镁掺杂氧化锰电极材料用于高性能水系镁离子二次电池

赵越; 王贝; 施敏杰; 安世博; 赵丽萍; 晏超

doi:10.1007/s12613-021-2346-7

Volume 29 Issue 11

Nov. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(11): 1954-1962

Yue Zhao, Bei Wang, Minjie Shi, Shibo An, Liping Zhao, and Chao Yan, Mg-intercalation engineering of MnO₂ electrode for high-performance aqueous magnesium-ion batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp. 1954-1962. https://doi.org/10.1007/s12613-021-2346-7

Cite this article as:

Yue Zhao, Bei Wang, Minjie Shi, Shibo An, Liping Zhao, and Chao Yan, Mg-intercalation engineering of MnO2 electrode for high-performance aqueous magnesium-ion batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp. 1954-1962. https://doi.org/10.1007/s12613-021-2346-7

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研究论文

镁掺杂氧化锰电极材料用于高性能水系镁离子二次电池

1)
江苏科技大学材料科学与工程学院，镇江 212003，中国
2)
上海交通大学材料科学与工程学院金属基复合材料国家重点实验室，上海 200240，中国

通讯作者:
施敏杰 E-mail: shiminjie@just.edu.cn

晏超 E-mail: chaoyan@just.edu.cn

文章亮点

(1) 提出了一种新颖的氧化锰电极材料的镁掺杂工程技术。

(2) 理论计算与原位拉曼证实了镁掺杂对于氧化锰的重要作用。

(3) 镁掺杂氧化锰作为电极材料展现出高比容量和循环稳定性。

(4) 实现了软包装型水系镁离子二次电池的高比能与长续航特性。

中文摘要

水系镁离子二次电池在低成本与高安全性储能设备中应用前景广阔。虽然氧化锰被认为是水系镁离子电池中一种有潜力的电极材料，但其电子导电性低和循环性能差的问题极大地阻碍了氧化锰电极材料实际应用。本文提出了一种新颖的氧化锰电极材料的镁掺杂工程技术，同时对构建的镁掺杂氧化锰电极材料的电子结构和电化学性能进行了深入研究。DFT理论计算证明了镁掺杂对调节氧化锰电子结构的重要作用，并且原位拉曼结果也证实了镁掺杂氧化锰在充放电过程中可逆的相变过程。因此，该电极材料展现出高比容量（419.8 mAh·g⁻¹），以及优越的循环性能（1000次循环后容量几乎没有衰减）。基于这种镁掺杂氧化锰电极材料，我们成功组装了一种软包装型水系镁离子二次电池，该储能器件具有优越的电化学储能性能，实现了水系镁离子二次电池的高比能与长续航特性，揭示了其在高性能能源技术领域中的巨大应用潜能。

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Research Article

Mg-intercalation engineering of MnO₂ electrode for high-performance aqueous magnesium-ion batteries

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Abstract

Abstract

Rechargeable aqueous magnesium-ion batteries (MIBs) show great promise for low-cost, high-safety, and high-performance energy storage applications. Although manganese dioxide (MnO₂) is considered as a potential electrode material for aqueous MIBs, the low electrical conductivity and unsatisfactory cycling performance greatly hinder the practical application of MnO₂ electrode. To overcome these problems, herein, a novel Mg-intercalation engineering approach for MnO₂ electrode to be used in aqueous MIBs is presented, wherein the structural regulation and electrochemical performance of the Mg-intercalation MnO₂ (denoted as MMO) electrode were thoroughly investigated by density functional theory (DFT) calculations and in-situ Raman investigation. The results demonstrate that the Mg intercalation is essential to adjusting the charge/ion state and electronic band gap of MMO electrode, as well as the highly reversible phase transition of the MMO electrode during the charging–discharging process. Because of these remarkable characteristics, the MMO electrode can be capable of delivering a significant specific capacity of ~419.8 mAh·g⁻¹, while exhibiting a good cycling capability over 1000 cycles in 1 M aqueous MgCl₂ electrolyte. On the basis of such MMO electrode, we have successfully developed a soft-packaging aqueous MIB with excellent electrochemical properties, revealing its huge application potential as the efficient energy storage devices.
- manganese oxide;
- aqueous batteries;
- intercalation engineering;
- density functional theory calculations;
- in-situ Raman

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