留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 12
Dec.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  791
  • HTML全文浏览量:  139
  • PDF下载量:  18
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(12): 1570-1577
Muhammad Ahsan Iqbal and Michele Fedel, Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1570-1577. https://doi.org/10.1007/s12613-019-1844-3
Cite this article as:
Muhammad Ahsan Iqbal and Michele Fedel, Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1570-1577. https://doi.org/10.1007/s12613-019-1844-3
shu
引用本文 PDF XML SpringerLink
研究论文

Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties

  • Department of Industrial Engineering, University of Trento, via Sommarive 9, Povo (TN), 38123, Italy

  • 通讯作者:

    Muhammad Ahsan Iqbal    E-mail: muhammadahsan.iqbal@unitn.it

  • A MgAl-layered double hydroxide (MgAl-LDH) protective film was developed on AA6082 substrates via the in situ hydrothermal growth method to obtain a distinct cauliflower-like LDH structure, and coated substrates were further heat-treated in air at temperatures from 100 to 250℃ to further improve the corrosion resistance of MgAl-LDH by taking advantage of the LDH memory effect; also, the effect of calcination on MgAl-LDH structural stability and the corresponding corrosion resistance properties were investigated. The structural characterization of uncalcined and calcined LDH films were examined using scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry, and Fourier transform infrared spectroscopy. The corresponding corrosion protection efficiency of the developed coating was studied through potentiodynamic polarization experiments and by electrochemical impedance spectroscopy. Compared with uncalcined MgAl-LDH, the calcined film showed a relatively lower corrosion current density and a higher impedance value, especially after heat treatment at 250℃. The findings demonstrate that calcination strongly affects the oriented growth of the LDH and causes an increase in the surface area and contraction of the basal spacing, which in turn caused a compact structure that substantially influenced the LDH corrosion resistance properties.
    • Research Article

    Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties

    + Author Affiliations
      Abstract
    • A MgAl-layered double hydroxide (MgAl-LDH) protective film was developed on AA6082 substrates via the in situ hydrothermal growth method to obtain a distinct cauliflower-like LDH structure, and coated substrates were further heat-treated in air at temperatures from 100 to 250℃ to further improve the corrosion resistance of MgAl-LDH by taking advantage of the LDH memory effect; also, the effect of calcination on MgAl-LDH structural stability and the corresponding corrosion resistance properties were investigated. The structural characterization of uncalcined and calcined LDH films were examined using scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry, and Fourier transform infrared spectroscopy. The corresponding corrosion protection efficiency of the developed coating was studied through potentiodynamic polarization experiments and by electrochemical impedance spectroscopy. Compared with uncalcined MgAl-LDH, the calcined film showed a relatively lower corrosion current density and a higher impedance value, especially after heat treatment at 250℃. The findings demonstrate that calcination strongly affects the oriented growth of the LDH and causes an increase in the surface area and contraction of the basal spacing, which in turn caused a compact structure that substantially influenced the LDH corrosion resistance properties.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(36)
    • [1]
      J.R. Davis, Corrosion of Aluminum and Aluminum Alloys, Asm International, Materials Park, 1999.
      [2]
      R. Winston Revie, Uhlig's Corrosion Handbook, 3rd Ed., John Wiley & Sons, New Jersey, 2011.
      [3]
      X. Klodian and M. Finšgar, Organic corrosion inhibitors for aluminium and its alloys in acid solutions:A review, RSC Adv., 6(2016), No. 67, p. 62833.
      [4]
      O. Zubillaga, F.J. Cano, I. Azkarate, I.S. Molchan, G.E. Thompson, and P. Skeldon, Anodic films containing polyaniline and nanoparticles for corrosion protection of AA2024T3 aluminium alloy, Surf. Coat. Technol., 203(2009), No. 10-11, p. 1494.
      [5]
      G. Boisier, A. Lamure, N. Pébère, N. Portail, and M. Villatte, Corrosion protection of AA2024 sealed anodic layers using the hydrophobic properties of carboxylic acids, Surf. Coat. Technol., 203(2009), No. 22, p. 3420.
      [6]
      F. Leroux and C. Taviot-Guého, Fine tuning between organic and inorganic host structure:New trends in layered double hydroxide hybrid assemblies, J. Mater. Chem., 35-36(2005), No. 15, p. 3628.
      [7]
      D.G. Evans and X. Duan, Preparation of layered double hydroxides and their applications as additives in polymers, as precursors to magnetic materials and in biology and medicine, Chem. Commun., 5(2006), p. 485.
      [8]
      D.G. Evans and R.C.T. Slade, Structural aspects of layered double hydroxides,[in] Layered Double Hydroxides, Springer, Berlin, Heidelberg, 2006, p. 1.
      [9]
      F. Bergaya and G. Lagaly, General introduction:Clays, clay minerals, and clay science, Dev. Clay Sci., 1(2006), p. 1.
      [10]
      S. Miyata, Physico-chemical properties of synthetic hydrotalcites in relation to composition, Clays Clay Miner., 28(1980), No. 1, p. 50.
      [11]
      R. Chitrakar, A. Sonoda, Y. Makita, and T. Hirotsu, Calcined Mg-Al layered double hydroxides for uptake of trace levels of bromate from aqueous solution, Ind. Eng. Chem. Res., 50(2011), No. 15, p. 9280.
      [12]
      K. Ye, L.N. Zhao, S. Zhang, F.Z. Zhang, M.D. Dong, and S.L. Xu, Morphologies, preparations and applications of layered double hydroxide micro-/nanostructures, Materials, 3(2010), No. 12, p. 5220.
      [13]
      Q.D. Ren, G. Wang, T.T. Wu, X. He, J.R. Wang, J. Yang, C. Yu, and J.S. Qiu, Calcined MgAl-layered double hydroxide/graphene hybrids for capacitive deionization, Ind. Eng. Chem. Res., 57(2018), No. 18, p. 6417.
      [14]
      X.Y. Yuan, Y.F. Wang, J. Wang, C. Zhou, Q. Tang, and X.B. Rao, Calcined graphene/MgAl-layered double hydroxides for enhanced Cr(VI) removal, Chem. Eng. J., 221(2013), p. 204.
      [15]
      T.P.F. Thaísa, S.F. Aquino, S.I. Pereira, and A. Dias, Use of calcined layered double hydroxides for the removal of color and organic matter from textile effluents:kinetic, equilibrium and recycling studies, Braz. J. Chem. Eng., 31(2014), No. 1, p. 19.
      [16]
      M.A. Iqbal and M. Fedel, The effect of the surface morphologies on the corrosion resistance of in situ growth MgAl-LDH based conversion film on AA6082, Surf. Coat. Technol., 352(2018), p. 166.
