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Volume 26 Issue 7
Jul.  2019
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文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(7): 839-848
Ming-tao Mao, Han-jie Guo, Fei Wang,  and Xiao-lin Sun, Chemical composition and structural identification of primary carbides in as-cast H13 steel, Int. J. Miner. Metall. Mater., 26(2019), No. 7, pp. 839-848. https://doi.org/10.1007/s12613-019-1796-7
Cite this article as:
Ming-tao Mao, Han-jie Guo, Fei Wang,  and Xiao-lin Sun, Chemical composition and structural identification of primary carbides in as-cast H13 steel, Int. J. Miner. Metall. Mater., 26(2019), No. 7, pp. 839-848. https://doi.org/10.1007/s12613-019-1796-7
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研究论文

Chemical composition and structural identification of primary carbides in as-cast H13 steel

  • School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

  • Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials, Beijing 100083, China

  • Central Iron & Steel Research Institute, Beijing 100081, China

  • 通讯作者:

    Han-jie Guo    E-mail: guohanjie@ustb.edu.cn

  • The aim of this study was to characterize the primary carbides formed in as-cast H13 steel. The composition, morphology, type, and size of primary carbides in as-cast H13 steel were investigated by optical microscope (OM), field emission scanning electron microscopy (FE-SEM), electron back-scattered diffraction (EBSD), and X-ray diffraction (XRD) analysis. The number of primary carbides was investigated by ASPEX automated inclusion analysis system. The results indicated that primary carbides in as-cast H13 steel are mainly composed of Cr, Mo, V, and Ti, and there exist four kinds of primary carbides in the interdendritic zones of H13 steel, which are stripy Mo-Cr-rich M2C, eutectic Mo-Cr-rich M2C, V-rich MC, and V-rich MC with Ti and N. Thermodynamic calculation indicated that M2C precipitates in liquid phase at solid fractions larger than 0.99, while MC precipitates in liquid phase at solid fractions larger than 0.96. Statistical results indicated that the number of M2C is much greater than the number of other kinds of primary carbides. Most primary carbides are blocky, with lengths of no more than 10 μm and a length/width ratio of no more than 3. The large primary carbides in as-cast H13 steel are mainly M2C.
    • Research Article

    Chemical composition and structural identification of primary carbides in as-cast H13 steel

