留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 9
Sep.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  582
  • HTML全文浏览量:  122
  • PDF下载量:  27
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(9): 1151-1165
Di Wu, Wan-lin Wang, Li-gang Zhang, Zhen-yu Wang, Ke-chao Zhou, and Li-bin Liu, New high-strength Ti-Al-V-Mo alloy: from high-throughput composition design to mechanical properties, Int. J. Miner. Metall. Mater., 26(2019), No. 9, pp. 1151-1165. https://doi.org/10.1007/s12613-019-1854-1
Cite this article as:
Di Wu, Wan-lin Wang, Li-gang Zhang, Zhen-yu Wang, Ke-chao Zhou, and Li-bin Liu, New high-strength Ti-Al-V-Mo alloy: from high-throughput composition design to mechanical properties, Int. J. Miner. Metall. Mater., 26(2019), No. 9, pp. 1151-1165. https://doi.org/10.1007/s12613-019-1854-1
shu
引用本文 PDF XML SpringerLink
研究论文

New high-strength Ti-Al-V-Mo alloy: from high-throughput composition design to mechanical properties

  • School of Metallurgy and Environment, Central South University, Changsha 410083, China

  • School of Material Science and Engineering, Central South University, Changsha 410083, China

  • Key Laboratory of Non-Ferrous Metallic Materials Science and Engineering, Ministry of Education, Changsha 410083, China

  • State Key Laboratory of Powder Metallurgy, Changsha 410083, China

  • 通讯作者:

    Ke-chao Zhou    E-mail: zhoukechao@csu.edu.cn

    Li-bin Liu    E-mail: lbliu@csu.edu.cn

  • The high-throughput diffusion-multiple technique and thermodynamics databases were used to design new high-strength Ti alloys. The composition-microstructure-property relationships of the Ti64-xMo alloys were obtained. The phase fraction and composition of the α and β phases of the Ti64-xMo alloys were calculated using the Thermo-Calc software. After aging at 600℃, the Ti64-6Mo alloy precipitated ultrafine α phases. This phenomenon was explained on the basis of the pseudo-spinodal mechanism by calculating the Gibbs energy curves of the α and β phases of the Ti64-xMo alloys at 600℃. Bulk forged Ti64-6Mo alloy exhibited high strength and moderate plasticity after α/β-phase-field solution treatment plus aging. The tensile properties of the alloy were determined by the size and morphology of the primary and secondary α phases and by the β grain size.
    • Research Article

    New high-strength Ti-Al-V-Mo alloy: from high-throughput composition design to mechanical properties