      [17]
      B.D. Cullity and S.R. Stock, Elements of X-ray Diffraction, Pearson, London, 2001.
      [18]
      R. Chitrakar, S. Tezuka, A. Sonoda, K. Sakane, and T. Hirotsu, A New method for synthesis of Mg-Al, Mg-Fe, and Zn-Al layered double hydroxides and their uptake properties of bromide ion, Ind. Eng. Chem. Res., 47(2008), No. 14, p. 4905.
      [19]
      F. Zhang, C.L. Zhang, L. Song, R.C. Zeng, Z.G. Liu, and H.Z. Cui, Corrosion of in-situ grown MgAl-LDH coating on aluminum alloy, Trans. Nonferrous Met. Soc. China, 25(2015), No. 10, p. 3498.
      [20]
      Q. Wang, H. Huang, J. Weig, L.W. Chen, Y. Liu, J. Chang, Z.Y. Zhong, J.Z. Luo, and A. Borgna, The effect of trivalent cations on the performance of Mg-M-CO3 layered double hydroxides for high-temperature CO2 capture, ChemSusChem, 3(2010), No. 8, p. 965.
      [21]
      M.Z.B Hussein, T.Y. Yun-Hin, M.M. bin Tawang, and R. Shahadan. Thermal degradation of (zinc-aluminium-layered double hydroxide-dioctyl sulphosuccinate) nanocomposite, Mater. Chem. Phys., 74(2002), No. 3, p. 265.
      [22]
      B.E. Warren and P. Bodenstein, The shape of two-dimensional carbon black reflections, Acta Crystallogr., 20(1966), p. 602.
      [23]
      S. Aisawa, H.i Hirahara, H. Uchiyama, S. Takahashi, and E. Narita, Synthesis and thermal decomposition of Mn-Al layered double hydroxides, J. Solid State Chem., 167(2002), No. 1, p. 152.
      [24]
      Q.L. Wu, A. Olafsen, Ø.B. Vistad, J. Roots, and P. Norby, Delamination and restacking of a layered double hydroxide with nitrate as counter anion, J. Mater. Chem., 15(2005), No. 44, p. 4695.
      [25]
      J.T. Kloprogge and R.L. Frost, Fourier transform infrared and Raman spectroscopic study of the local structure of Mg-, Ni-, and Co-hydrotalcites, J. Solid State Chem., 146(1999), No. 2, p. 506.
      [26]
      Z.M. Ni, S.J. Xia, C.P. Fang, L.G. Wang, and J. Hu, Synthesis, characterization and thermal property of Cu/Co/Mg/Al hydrotalcite like compounds, Rare Met. Mater. Eng., 37(2008), Suppl. 2, p. 634.
      [27]
      B.R. Venugopal, C. Shivakumara, and M. Rajamathi, A composite of layered double hydroxides obtained through random costacking of layers from Mg-Al and Co-Al LDHs by delamination-restacking:Thermal decomposition and reconstruction behavior, Solid State Sci., 9(2007), No. 3-4, p. 287.
      [28]
      F.Y. Wang and Z.G. Guo, Insitu growth of durable superhydrophobic Mg-Al layered double hydroxides nanoplatelets on aluminum alloys for corrosion resistance, J. Alloys Compd., 767(2018), p. 382.
      [29]
      F. Zhang, C.L. Zhang, L. Song, R.C. Zeng, Z.G. Liu, and H.Z. Cui, Corrosion of in-situ grown MgAl-LDH coating on aluminum alloy, Trans. Nonferrous Met. Soc. China, 25(2015), No. 10, p. 3498.
      [30]
      X.Y. Ke, S.A. Bernal, and J.L. Provis, Uptake of chloride and carbonate by Mg-Al and Ca-Al layered double hydroxides in simulated pore solutions of alkali-activated slag cement, Cem. Concr. Res., 100(2017), p. 1.
      [31]
      M.A. Iqbal and M. Fedel, Effect of synthesis conditions on the controlled growth of MgAl-LDH corrosion resistance film:Structure and corrosion resistance properties, Coatings, 9(2019), No. 30, p. 1.
      [32]
      F. Zhang, Z.G. Liu, R.C. Zeng, S.Q. Li, H.Z. Cui, L. Song, and E.H. Han, Corrosion resistance of Mg-Al-LDH coating on magnesium alloy AZ31, Surf. Coat. Technol., 258(2014), p. 1152.
      [33]
      K.D. Lin, X.H. Luo, X.Y. Pan, C.X. Zhang, and Y.L. Liu, Enhanced corrosion resistance of LiAl-layered double hydroxide (LDH) coating modified with a Schiff base salt on aluminum alloy by one step in-situ synthesis at low temperature, Appl. Surf. Sci., 463(2019), p. 1085.
      [34]
      Q. Wang and D. O'Hare, Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets, Chem. Rev., 112(2012), No. 7, p. 4124.
      [35]
      A. Elhalil, M. Farnane, A. Machrouhi, F.Z. Mahjoubi, R. Elmoubarki, H. Tounsadi, M. Abdennouri, and N. Barka, Effects of molar ratio and calcination temperature on the adsorption performance of Zn/Al layered double hydroxide nanoparticles in the removal of pharmaceutical pollutants, J. Sci.:Adv. Mater. Devices, 3(2018), No. 2, p. 188.
      [36]
      Z.X. Yan, B.C. Zhu, J.G. Yu, and Z.H. Xu, Effect of calcination on adsorption performance of Mg-Al layered double hydroxide prepared by a water-in-oil microemulsion method, RSC Adv., 6(2016), No. 55, p. 50128.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计