    + Author Affiliations
      Abstract
    • The aim of this study was to characterize the primary carbides formed in as-cast H13 steel. The composition, morphology, type, and size of primary carbides in as-cast H13 steel were investigated by optical microscope (OM), field emission scanning electron microscopy (FE-SEM), electron back-scattered diffraction (EBSD), and X-ray diffraction (XRD) analysis. The number of primary carbides was investigated by ASPEX automated inclusion analysis system. The results indicated that primary carbides in as-cast H13 steel are mainly composed of Cr, Mo, V, and Ti, and there exist four kinds of primary carbides in the interdendritic zones of H13 steel, which are stripy Mo-Cr-rich M2C, eutectic Mo-Cr-rich M2C, V-rich MC, and V-rich MC with Ti and N. Thermodynamic calculation indicated that M2C precipitates in liquid phase at solid fractions larger than 0.99, while MC precipitates in liquid phase at solid fractions larger than 0.96. Statistical results indicated that the number of M2C is much greater than the number of other kinds of primary carbides. Most primary carbides are blocky, with lengths of no more than 10 μm and a length/width ratio of no more than 3. The large primary carbides in as-cast H13 steel are mainly M2C.
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    • [1]
      D.L. Cong, H. Zhou, Z.N. Ren, H.F. Zhang, L.Q. Ren, C. Meng, and C.W. Wang, Thermal fatigue resistance of hot work die steel repaired by partial laser surface remelting and alloying process, Opt. Lasers Eng., 54(2014), p. 55.
      [2]
      Y.G. Zhao, Y.H. Liang, W. Zhou, Q.D. Qin, and Q.C. Jiang, Effect of a current pulse on the thermal fatigue behavior of cast hot work die steel, ISIJ Int., 45(2005), No. 3, p. 410.
      [3]
      J. Zhou, D.S. Ma, H.X. Chi, Z.Z. Chen, and X.Y. Li, Microstructure and properties of hot working die steel H13MOD, J. Iron Steel Res. Int., 20(2013), No. 9, p. 117.
      [4]
      X.L. Sun, H.J. Guo, X.C. Chen, A.G. Ning, G.W. Du, and C.B. Shi, Formation mechanism of primary carbide in H13 steel during electroslag remelting process, Iron Steel, 49(2014), No. 5, p. 68.
      [5]
      Y. Xie, G.G. Cheng, L. Chen, Y.D. Zhang, Q.Z. Yan, Mechanism of generation of large (Ti,Nb,V)(C,N)-type precipitates in H13+ Nb tool steel, Int. J. Miner. Metall. Mater., 23(2016), No. 11, p. 1264.
      [6]
      K. Ozaki, Effect of the distribution of primary carbide on fatigue strength of cold work die steels, DENKI-SEIKO, 76(2005), No. 4, p. 249.
      [7]
      L.L. Mishnaevsky Jr., N. Lippmann, and S. Schmauder, Micromechanisms and modelling of crack initiation and growth in tool steels:Role of primary carbides, Z. Metallkd., 94(2003), No. 6, p. 676.
      [8]
      K. Wieczerzak, P. Bała, M. Stępień, G. Cios, and T. KozieŁ, The characterization of cast Fe-Cr-C alloy, Arch. Metall. Mater., 60(2015), No. 2, p. 779.
      [9]
      M. Venkatraman and J.P. Neumann, The C-Cr (carbon-chromium) system, Bull. Alloy Phase Diagrams, 11(1990), No. 2, p. 152.
      [10]
      M. Hillert and C. Qiu, A reassessment of the Fe-Cr-Mo-C system, J. Phase Equilib., 13(1992), No. 5, p. 512.
      [11]
      A. Kroupa, J. Havránková, M. Svoboda, M. Coufalová, and J. Vřešt'ál, Phase diagram in the iron-rich corner of the Fe-Cr-Mo-V-C system below 1000 K, J. Phase Equilib., 22(2001), No. 3, p. 312.
      [12]
      Y.J. Shi, X.C. Wu, J.W. Li, and N. Min, Tempering stability of Fe-Cr-Mo-W-V hot forging die steels, Int. J. Miner. Metall. Mater., 24(2017), No. 10, p. 1145.
      [13]
      Ö.N. Doğan, J.A. Hawk, and G. Laird Ⅱ, Solidification structure and abrasion resistance of high chromium white irons, Metall. Mater. Trans. A, 28(1997), No. 6, p, 1315.
      [14]
      C.P. Tabrett, I.R. Sare, and M.R. Ghomashchi, Microstructure-property relationships in high chromium white iron alloys, Int. Mater. Rev., 41(1996), No. 2, p. 59.
      [15]
      A. Inoue, Y. Harakawa, M. Oguchi, and T. Masumoto, Metastable MC phase in melt-quenched Fe-C-V and Fe-C-V-(Cr or Mo) alloys-mechanical properties and powder-forming tendency by comminution, J. Mater. Sci., 21(1986), No. 4, p. 1310.
      [16]
      Y. Xie, G.G. Cheng, L. Chen, Y.D, Zhang, and Q.Z. Yan, Characteristics and generating mechanism of large precipitates in Nb-Ti-microalloyed H13 tool steel, ISIJ Int., 56(2016), No. 6, p. 995.
      [17]
      Y. Xie, G.G. Cheng, X.L. Meng, L. Chen, and Y.D. Zhang, Precipitation behavior of primary precipitates in Ti-microalloyed H13 tool steel, ISIJ Int., 56(2016), No. 11, p. 1996.
      [18]
      X.L. Sun, F. Wang, X.C. Chen, M.T. Mao, and H.J. Guo, Study on decomposition of primary carbonitrides in H13 steel under high temperature, Chin. J. Eng., 39(2017), No. 5, p. 721.
      [19]
      X.L. Sun, F. Wang, X.C. Chen, H.J. Guo, and M.T. Mao, Study on primary carbonitrides in H13 steel based on the two-sublattice model, Chin. J. Eng., 39(2017), No. 1, p. 61.
      [20]
      W.W. Song, Y.A. Min, and X.C. Wu, Study on carbides and their evolution in H13 hot work steel, Trans. Mater. Heat Treat., 30(2009), No. 5, p. 122.
      [21]
      Y.M. Won and B.G. Thomas, Simple model of microsegregation during solidification of steels, Metall. Mater. Trans. A, 32(2001), No. 7, p. 1755.
      [22]
      V. Raghavan, C-Cr-Fe-Mo-V (carbon-chromium-iron-molybdenum-vanadium), J. Phase Equilib. Diffus., 28(2007), No. 3, p. 286.
      [23]
      A.G. Ning, Investigation on Nanoscale Precipitates in Hot-work Die Steel and Comprehensive Strengthening Mechanism of Steel[Dissertation], University of Science and Technology Beijing, Beijing, 2015.
      [24]
      J. Miettinen, Mathematical simulation of interdendritic solidification of low-alloyed and stainless steels, Metall. Trans. A, 23(1992), No. 4, p. 1155.
      [25]
      T.W. Clyne and W. Kurz, Solute redistribution during solidification with rapid solid state diffusion, Metall. Trans. A, 12(1981), No. 6, p. 965.
      [26]
      J.X. Chen, Databook Commonly Used in Steelmaking, Metallurgical Industry Press, Beijing, 2010.
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