doi:10.1007/s12613-020-2011-6

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文章导航 > 矿物冶金与材料学报（英文） > 2020 > 27(7): 987-995

Jashandeep Singh and Ashok Kumar, Investigation of structural, morphological and electrochemical properties of mesoporous La₂CuCoO₆ rods fabricated by facile hydrothermal route, Int. J. Miner. Metall. Mater., 27(2020), No. 7, pp. 987-995. https://doi.org/10.1007/s12613-020-2011-6

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Jashandeep Singh and Ashok Kumar, Investigation of structural, morphological and electrochemical properties of mesoporous La2CuCoO6 rods fabricated by facile hydrothermal route, Int. J. Miner. Metall. Mater., 27(2020), No. 7, pp. 987-995. https://doi.org/10.1007/s12613-020-2011-6

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Research Article

Investigation of structural, morphological and electrochemical properties of mesoporous La₂CuCoO₆ rods fabricated by facile hydrothermal route

Jashandeep Singh¹ and
Ashok Kumar^1,2,

+ Author Affiliations

Abstract

Abstract

This work introduces the facile hydrothermal synthesis of double perovskite La₂CuCoO₆. X-ray diffraction pattern confirmed the formation of a monoclinic phase with P12₁/c1 symmetry. Transmission electron microscopy results revealed that the self-assembled porous rods were composed of nanocrystallite aggregates. The estimated specific surface area of these mesoporous rods with an average pore diameter of 6 nm was ~41 m²·g^–1. The presence of ions with oxidation states of La³⁺, Cu²⁺, and Co²⁺/Co³⁺ on the surface of the mesoporous La₂CuCoO₆ rods was confirmed by X-ray photoelectron spectroscopic analysis. Via cyclicvoltammetry and chronopotentiometry, the electrode fabricated from the mesoporous La₂CuCoO₆ rods were found to exhibit pseudocapacitive behavior with a specific capacitance of 259.4 F·g^–1 at a current density of 0.5 A·g^–1. An ~89% retention in specific capacitance was achieved after 1000 charge/discharge cycles at a constant current density of 4 A·g^–1.
- rare earth;
- double perovskites;
- oxide materials;
- hydrothermal;
- electrochemical

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Investigation of structural, morphological and electrochemical properties of mesoporous La₂CuCoO₆ rods fabricated by facile hydrothermal route

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