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Santi Phumying, Thongsuk Sichumsaeng, Pinit Kidkhunthod, Narong Chanlek, Jessada Khajonrit, Somchai Sonsupap, and Santi Maensiri, Influence of polymer solution on the morphology and local structure of NH4ZnPO4 powders synthesized by a simple precipitation method at room temperature, Int. J. Miner. Metall. Mater., 29(2022), No. 2, pp. 298-304. https://doi.org/10.1007/s12613-020-2208-8
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Santi Maensiri E-mail: santimaensiri@g.sut.ac.th
我们采用一种简易的沉淀法在室温下合成了NH4ZnPO4粉体。我们研究了聚乙烯吡咯烷酮(PVP)、聚乙烯醇(PVA)、葡萄糖和十六烷基三甲基溴化铵(CTAB)溶液对制备的样品形貌和结构的影响，然后利用X射线衍射和扫描电镜分别对制备的样品进行了物相组成和形貌表征。研究发现在不同的聚合物下，加入CTAB后，由水的非表面活性剂制备的六方结构完全转变为单斜结构。我们采用X射线吸收近边结构(XANES)和X射线光电子能谱(XPS)对制备的样品进行的局部结构和表面电子结构研究确定了P离子和Zn离子的氧化态分别为5+和2+。在电感耦合等离子体原子发射光谱(ICP-OES)分析结果的基础上，NH4ZnPO4粉末可以归类为在24小时内只有不到15%的离子被释放出的缓释肥料。研究结果表明这种简易的使用水,PVP, PVA,蔗糖和CTAB作为溶液模板的沉淀方法可以用来合成NH4ZnPO4粉末；该方法还可推广应用于其它氧化物材料的制备。
NH4ZnPO4 powders were synthesized using a simple precipitation method at room temperature. The effects of polyvinyl pyrrolidone (PVP), polyvinyl alcohol (PVA), glucose, and hexadecyltrimethylammonium bromide (CTAB) solutions on the morphology and structure of the prepared samples were investigated. The phase composition and morphology of the prepared samples were characterized using X-ray diffraction and scanning electron microscopy, respectively. Depending on the polymer sources, the hexagonal structure prepared using non-surfactant of water completely changed to monoclinic structure when CTAB was added. X-ray absorption near-edge structure (XANES) and X-ray photoelectron spectroscopy (XPS) were performed to study the local structure and surface electronic structure of the prepared samples, confirming that the oxidation states of P and Zn ions are 5+ and 2+, respectively. On the basis of the results of inductively coupled plasma atomic emission spectroscopy (ICP-OES), the NH4ZnPO4 powders can be classified as a slow-release fertilizer where less than 15% of the ions were released in 24 h. A simple precipitation method using water, PVP, PVA, sucrose, and CTAB as a template can be used to synthesize NH4ZnPO4 powders. In addition, this method may be extended for the preparation of other oxide materials.
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