留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 10
Oct.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  655
  • HTML全文浏览量:  134
  • PDF下载量:  19
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(10): 1239-1246
Peijia Lin, Jiajia Wu, Junmo Ahn,  and Jaeheon Lee, Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1239-1246. https://doi.org/10.1007/s12613-019-1832-7
Cite this article as:
Peijia Lin, Jiajia Wu, Junmo Ahn,  and Jaeheon Lee, Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1239-1246. https://doi.org/10.1007/s12613-019-1832-7
shu
引用本文 PDF XML SpringerLink
研究论文

Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay

  • Department of Mining and Geological Engineering, The University of Arizona, Tucson, AZ, 85721, USA

  • 通讯作者:

    Jaeheon Lee    E-mail: jaeheon@email.arizona.edu

  • An environmentally friendly organic biosorbent was fabricated using hay by succinylation. Metallic cation adsorption tests were performed using synthetic nickel(Ⅱ) and cadmium(Ⅱ) solutions to simulate heavy-metal recovery from aqueous solution. The adsorption efficiency was greater than 98% for both cadmium and nickel ions when the biosorbent concentration was 5.0 g/L and the initial metal concentrations were 50 mg/L. The surface of the biosorbent was characterized using Fourier transform infrared spectroscopy to investigate the changes in the surface functional groups. The functional groups changed according to the surface treatment, resulting in an effective biosorbent. The kinetics of the metals adsorption revealed that the reactions are pseudo-second order, and the adsorption isotherm well followed the Langmuir model. The maximum adsorption capacities predicted by the Langmuir model were 75.19 mg/g and 57.77 mg/g for cadmium and nickel, respectively. The fabricated biosorbent was regenerated using NaCl multiple times, with 2.1% for Cd and 4.0% for Ni in adsorption capacity after three regeneration cycles. The proposed biosorbent can be a good alternative to resin or other chemical adsorbents for heavy-metal recovery in metallurgical processing or municipal water treatment.
    • Research Article

    Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay

    + Author Affiliations
      Abstract
    • An environmentally friendly organic biosorbent was fabricated using hay by succinylation. Metallic cation adsorption tests were performed using synthetic nickel(Ⅱ) and cadmium(Ⅱ) solutions to simulate heavy-metal recovery from aqueous solution. The adsorption efficiency was greater than 98% for both cadmium and nickel ions when the biosorbent concentration was 5.0 g/L and the initial metal concentrations were 50 mg/L. The surface of the biosorbent was characterized using Fourier transform infrared spectroscopy to investigate the changes in the surface functional groups. The functional groups changed according to the surface treatment, resulting in an effective biosorbent. The kinetics of the metals adsorption revealed that the reactions are pseudo-second order, and the adsorption isotherm well followed the Langmuir model. The maximum adsorption capacities predicted by the Langmuir model were 75.19 mg/g and 57.77 mg/g for cadmium and nickel, respectively. The fabricated biosorbent was regenerated using NaCl multiple times, with 2.1% for Cd and 4.0% for Ni in adsorption capacity after three regeneration cycles. The proposed biosorbent can be a good alternative to resin or other chemical adsorbents for heavy-metal recovery in metallurgical processing or municipal water treatment.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(30)
    • [1]
      E. Rudnik and M. Nikiel, Hydrometallurgical recovery of cadmium and nickel from spent Ni–Cd batteries, Hydrometallurgy, 89(2007), No. 1-2, p. 61.
      [2]
      M.S. Safarzadeh, M.S. Bafghi, D. Moradkhani, and M.O. Ilkhchi, A review on hydrometallurgical extraction and recovery of cadmium from various resources, Miner. Eng., 20(2007), No. 3, p. 211.
      [3]
      A.M. Bernardes, D.C.R. Espinosa, and J.A.S. Tenório, Recycling of batteries: a review of current processes and technologies, J. Power Sources, 130(2004), No. 1-2, p. 291.
      [4]
      B. Belhalfaoui, A. Aziz, E.H. Elandaloussi, M.S. Ouali, and L.C. De Ménorval, Succinate-bonded cellulose: A regenerable and powerful sorbent for cadmium-removal from spiked high-hardness groundwater, J. Hazard. Mater., 169(2009), No. 1-3, p. 831.
      [5]
      H. Guo, S.F. Zhang, Z.N. Kou, S.R. Zhai, W. Ma, and Y. Yang, Removal of cadmium(Ⅱ) from aqueous solutions by chemically modified maize straw, Carbohydr. Polym., 115(2015), p. 177.
      [6]
      M.N. Khan and M.F. Wahab, Characterization of chemically modified corncobs and its application in the removal of metal ions from aqueous solution, J. Hazard. Mater., 141(2007), No. 1, p. 237.
      [7]
      X.Y. Hu, M.M. Zhao, G.S. Song, and H.H. Huang, Modification of pineapple peel fibre with succinic anhydride for Cu2+, Cd2+ and Pb2+ removal from aqueous solutions, Environ. Technol., 32(2011), No. 7, p. 739.
      [8]
      A. Aziz, E.H. Elandaloussi, B. Belhalfaoui, M.S. Ouali, and L.C. De Ménorval, Efficiency of succinylated-olive stone biosorbent on the removal of cadmium ions from aqueous solutions, Colloids Surf., B, 73(2009), No. 2, p. 192.
      [9]
      H.K. AN, B.Y. Park, and D.S. Kim, Crab shell for the removal of heavy metals from aqueous solution, Water Res., 35(2001), No. 15, p. 3551.
      [10]
      G. Pandey, Removal of Cd(Ⅱ) and Cu(Ⅱ) from aqueous solution using Bengal gram husk as a biosorbent, Desalin. Water Treat., 57(2016), No. 16, p. 7270.
      [11]
      M. Iqbal, N. Iqbal, I.A. Bhatti, N. Ahmad, and M. Zahid, Response surface methodology application in optimization of cadmium adsorption by shoe waste: A good option of waste mitigation by waste, Ecol. Eng., 88(2016), p. 265.
      [12]
      Y.Y. Deng, S. Huang, D.A. Laird, X.G. Wang, and C.Q. Dong, Quantitative mechanisms of cadmium adsorption on rice straw and swine manure-derived biochars, Environ. Sci. Pollut. Res., 25(2018), No. 32, p. 32418.
      [13]
      X.M. Zhao, L.A. Yao, Q.L. Ma, G.J. Zhou, L. Wang, Q.L. Fang, and Z.C. Xu, Distribution and ecological risk assessment of cadmium in water and sediment in Longjiang River, China: Implication on water quality management after pollution accident, Chemosphere, 194(2018), p. 107.
      [14]
      C.R.T. Tarley, S.L.C. Ferreira, and M.A.Z. Arruda, Use of modified rice husks as a natural solid adsorbent of trace metals: characterisation and development of an on-line preconcentration system for cadmium and lead determination by FAAS, Microchem. J., 77(2004), No. 2, p. 163.
      [15]
      S. Hokkanen, A. Bhatnagar, and M. Sillanpää, A review on modification methods to cellulose-based adsorbents to improve adsorption capacity, Water Res., 91(2016), p. 156.
      [16]
      J. Lehrfeld, Concersion of agricultural residues into cation exchange materialse, J. Appl. Polym. Sci., 61(1996), No. 12, p. 2099.
      [17]
      O. Karnitz Jr., L.V.A. Gurgel, J.C.P. de Melo, V.R. Botano, T.M.S. Melo, R.P. de Freitas Gil, and L.F. Gil, Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse, Bioresour. Technol., 98(2007), No. 6, p. 1291.
      [18]
      C.F. Liu, R.C. Sun, M.H. Qin, A.P. Zhang, J.L. Ren, J. Ye, W. Luo, and Z.N. Cao, Succinoylation of sugarcane bagasse under ultrasound irradiation, Bioresour Technol, 99(2008), No. 5, p. 1465.
      [19]
      E. Nabedryk, Characterization of the photoreduction of the secondary quinone QB in the photosynthetic reaction center from Rhodobacter capsulatus with FTIR spectroscopy, Biochim. Biophys. Acta Bioenerg., 1411(1999), No. 1, p. 206.
      [20]
      N. Fiol, I. Villaescusa, M. Martinez, N. Miralles, J. Poch, and J. Serarols, Sorption of Pb(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Cd(Ⅱ) from aqueous solution by olive stone waste, Sep. Purif. Technol., 50(2006), No. 1, p. 132.
      [21]
      Y.S. Ho, Review of second-order models for adsorption systems, J. Hazard. Mater., 136(2006), No. 3, p. 681.
      [22]
      Y.S. Ho and G. McKay, A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents, Process Saf. Environ. Prot., 76(1998), No. 4, p. 332.
      [23]
      M. Tanzifi, M.K. Nezhad, and K. Karimipour, Kinetic and isotherm studies of cadmium adsorption on polypyrrole/titanium dioxide nanocomposite, J. Water Environ. Nanotechnol., 2(2017), No. 4, p. 265.
      [24]
      M.B. Desta, Batch sorption experiments: Langmuir and freundlich isotherm studies for the adsorption of textile metal ions onto teff straw (Eragrostis tef) agricultural waste, Int. J. Thermodyn., 2013(2013), art. No. 375830.
      [25]
      V.B.H. Dang, H.D. Doan, T. Dang-Vu, and A. Lohi, Equilibrium and kinetics of biosorption of cadmium(Ⅱ) and copper(Ⅱ) ions by wheat straw, Bioresour. Technol., 100(2009), No. 1, p. 211.
      [26]
      M. Arshadi, M.J. Amiri, and S. Mousavi, Kinetic, equilibrium and thermodynamic investigations of Ni(Ⅱ), Cd(Ⅱ), Cu(Ⅱ) and Co(Ⅱ) adsorption on barley straw ash, Water Resour. Ind., 6(2014), p. 1.
      [27]
      Y. Ding, D.B. Jing, H.L. Gong, L.B. Zhou, and X.S. Yang, Biosorption of aquatic cadmium(Ⅱ) by unmodified rice straw, Bioresour. Technol., 114(2012), p. 20.
      [28]
      P.O. Boamah, Y. Huang, M.Q. Hua, Q. Zhang, Y.Y. Liu, J. Onumah, W. Wang, and Y.X. Song, Removal of cadmium from aqueous solution using low molecular weight chitosan derivative, Carbohydr. Polym., 122(2015), p. 255.
      [29]
      D. Mohan, C.U. Pittman Jr., and P.H. Steele, Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on Kraft lignin—a biosorbent, J. Colloid Interface Sci., 297(2006), No. 2, p. 489.
      [30]
      L.V.A. Gurgel, O.K. Júnior, R.P. de Freitas Gil, and L.F. Gil, Adsorption of Cu(Ⅱ), Cd(Ⅱ), and Pb(Ⅱ) from aqueous single metal solutions by cellulose and mercerized cellulose chemically modified with succinic anhydride, Bioresour. Technol., 99(2008), No. 8, p. 3077.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计