留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 1
Jan.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  942
  • HTML全文浏览量:  259
  • PDF下载量:  46
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(1): 33-40
Zhi-yuan Ma, Yong Liu, Ji-kui Zhou, Mu-dan Liu,  and Zhen-zhen Liu, Recovery of vanadium and molybdenum from spent petrochemical catalyst by microwave-assisted leaching, Int. J. Miner. Metall. Mater., 26(2019), No. 1, pp. 33-40. https://doi.org/10.1007/s12613-019-1707-y
Cite this article as:
Zhi-yuan Ma, Yong Liu, Ji-kui Zhou, Mu-dan Liu,  and Zhen-zhen Liu, Recovery of vanadium and molybdenum from spent petrochemical catalyst by microwave-assisted leaching, Int. J. Miner. Metall. Mater., 26(2019), No. 1, pp. 33-40. https://doi.org/10.1007/s12613-019-1707-y
shu
引用本文 PDF XML SpringerLink
研究论文

Recovery of vanadium and molybdenum from spent petrochemical catalyst by microwave-assisted leaching

  • Guangdong Institute of Resources Comprehensive Utilization, Guangdong Academy of Sciences, Guangzhou 510650, China

  • State Key Laboratory of Separation and Comprehensive Utilization of Rare Metals, Guangzhou 510650, China

  • Guangdong Provincial Key Laboratory of Development and Comprehensive Utilization of Mineral Resources, Guangzhou 510650, China

  • 通讯作者:

    Zhi-yuan Ma    E-mail: mzy1988@163.com

  • The study of the leaching of vanadium (V) and molybdenum (Mo) from spent petrochemical catalysts in sodium hydroxide (NaOH) medium was performed using two approaches, namely, conventional leaching and microwave-assisted leaching methods. The influence of microwave power, leaching time, leaching temperature, and NaOH concentration on the leaching efficiency of spent petrochemical catalyst was investigated. Under microwave-assisted conditions (600 W, 10 min, 90℃, 2.0 mol·L-1 NaOH, and 0.20 g·mL-1 solid-liquid ratio), the leaching efficiencies of V and Mo reached 94.35% and 96.23%, respectively. It has been confirmed that microwave energy has considerable potential to enhance the efficiency of the leaching process and reduce the leaching time. It is suggested that the enhancement of the leaching efficiencies of V and Mo can be attributed to the existence of a thermal gradient between solid and liquid and the generation of cracks on the mineral surface.
    • Research Article

    Recovery of vanadium and molybdenum from spent petrochemical catalyst by microwave-assisted leaching

