reverse flotation of hematite, Int. J. Miner. Metall. Mater., 23(2016), No. 4, p. 373.
      [34]
      Z.Q. Chen, N.H. Wang, E.S. Han, J. Chen, and G.X. Wang, The effects of calcium ion, pH value on the rheological properties of sodium alginate solution, Acta Chim. Sinica, 49(1991), p. 462.
      [35]
      J. Kou, Y. Guo, T.C. Sun, S.H. Xu, and C.Y. Xu, Adsorption mechanism of two different anionic collectors on quartz surface, J. Cent. South Univ. Sci. Technol., 11(2015), No. 46, p. 4005.
      [36]
      L.M. Surhone, M.T. Tennoe, and S.F. Henssonow, Van der Waals Force, Betascript Publishing, London, 2010.
      [37]
      L.N. Brush and S.M. Roper, The thinning of lamellae in surfactant-free foams with non-Newtonian liquid phase, J. Fluid Mech., 616(2008), p. 235.
      [38]
      A. Donev, I. Cisse, D. Sachs, E.A. Variano, F.H. Stillinger, R. Connelly, S. Torquato, and P.M. Chaikin, Improving the density of jammed disordered packings using ellipsoids, Science, 303(2004), No. 5660, p. 990.
      [39]
      S.G. Bardenhagen, A.D. Brydon, and J.E. Guilkey, Insight into the physics of foam densification via numerical simulation, J. Mech. Phys. Solids, 53(2005), p. 597.

    Catalog


    • /

      返回文章
      返回