留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 8
Aug.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  603
  • HTML全文浏览量:  164
  • PDF下载量:  24
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(8): 946-952
Mehmet Deniz Turan, Optimization of selective copper extraction from chalcopyrite concentrate in presence of ammonium persulfate and ammonium hydroxide, Int. J. Miner. Metall. Mater., 26(2019), No. 8, pp. 946-952. https://doi.org/10.1007/s12613-019-1804-y
Cite this article as:
Mehmet Deniz Turan, Optimization of selective copper extraction from chalcopyrite concentrate in presence of ammonium persulfate and ammonium hydroxide, Int. J. Miner. Metall. Mater., 26(2019), No. 8, pp. 946-952. https://doi.org/10.1007/s12613-019-1804-y
shu
引用本文 PDF XML SpringerLink
研究论文

Optimization of selective copper extraction from chalcopyrite concentrate in presence of ammonium persulfate and ammonium hydroxide

  • Department of Metallurgical and Materials Engineering, Fırat University, Elazığ 23119, Turkey

  • 通讯作者:

    Mehmet Deniz Turan    E-mail: mdturan@firat.edu.tr

  • The dissolution of copper and iron from chalcopyrite concentrate in the presence of ammonium persulfate (APS) and ammonium hydroxide was investigated under atmospheric leaching conditions. Experiments were designed by central composite design (CCD). Under the optimum leaching conditions ((NH4)2S2O8 concentration=328 g/L; NH4OH addition=16vol%; leaching temperature=321 K (48℃); leaching time=120 min; liquid-to-solid ratio=16; stirring speed=400 r/min), selective leaching was achieved. 98.14% of the copper was leached, whereas iron did not pass into the solution. X-ray diffraction analysis of the leaching residue showed that iron compounds were predominant. Given the leaching results, the fact that the leaching process does not include uneconomical leaching stages such as extended milling/mechanical activation or high pressures/temperatures, and the low copper dissolution conditions, the attained selective leaching yield may be remarkable.
    • Research Article

    Optimization of selective copper extraction from chalcopyrite concentrate in presence of ammonium persulfate and ammonium hydroxide

