留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 26 Issue 11
Nov.  2019
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  665
  • HTML全文浏览量:  111
  • PDF下载量:  11
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(11): 1405-1414
Jin-yang Zhu, Li-ning Xu, Min-xu Lu,  and Wei Chang, Cathodic reaction mechanisms in CO2 corrosion of low-Cr steels, Int. J. Miner. Metall. Mater., 26(2019), No. 11, pp. 1405-1414. https://doi.org/10.1007/s12613-019-1861-2
Cite this article as:
Jin-yang Zhu, Li-ning Xu, Min-xu Lu,  and Wei Chang, Cathodic reaction mechanisms in CO2 corrosion of low-Cr steels, Int. J. Miner. Metall. Mater., 26(2019), No. 11, pp. 1405-1414. https://doi.org/10.1007/s12613-019-1861-2
shu
引用本文 PDF XML SpringerLink
研究论文

Cathodic reaction mechanisms in CO2 corrosion of low-Cr steels

  • National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China

  • Corrosion and Protection Center, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

  • CNOOC Research Institute, Beijing 100027, China

  • 通讯作者:

    Jin-yang Zhu    E-mail: zhujinyang@ustb.edu.cn

  • The cathodic reaction mechanisms in CO2 corrosion of low-Cr steels were investigated by potentiodynamic polarization and galvanostatic measurements. Distinct but different dominant cathodic reactions were observed at different pH levels. At the higher pH level (pH >~5), H2CO3 reduction was the dominant cathodic reaction. The reaction was under activation control. At the lower pH level (pH <~3.5), H+ reduction became the dominant one and the reaction was under diffusion control. In the intermediate area, there was a transition region leading from one cathodic reaction to another. The measured electrochemical impedance spectrum corresponded to the proposed cathodic reaction mechanisms.
    • Research Article

