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Volume 25 Issue 12
Dec.  2018
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文章导航 >  矿物冶金与材料学报（英文）  > 2018  >  25(12): 1482-1492
Meng Ren, Cheng-yun Zhang, Yue-lin Wang,  and Jin-jun Cai, Development of N-doped carbons from zeolite-templating route as potential electrode materials for symmetric supercapacitors, Int. J. Miner. Metall. Mater., 25(2018), No. 12, pp. 1482-1492. https://doi.org/10.1007/s12613-018-1703-7
Cite this article as:
Meng Ren, Cheng-yun Zhang, Yue-lin Wang,  and Jin-jun Cai, Development of N-doped carbons from zeolite-templating route as potential electrode materials for symmetric supercapacitors, Int. J. Miner. Metall. Mater., 25(2018), No. 12, pp. 1482-1492. https://doi.org/10.1007/s12613-018-1703-7
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研究论文

Development of N-doped carbons from zeolite-templating route as potential electrode materials for symmetric supercapacitors

  • Hunan Key Laboratory of Environment Friendly Chemical Process Technology, School of Chemical Engineering, Xiangtan University, Xiangtan 411105, China

  • State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

  • School of Engineering Materials & Science, Queen Mary University of London, London E1 4NS, United Kingdom

  • 通讯作者:

    Jin-jun Cai    E-mail: caijj@xtu.edu.cn,j.cai@qmul.ac.uk

  • N-doped carbons were fabricated from zeolite-templated carbon via modification with melamine and mild KOH activation. The N-doping treatment and KOH activation slightly lowered the surface areas of pristine zeolite-templated carbon; nonetheless, N-doped carbons with a lower surface area exhibited much higher capacitance and cycling stability as fabricated into symmetric supercapacitor. Significantly, N-doped carbon obtained at 700℃ showed a capacitance of 45.7 F/g at 0.1 A/g and 42.0 F/g at 10 A/g for the fabricated supercapacitor with 6 M KOH electrolyte, with 92% retention of initial capacitance as current density increased up to 100-fold. This performance was attributed to the dual contribution of electric double-layer capacitance and pseudo-capacitance. The assembled supercapacitor also exhibited excellent cycling stability, with 91% capacitance retention at 10 A/g after 10000 cycles.
    • Research Article

    Development of N-doped carbons from zeolite-templating route as potential electrode materials for symmetric supercapacitors

    + Author Affiliations
      Abstract
    • N-doped carbons were fabricated from zeolite-templated carbon via modification with melamine and mild KOH activation. The N-doping treatment and KOH activation slightly lowered the surface areas of pristine zeolite-templated carbon; nonetheless, N-doped carbons with a lower surface area exhibited much higher capacitance and cycling stability as fabricated into symmetric supercapacitor. Significantly, N-doped carbon obtained at 700℃ showed a capacitance of 45.7 F/g at 0.1 A/g and 42.0 F/g at 10 A/g for the fabricated supercapacitor with 6 M KOH electrolyte, with 92% retention of initial capacitance as current density increased up to 100-fold. This performance was attributed to the dual contribution of electric double-layer capacitance and pseudo-capacitance. The assembled supercapacitor also exhibited excellent cycling stability, with 91% capacitance retention at 10 A/g after 10000 cycles.
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