    + Author Affiliations
      Abstract
    • The high-throughput diffusion-multiple technique and thermodynamics databases were used to design new high-strength Ti alloys. The composition-microstructure-property relationships of the Ti64-xMo alloys were obtained. The phase fraction and composition of the α and β phases of the Ti64-xMo alloys were calculated using the Thermo-Calc software. After aging at 600℃, the Ti64-6Mo alloy precipitated ultrafine α phases. This phenomenon was explained on the basis of the pseudo-spinodal mechanism by calculating the Gibbs energy curves of the α and β phases of the Ti64-xMo alloys at 600℃. Bulk forged Ti64-6Mo alloy exhibited high strength and moderate plasticity after α/β-phase-field solution treatment plus aging. The tensile properties of the alloy were determined by the size and morphology of the primary and secondary α phases and by the β grain size.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(48)
    • [1]
      H.X. Li, X.Y. Nie, Z.B. He, K.N. Zhao, Q. Du, J.S. Zhang, and L.Z. Zhuang, Interfacial microstructure and mechanical properties of Ti-6Al-4V/Al7050 joints fabricated using the insert molding method, Int. J. Miner. Metall. Mater., 24(2017), No. 12, p. 1412.
      [2]
      M.K. Ibrahim, E. Hamzah, S.N. Saud, E.N.E. Abu Bakar, and A. Bahador, Microwave sintering effects on the microstructure and mechanical properties of Ti-51at% Ni shape memory alloys, Int. J. Miner. Metall. Mater., 24(2017), No. 3, p. 280.
      [3]
      R.R. Boyer, An overview on the use of titanium in the aerospace industry, Mater. Sci. Eng. A, 213(1996), No. 1-2, p. 103.
      [4]
      T.N. Prasanthi, C. Sudha, and S. Saroja, Effect of alloying elements on interdiffusion phenomena in explosive clads of 304LSS/Ti-5Ta-2Nb alloy, J. Mater. Sci., 51(2016), No. 11, p. 5290.
      [5]
      H.P. Duan, H.X. Xu, W.H. Su, Y.B. Ke, Z.Q. Liu, and H.H. Song, Effect of oxygen on the microstructure and mechanical properties of Ti-23Nb-0.7Ta-2Zr alloy, Int. J. Miner. Metall. Mater., 19(2012), No. 12, p. 1128.
      [6]
      S.L. Semiatin, P.N. Fagin, M.G. Glavicic, I.M. Sukonnik, and O.M. Ivasishin, Influence on texture on beta grain growth during continuous annealing of Ti-6Al-4V, Mater. Sci. Eng. A, 299(2001), No. 1-2, p. 225.
      [7]
      Y.J. Lai, S.W. Xin, P.X. Zhang, Y.Q. Zhao, F.J. Ma, X.H. Liu, and Y. Feng, Recrystallization behavior of Ti40 burn-resistant titanium alloy during hot working process, Int. J. Miner. Metall. Mater., 23(2016), No. 5, p 581.
      [8]
      T. Seshacharyulu, S.C. Medeiros, J.T. Morgan, J.C. Malas, W.G. Frazier, and Y.V.R.K. Prasad, Hot deformation and microstructural damage mechanisms in extra-low interstitial (ELI) grade Ti-6Al-4V, Mater. Sci. Eng. A, 279(2000), No. 1-2, p. 289.
      [9]
      A. Nocivin, I. Cinca, D. Raducanu, V.D. Cojocaru, and I.A. Popovici, Mechanical properties of a Gum-type Ti-Nb-Zr-Fe-O alloy, Int. J. Miner. Metall. Mater., 24(2017), No. 8, p. 909.
      [10]
      S. Raghunathan, R.J. Dashwood, M. Jackson, S.C. Vogel, and D. Dye, The evolution of microtexture and macrotexture during subtransus forging of Ti-10V-2Fe-3Al, Mater. Sci. Eng. A, 488(2008), No. 1-2, p. 8.
      [11]
      G.T. Terlinde, T.W. Duerig, and J.C. Williams, Microstructure, tensile deformation, and fracture in aged ti 10V-2Fe-3Al, Metall. Trans. A, 14(1983), No. 10, p. 2101.
      [12]
      B. He, X.J. Tian, X. Cheng, J. Li, and H.M. Wang, Effect of weld repair on microstructure and mechanical properties of laser additive manufactured Ti-55511 alloy, Mater. Des., 119(2017), p. 437.
      [13]
      S. Nag, R. Banerjee, J.Y. Hwang, M. Harper, and H.L. Fraser, Elemental partitioning between α and β phases in the Ti-5Al-5Mo-5V-3Cr-0.5Fe (Ti-5553) alloy, Philos. Mag., 89(2009), No. 6, p. 535.