    + Author Affiliations
      Abstract
    • The study of the leaching of vanadium (V) and molybdenum (Mo) from spent petrochemical catalysts in sodium hydroxide (NaOH) medium was performed using two approaches, namely, conventional leaching and microwave-assisted leaching methods. The influence of microwave power, leaching time, leaching temperature, and NaOH concentration on the leaching efficiency of spent petrochemical catalyst was investigated. Under microwave-assisted conditions (600 W, 10 min, 90℃, 2.0 mol·L-1 NaOH, and 0.20 g·mL-1 solid-liquid ratio), the leaching efficiencies of V and Mo reached 94.35% and 96.23%, respectively. It has been confirmed that microwave energy has considerable potential to enhance the efficiency of the leaching process and reduce the leaching time. It is suggested that the enhancement of the leaching efficiencies of V and Mo can be attributed to the existence of a thermal gradient between solid and liquid and the generation of cracks on the mineral surface.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(30)
    • [1]
      R. Banda, T.H. Nguyen, S.H. Sohn, and M.S. Lee, Recovery of valuable metals and regeneration of acid from the leaching solution of spent HDS catalysts by solvent extraction, Hydrometallurgy, 133(2013), p. 161.
      [2]
      A. Akcil, F. Vegliò, F. Ferella, M.D. Okudan, and A. Tuncuk, A review of metal recovery from spent petroleum catalysts and ash, Waste Manage., 45(2015), p. 420.
      [3]
      Z. Li, M. Chen, Q.W. Zhang, X.Z. Liu, and F. Saito, Mechanochemical processing of molybdenum and vanadium sulfides for metal recovery from spent catalysts wastes, Waste Manage., 60(2017), p. 734.
      [4]
      N.M. Al-Mansi and N.M.A. Monem, Recovery of nickel oxide from spent catalyst, Waste Manage., 22(2002), No. 1, p. 85.
      [5]
      V. Mymrin, A.M. Pedroso, H.A. Ponte, M.J.J. Ponte, K. Alekseev, D. Evaniki, and R.C.Y. Pan, Thermal engineering method application for hazardous spent petrochemical catalyst neutralization, Appl. Therm. Eng., 110(2017), p. 1428.
      [6]
      I.S.S. Pinto and H.M.V.M. Soares, Selective leaching of molybdenum from spent hydrodesulphurisation catalysts using ultrasound and microwave methods, Hydrometallurgy, 129-130(2012), p. 19.
      [7]
      I.S.S. Pinto and H.M.V.M. Soares, Microwave-assisted selective leaching of nickel from spent hydrodesulphurization catalyst:A comparative study between sulphuric and organic acids, Hydrometallurgy, 140(2013), p. 20.
      [8]
      Y.C. Lai, W.J. Lee, K.L. Huang, and C.M. Wu, Metal recovery from spent hydrodesulfurization catalysts using a combined acid-leaching and electrolysis process, J. Hazard. Mater., 154(2008), No. 1-3, p. 588.
      [9]
      I.M. Valverde Jr., J.F. Paulino, and J.C. Afonso, Hydrometallurgical route to recover molybdenum, nickel, cobalt and aluminum from spent hydrotreating catalysts in sulphuric acid medium, J. Hazard. Mater., 160(2008), No. 2-3, p. 310.
      [10]
      H.I. Kim, K.H. Park, and D. Mishra, Influence of sulfuric acid baking on leaching of spent Ni-Mo/Al2O3 hydro-processing catalyst, Hydrometallurgy, 98(2009), No. 1-2, p. 192.
      [11]
      S.P. Barik, K.H. Park, P.K. Parhi, J.T. Park, and C.W. Nam, Extraction of metal values from waste spent petroleum catalyst using acidic solutions, Sep. Purif. Technol., 101(2012), p. 85.
      [12]
      A.L. Salgado, A.M.O. Veloso, D.D. Pereira, G.S. Gontijo, A. Salum, and M.B. Mansur, Recovery of zinc and manganese from spent alkaline batteries by liquid-liquid extraction with Cyanex 272, J. Power Sources., 115(2003), No. 2, p. 367.
      [13]
      K.H. Park, D. Mohapatra, and C.W. Nam, Two stage leaching of activated spent HDS catalyst and solvent extraction of aluminium using organo-phosphinic extractant, Cyanex 272, J. Hazard. Mater., 148(2007), No. 1-2, p. 287.
      [14]
      T. Havlik, D. Orac, M. Petranikova, A. Miskufova, F. Kukurugya, and Z. Takacova, Leaching of copper and tin from used printed circuit boards after thermal treatment, J. Hazard. Mater., 183(2010), No. 1-3, p. 866.
      [15]
      B.B. Kar, P. Datta, and V.N. Misra, Spent catalyst:secondary source for molybdenum recovery, Hydrometallurgy, 72(2004), No. 1-2, p. 87.
      [16]
      B.B. Kar, B.V.R. Murthy, and V.N. Misra, Extraction of molybdenum from spent catalyst by salt-roasting, Int. J. Miner. Process., 76(2005), No. 3, p. 143.
      [17]
      K.H. Park, B.R. Reddy, D. Mohapatra, and C.W. Nam, Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst, Int. J. Miner. Process., 80(2006), No. 2-4, p. 261.
      [18]
      K. Onol and M.N. Saridede, Investigation on microwave heating for direct leaching of chalcopyrite ores and concentrates, Int. J. Miner. Metall. Mater., 20(2013), No. 3, p. 228.
      [19]
      L.L. Wang, X.Z. Yuan, H. Zhong, H. Wang, Z.B. Wu, X.H. Chen, and G.M. Zeng, Release behavior of heavy metals during treatment of dredged sediment by microwave-assisted hydrogen peroxide oxidation, Chem. Eng. J., 258(2014), p. 334.
      [20]
      Z.Y. Ma, H.Y. Yang, S.T. Huang, Y. Lü, and L. Xiong, Ultra fast microwave-assisted leaching for the recovery of copper and tellurium from copper anode slime, Int. J. Miner. Metall. Mater., 22(2015), No. 6, p. 582.
      [21]
      Y.Z. Yuan, Y.M. Zhang, T. Liu, and T.J. Chen, Comparison of the mechanisms of microwave roasting and conventional roasting and of their effects on vanadium extraction from stone coal, Int. J. Miner. Metall. Mater., 22(2015), No. 5, p. 476.
      [22]
      R. Schmuhl, J.T. Smit, and J.H. Marsh, The influence of microwave pre-treatment of the leach behaviour of disseminated sulphide ore, Hydrometallurgy, 108(2011), No. 3-4, p. 157.
      [23]
      S.U. Bayca, Microwave radiation leaching of colemanite in sulfuric acid solutions, Sep. Purif. Technol., 105(2013), p. 24.
      [24]
      G. Chen, J. Chen, Z.Y. Zhang, S.H. Guo, Z.B. Zhang, J.H. Peng, C. Srinivasakannan, X.Q. Li, Y.K. Zhuang, and Z.M. Xu, Leaching of refractory gold ores by microwave irradiation:comparison with conventional leaching, Metallurgist, 57(2013), No. 7-8, p. 647.
      [25]
      M. Al-Harahsheh, S. Kingman, and S. Bradshaw, Scale up possibilities for microwave leaching of chalcopyrite in ferric sulphate, Int. J. Miner. Process., 80(2006), No. 2-4, p. 198.
      [26]
      M. Al-Harahsheh, S. Kingman, and S. Bradshaw, The reality of non-thermal effects in microwave assisted leaching systems?, Hydrometallurgy, 84(2006), No. 1-2, p. 1.
      [27]
      H.Y. Yang, Z.Y. Ma, S.T. Huang, Y. Lv, and L. Xiong, Intensification of pretreatment and pressure leaching of copper anode slime by microwave radiation, J. Cent. South Univ., 22(2015), No. 12, p. 4536.
      [28]
      M. Al-Harahsheh, S. Kingman, N. Hankins, C. Somerfield, S. Bradshaw, and W. Louw, The influence of microwaves on the leaching kinetics of chalcopyrite, Miner. Eng., 18(2005), No. 13-14, p. 1259.
      [29]
      M. Al-Harahsheh and S.W. Kingman, Microwave-assisted leaching-a review, Hydrometallurgy, 73(2004), No. 3-4, p. 189.
      [30]
      R.K. Amankwah and G. Ofori-Sarpong, Microwave heating of gold ores for enhanced grindability and cyanide amenability, Miner. Eng., 24(2011), No. 6, p. 541.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计