    + Author Affiliations
      Abstract
    • The dissolution of copper and iron from chalcopyrite concentrate in the presence of ammonium persulfate (APS) and ammonium hydroxide was investigated under atmospheric leaching conditions. Experiments were designed by central composite design (CCD). Under the optimum leaching conditions ((NH4)2S2O8 concentration=328 g/L; NH4OH addition=16vol%; leaching temperature=321 K (48℃); leaching time=120 min; liquid-to-solid ratio=16; stirring speed=400 r/min), selective leaching was achieved. 98.14% of the copper was leached, whereas iron did not pass into the solution. X-ray diffraction analysis of the leaching residue showed that iron compounds were predominant. Given the leaching results, the fact that the leaching process does not include uneconomical leaching stages such as extended milling/mechanical activation or high pressures/temperatures, and the low copper dissolution conditions, the attained selective leaching yield may be remarkable.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(22)
    • [1]
      W.G. Davenport, M.J. King, M.E. Schlesinger, and A.K. Biswas, Extractive Metallurgy of Copper, Pergamon, London, 2002.
      [2]
      T.S. Qiu, G.H. Nie, J.F. Wang, and L.F. Cui, Kinetic process of oxidative leaching of chalcopyrite under low oxygen pressure and low temperature, Trans. Nonferrous Met. Soc. China, 17(2007), No. 2, p. 418.
      [3]
      M. Al-Harahsheh, S. Kingman, and A. Al-Harahsheh, Ferric chloride leaching of chalcopyrite:Synergetic effect of CuCl2, Hydrometallurgy, 91(2008), No. 1-4, p. 89.
      [4]
      F. Carranza, N. Iglesias, A. Mazuelos, I. Palencia, and R. Romero, Treatment of copper concentrates containing chalcopyrite and non-ferrous sulphides by the BRISA process, Hydrometallurgy, 71(2004), No. 3-4, p. 413.
      [5]
      R. Padilla, M. Rodriguez, and M.C Ruiz, Sulphidation of chalcopyrite with elemental sulphur, Metall. Mater. Trans. B, 34(2003), No. 1, p. 15.
      [6]
      M.D. Turan, Z.A. Sarı, and J.D. Miller, Leaching of blended copper slag in microwave oven, Trans. Nonferrous Met. Soc. China, 27(2017), No. 6, p. 1404.
      [7]
      M.D. Turan, M. Sarıkaya, Z.A. Sarı, A. Haxiaj, T. Depci, A. Demiraslan, and H. Nizamoğlu, Investigating and optimization of copper extraction from chalcopyrite concentrate with hydrogen peroxide in presence of acetic acid, Curr. Phys. Chem., 7(2017), No. 4, p. 267.
      [8]
      M.D. Turan, M. Boyrazlı, and H.S. Altundoğan, Improving of copper extraction from chalcopyrite by using NaCl, J. Cent. South Univ., 25(2018), No. 1, p. 21.
      [9]
      E.M. Córdoba, J.A. Muñoz, M.L. Blázquez, F. González, and A. Ballester, Leaching of chalcopyrite with ferric ion. Part Ⅲ:Effect of redox potential on the silver-catalyzed process, Hydrometallurgy, 93(2008), No. 3-4, p. 97.
      [10]
      S. Vafaeian, M. Ahmadian, and B. Rezaei, Sulphuric acid leaching of mechanically activated copper sulphidic concentrate, Miner. Eng., 24(2011), No. 15, p. 1713.
      [11]
      M. Chakravorty and S. Srikanth, Kinetics of salt roasting of chalcopyrite using KCl, Thermochim. Acta, 362(2000), No. 1-2, p. 25.
      [12]
      R. Padilla, E. Olivares, M.C. Ruiz, and H.Y. Sohn, Kinetics of the sulfidation of chalcopyrite with gaseous sulfur, Metall. Mater. Trans. B, 34(2003), No. 1, p. 61.
      [13]
      K. Tkáčová and P. Baláž, Reactivity of mechanically activated chalcopyrite, Int. J. Miner. Process., 44-45(1996), p. 197.
      [14]
      M.S. Bafghi, A.H. Emami, A. Zakeri, and J.V. Khaki, Effect of mechanical activation on the kinetics of leaching of chalcopyrite in the ferric sulfate media, Iran. J. Mater. Sci. Eng., 7(2010), No. 2, p. 30.
      [15]
      A. Katsiapi, P.E. Tsakiridis, P. Oustadakis, and S. Agatzini-Leonardou, Cobalt recovery from mixed Co-Mn hydroxide precipitates by ammonia-ammonium carbonate leaching, Miner. Eng., 23(2010), No. 8, p. 643.
      [16]
      R.K. Nadirov, L.I. Syzdykova, A.K. Zhussupova, and M.T. Usserbaev, Recovery of value metals from copper smelter slag by ammonium chloride treatment, Int. J. Miner. Process., 124(2013), p. 145.
      [17]
      D. Feng and J.S.J. Van Deventer, Leaching behaviour of sulphides in ammoniacal thiosulphate systems, Hydrometallurgy, 63(2002), No. 2, p. 189.
      [18]
      M.D. Turan and H.S. Altundoğan, Leaching of a copper flotation concentrate with ammonium persulfate in an autoclave system, Int. J. Miner. Metall. Mater., 21(2014), No. 9, p. 862.
      [19]
      M.D. Turan, Direct selective leaching of chalcopyrite concentrate, Can. Metall. Q., 53(2014), No. 4, p. 444.
      [20]
      M.D. Turan, H. Arslanoğlu, and H.S. Altundoğan, Optimization of the leaching conditions of chalcopyrite concentrate using ammonium persulfate in an autoclave system, J. Taiwan Inst. Chem. Eng., 50(2015), p. 49.
      [21]
      G.H. Jeffery, J. Bassett, J. Mendham, and R.C. Denney, Vogel's Textbook of Quantitative Chemical Analysis, Addison-Wesley Longman, London, 1989.
      [22]
      D.C. Montgomery, Design and Analysis of Experiments, John Wiley & Sons, USA, 2001.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计