      [14]
      F.W. Chen, G.L. Xu, X.Y. Zhang, K.C. Zhou, and Y.W. Cui, Effect of α morphology on the diffusional β↔α transformation in Ti-55531 during continuous heating:Dissection by dilatometer test, microstructure observation and calculation, J. Alloys Compd., 702(2017), No. 25, p. 352.
      [15]
      J.K. Fan, J.S. Li, H.C. Kou, K. Hua, and B. Tang, The interrelationship of fracture toughness and microstructure in a new near β titanium alloy Ti-7Mo-3Nb-3Cr-3Al, Mater. Charact., 96(2014), p. 93.
      [16]
      B. Cherukuri, R. Srinivasan, S. Tamirisakandala, and D.B. Miracle, The influence of trace boron addition on grain growth kinetics of the beta phase in the beta titanium alloy Ti-15Mo-2.6Nb-3Al-0.2Si, Scripta Mater., 60(2009), No. 7, p. 496.
      [17]
      N.G. Jones, R.J. Dashwood, M. Jackson, and D. Dye, Development of chevron-shaped α precipitates in Ti-5Al-5Mo-5V-3Cr, Scripta Mater., 60(2009), No. 7, p. 571.
      [18]
      A. Dehghan-Manshadi and R.J. Dippenaar, Development of α-phase morphologies during low temperature isothermal heat treatment of a Ti-5Al-5Mo-5V-3Cr alloy, Mater. Sci. Eng. A, 528(2011), No. 3, p 1833.
      [19]
      J.K. Fan, H.C. Kou, M.J. Lai, B. Tang, H. Chang, and J.S. Li, Characterization of hot deformation behavior of a new near beta titanium alloy:Ti-7333, Mater. Des., 49(2013), p. 945.
      [20]
      J.I. Qazi, H.J. Rack, and B. Marquardt, High-strength metastable beta-titanium alloys for biomedical applications, JOM, 56(2004), No. 11, p. 49.
      [21]
      R. Banerjee, S. Nag, J. Stechschulte, and H.L. Fraser, Strengthening mechanisms in Ti-Nb-Zr-Ta and Ti-Mo-Zr-Fe orthopaedic alloys, Biomaterials, 25(2004), No. 17, p. 3413.
      [22]
      T. Zhou, M. Aindow, S.P. Alpay, M.J. Blackburn, and M.H. Wu, Pseudo-elastic deformation behavior in a Ti/Mo-based alloy, Scripta Mater., 50(2004), No. 3, p. 343.
      [23]
      T. Oyama, C. Watanabe, and R. Monzen, Growth kinetics of ellipsoidal ω-precipitates in a Ti-20 wt%Mo alloy under compressive stress, J. Mater. Sci., 51(2016), No. 19, p. 8880.
      [24]
      C.H. Wang, C.D. Yang, M. Liu, X. Li, P.F. Hu, A.M. Russell, and G.H. Cao, Martensitic microstructures and mechanical properties of as-quenched metastable β-type Ti-Mo alloys, J. Mater. Sci., 51(2016), No. 14, p. 6886.
      [25]
      R. Monzen, R. Kawai, T. Oyama, and C. Watanabe, Tensile-stress-induced growth of ellipsoidal ω-precipitates in a Ti-20wt%Mo Alloy, J. Mater. Sci., 51(2016), No. 5, p. 2490.
      [26]
      J.C. Zhao, A combinatorial approach for efficient mapping of phase diagrams and properties, J. Mater. Res., 16(2001), No. 6, p. 1565.
      [27]
      J.C. Zhao, X. Zheng, and D.G. Cahill, High-throughput diffusion multiples, Mater. Today, 8(2005), No. 10, p. 28.
      [28]
      J.C. Zhao, X. Zheng, and D.G. Cahill, High-throughput measurements of materials properties, JOM, 63(2011), No. 3, p. 40.
      [29]
      X. Zheng, D.G. Cahill, P. Krasnochtchekov, R.S. Averback, and J.C. Zhao, High-throughput thermal conductivity measurements of nickel solid solutions and the applicability of the Wiedemann-Franz law, Acta Mater., 55(2007), No. 15, p. 5177.
      [30]
      X.D. Zhang, L.B. Liu, J.C. Zhao, J.L. Wang, F. Zheng, and Z.P. Jin, High-efficiency combinatorial approach as an effective tool for accelerating metallic biomaterials research and discovery, Mater. Sci. Eng. C, 39(2014), No. 1, p. 273.
      [31]
      D. Wu, L.B. Liu, L.G. Zhang, L.J. Zeng, and X. Shi, Investigation of the influence of Cr on the microstructure and properties of Ti6Al4VxCr alloys with a combinatorial approach, J. Mater. Eng. Perform., 26(2017), No. 9, p. 4364.
