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Volume 29 Issue 6
Jun.  2022

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Fangyi Zhao, Zhen Song, and Quanlin Liu, Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation, Int. J. Miner. Metall. Mater., 29(2022), No. 6, pp. 1286-1294. https://doi.org/10.1007/s12613-021-2363-6
Cite this article as:
Fangyi Zhao, Zhen Song, and Quanlin Liu, Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation, Int. J. Miner. Metall. Mater., 29(2022), No. 6, pp. 1286-1294. https://doi.org/10.1007/s12613-021-2363-6
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研究论文

新型Cr3+激活的远红光荧光粉

  • 通讯作者:

    宋振    E-mail: zsong@ustb.edu.cn

    刘泉林    E-mail: qlliu@ustb.edu.cn

文章亮点

  • (1) 报道了一系列Cr3+激活的β-Ca3(PO4)2结构的远红光-近红外发光材料Ca9Ga(PO4)7:Cr3+ (M = Al, Ga, Sc, In, Lu, Y)。
  • (2)Ca9Ga(PO4)7:Cr3+远红光荧光粉具有高的内量子效率值以及优异的热稳定性。
  • (3) Ca9Ga(PO4)7:Cr3+远红光荧光粉有望用于室内植物种植领域。
  • 远红光和近红外光谱在食品分析、植物生长、夜视、生物成像、安全监控、虹膜识别等领域具有广泛的应用价值,近年来对远红光和近红外荧光粉的研究获得了越来越多的关注。本文采用高温固相法合成了一系列Cr3+激活的β-Ca3(PO4)2结构的远红光-近红外发光材料Ca9M(PO4)7:Cr3+ (M = Al, Ga, Sc, In, Lu, Y),并对这一系列样品进行了XRD、光谱、紫外漫反射及扫描电镜测试。随着M3+离子类型由半径较小的Al3+变为半径较大的Y3+,发射光谱由694 nm红移至795 nm;由于M3+离子半径的增加为Cr3+离子提供了更为宽松的八面体环境,晶体场强度降低,从而引起发射光谱的红移。其中,当M3+离子为Ga3+时发射光谱强度最大,在440 nm蓝光激发下,该荧光粉可呈现出峰位在735 nm的宽带远红光发射,发射范围从650 nm到850 nm,并在690 nm和698 nm处呈现出两个尖锐的R线发射。Ca9Ga0.97 (PO4)7:0.03Cr3+荧光粉的内量子效率达到55.7%;且该样品具有优异的发光热稳定性能,在423 K时发射光谱的强度仍可保持室温的68.5%。由于Ca9Ga(PO4)7:Cr3+荧光粉的发射光谱与植物远红光光敏色素PFR的吸收光谱存在很大的光谱重叠,通过搭配450 nm蓝光芯片进行封装所得到的LED器件有望用于室内植物种植领域,从而促进植物生长。
  • Research Article

    Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation

    + Author Affiliations
    • Cr3+-activated far-red and near-infrared phosphors have drawn considerable attention owing to their adjustable emission wavelengths and wide applications. Herein, we reported a series of Cr3+-doped phosphors with β-Ca3(PO4)2-type structure, of which Ca9Ga(PO4)7:Cr3+ possessed the highest far-red emission intensity. At an excitation of 440 nm, the Ca9Ga(PO4)7:Cr3+ phosphors exhibited a broad emission band ranging from 650 to 850 nm and peaking at 735 nm, and the broadband superimposed two sharp lines centering at 690 and 698 nm. The optimal sample Ca9Ga0.97(PO4)7:0.03Cr3+ had an internal quantum efficiency of 55.7%. The luminescence intensity of the Ca9Ga0.97(PO4)7:0.03Cr3+ phosphor obtained at 423 K could maintain 68.5% of that at room temperature, demonstrating its outstanding luminescence thermal stability. A phosphor-conversion light-emitting diode was fabricated, indicating that the Ca9Ga(PO4)7:Cr3+ phosphor has potential applications in indoor plant cultivation.
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