    Cathodic reaction mechanisms in CO2 corrosion of low-Cr steels

    + Author Affiliations
      Abstract
    • The cathodic reaction mechanisms in CO2 corrosion of low-Cr steels were investigated by potentiodynamic polarization and galvanostatic measurements. Distinct but different dominant cathodic reactions were observed at different pH levels. At the higher pH level (pH >~5), H2CO3 reduction was the dominant cathodic reaction. The reaction was under activation control. At the lower pH level (pH <~3.5), H+ reduction became the dominant one and the reaction was under diffusion control. In the intermediate area, there was a transition region leading from one cathodic reaction to another. The measured electrochemical impedance spectrum corresponded to the proposed cathodic reaction mechanisms.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(25)
    • [1]
      X. Jiang, Y.G. Zheng, D.R. Qu, and W. Ke, Effect of calcium ions on pitting corrosion and inhibition performance in CO2 corrosion of N80 steel, Corros. Sci., 48(2006), No. 10, p. 3091.
      [2]
      G. Schmitt, Advances in CO2 corrosion,[in] NACE Corrosion, Houston, 1984, art. No. 84001.
      [3]
      A. Ikeda, M. Ueda, and S. Mukai, CO2 behavior of carbon and Cr steels,[in] NACE Corrosion, Houston, 1984, art. No. 84039.
      [4]
      C. de Waard and D.E. Milliams, Carbonic acid corrosion of steel, Corrosion, 31(1975), No. 5, p. 177.
      [5]
      G. Schmitt and M. Horstemeier, Fundamental aspects of CO2 metal loss corrosion-Part II:Influence of different parameters on CO2 corrosion mechanism,[in] NACE Corrosion, Houston, 2006, art. No. 06112.
      [6]
      G.I. Ogundele and W.E. White, Some observation on corrosion of carbon steel in aqueous environments containing carbon dioxide, Corrosion, 42(1986), No. 2, p. 71.
      [7]
      S. Nesic, J. Postlethwaite, and S. Olsen, An electrochemical model for prediction of corrosion of mild steel in aqueous carbon dioxide solutions, Corrosion, 52(1996), No. 4, p. 280.
      [8]
      X.Y. Zhang, G. Yu, F.P. Wang, and Y.L. Du, Influence of Cl- on corrosion behavior of API P105 steel in the CO2 saturated solution, Chem. Res. Chin. Univ., 20(1999), No. 7, p. 1115.
      [9]
      B.R. Linter and G.T. Burstein, Reaction of pipeline steels in carbon dioxide solutions, Corros. Sci., 41(1999), No. 1, p. 117.
      [10]
      C.F. Chen, M.X. Lu, G.X. Zhao, Z.Q. Bai, M.L. Yan, and Y.Q. Yang, The EIS analysis of cathodic reactions during CO2 corrosion of N80 steel, Acta Metall. Sin., 39(2003), No. 1, p. 94.
      [11]
      J.Y. Zhu, L.N. Xu, M.X. Lu, L. Zhang, W. Chang, and L.H. Hu, Essential criterion for evaluating the corrosion resistance of 3Cr steel in CO2 environments:Prepassivation, Corros. Sci., 93(2015), p. 336.
      [12]
      B.W. Luo, J. Zhou, P.P. Bai, S.Q. Zheng, T. An, and X.L. Wen, Comparative study on the corrosion behavior of X52, 3Cr, and 13Cr steel in an O2-H2O-CO2 system:products, reaction kinetics, and pitting sensitivity, Int. J. Miner. Metall. Mater., 24(2017), No. 6, p. 646.
      [13]
      A. Pfennig and A. Kranzmann, Effect of CO2 and pressure on the stability of steels with different amounts of chromium in saline water, Corros. Sci., 65(2012), p. 441.
      [14]
      H.B. Wu, T. Wu, G. Niu, T. Li, R.Y. Sun, and Y. Gu, Effect of the frequency of high-angle grain boundaries on the corrosion performance of 5wt%Cr steel in a CO2 aqueous environment, Int. J. Miner. Metall. Mater., 25(2018), No. 3, p. 315.
      [15]
      Q.L. Wu, Z.H. Zhang, X.M. Dong, and J.Q. Yang, Corrosion behavior of low-alloy steel containing 1% chromium in CO2 environments, Corros. Sci., 75(2013), p. 400.
      [16]
      M. Ko, B. Ingham, N. Laycock, and D.E. Williams, In situ synchrotron X-ray diffraction study of the effect of chromium additions to the steel and solution on CO2 corrosion of pipeline steels, Corros. Sci., 80(2014), p. 237.
      [17]
      S.Q. Guo, L.N. Xu, L. Zhang, W. Chang, and M.X. Lu, Characterization of corrosion scale formed on 3Cr steel in CO2-saturated formation water, Corros. Sci., 110(2016), p. 123.
      [18]
      C.N. Cao and J.Q. Zhang, An Introduction to Electrochemical Impedance Spectroscopy, Science Press, Beijing, 2002.
      [19]
      Q.X. Zha, Kinetics of Electrode Process, Science Press, Beijing, 2002.
      [20]
      J.Y. Zhu, L.N. Xu, M.X. Lu, L. Zhang, W. Chang, and L.H. Hu, Cathodic reaction mechanism of 3Cr low alloy steel corroded in CO2-saturated high salinity solutions, Int. J. Electrochem. Soc., 10(2015), p. 1434.
      [21]
      C. de Waard, U. Lotz, and D.E. Milliams, Predictive model for CO2 corrosion engineering in wet natural gas pipelines, Corrosion, 47(1991), No.12, p. 976.
      [22]
      K. Videm, A. Dugstad, and L. Lunde, Parametric study of CO2 corrosion of carbon steel, Corrosion, 94(1994), p. 14.
      [23]
      Z.H. Duan and D.D. Li, Coupled phase and aqueous species equilibrium of the H2O-CO2-NaCl-CaCO3 system from 0 to 250℃, 1 to 1000 bar with NaCl concentrations up to saturation of halite, Geochim. Cosmochim. Acta, 72(2008), No. 20, p. 5128.
      [24]
      R.C. Weast, M.J. Astle, and W.H. Beyer, Handbook of Chemistry and Physics, CRC Press, Florida, 2001.
      [25]
      S.Q. Guo, L.N. Xu, L. Zhang, W. Chang, and M.X. Lu, Corrosion of alloy steels containing 2% chromium in CO2 environments, Corros. Sci., 63(2012), p. 246.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计