      [32]
      C. Wang, N. Li, Y. Cui, and M.T. Pérez-Prado, Effect of solutes on the rate sensitivity in Ti-xAl-yMo-zV and Ti-xAl-yMo-zCr β-Ti alloys, Scripta Mater., 149(2018), p. 129.
      [33]
      J.C. Williams and B.S. Hickman, Tempering behavior of orthorhombic martensite in titanium alloys, Metall. Mater. Trans. B, 1(1970), No. 9, p. 2648.
      [34]
      H.Y. Kim, Y. Ikehara, J.I. Kim, H. Hosoda, and S. Miyazaki, Martensitic transformation, shape memory effect and superelasticity of Ti-Nb binary alloys, Acta Mater., 54(2006), No. 9, p. 2419.
      [35]
      W.F. Ho, S.C. Wu, S.K. Hsu, Y.C. Li, and H.C. Hsu, Effects of molybdenum content on the structure and mechanical properties of as-cast Ti-10Zr-based alloys for biomedical applications, Mater. Sci. Eng. C, 32(2012), No. 3, p. 517.
      [36]
      W.F. Ho, S.C. Wu, H.H. Chang, and H.C. Hsu, Structure and mechanical properties of Ti-5Cr based alloy with Mo addition, Mater. Sci. Eng. C, 30(2010), No. 6, p. 904.
      [37]
      Z. Du, S. Xiao, L. Xu, J. Tian, F. Kong, and Y. Chen, Effect of heat treatment on microstructure and mechanical properties of a new β high strength titanium alloy, Mater. Des., 55(2014), No. 55, p. 183.
      [38]
      W.F. Ho, C.P. Ju, and J.H. Lin, Structure and properties of cast binary Ti-Mo alloys, Biomaterials, 20(1999), No. 22, p. 2115.
      [39]
      Y. Ni and A.G. Khachaturyan, From chessboard tweed to chessboard nanowire structure during pseudospinodal decomposition, Nat. Mater., 8(2009), No. 5, p. 410.
      [40]
      N.T.C. Oliveira and A.C. Guastaldi, Electrochemical stability and corrosion resistance of Ti-Mo alloys for biomedical applications, Acta Biomater., 5(2009), No. 1, p. 399.
      [41]
      S.K. Kar, A. Ghosh, N. Fulzele, and A. Bhattacharjee, Quantitative microstructural characterization of a near beta Ti alloy, Ti-5553 under different processing conditions, Mater. Charact., 81(2013), No. 4, p. 37.
      [42]
      C.Y. Wang, L.W. Yang, Y.W. Cui, and M.T. Pérez-Prado, High throughput analysis of solute effects on the mechanical behavior and slip activity of beta titanium alloys, Mater. Des., 137(2017), p. 371.
      [43]
      L. Mora, C. Quesne, C. Haut, C. Servant, and R. Penelle, Relationships among thermomechanical treatments, microstructure, and tensile properties of a near beta-titanium alloy:β-CEZ:Part I. relationships between thermomechanical treatments and microstructure, J. Mater. Res., 11(1996), No. 1, p. 89.
      [44]
      G. Srinivasu, Y. Natraj, A. Bhattacharjee, T.K. Nandy, and G.V.S.N. Rao, Tensile and fracture toughness of high strength β titanium alloy, Ti-10V-2Fe-3Al, as a function of rolling and solution treatment temperatures, Mater. Des., 47(2013), p. 323.
      [45]
      J. Huang, Z. Wang, and K. Xue, Cyclic deformation response and micromechanisms of Ti alloy Ti-5Al-5V-5Mo-3Cr-0.5Fe, Mater. Sci. Eng. A, 528(2011), No. 29-30, p. 8723.
      [46]
      M. Jackson, N.G. Jones, D. Dye, and R.J. Dashwood, Effect of initial microstructure on plastic flow behaviour during isothermal forging of Ti-10V-2Fe-3Al, Mater. Sci. Eng. A, 501(2009), No. 1-2, p. 248.
      [47]
      D. Qin, Y. Lu, D. Guo, L. Zheng, Q. Liu, and L. Zhou, Tensile deformation and fracture of Ti-5Al-5V-5Mo-3Cr-1.5Zr-0.5Fe alloy at room temperature, Mater. Sci. Eng. A, 587(2013), p. 100.
      [48]
      W.F. Ho, S.C. Wu, S.K. Hsu, Y.C. Li, and H.C. Hsu, Effects of molybdenum content on the structure and mechanical properties of as-cast Ti-10Zr-based alloys for biomedical applications, Mater. Sci. Eng. C, 32(2012), No. 3, p. 517.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计