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Volume 30 Issue 1
Jan.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(1): 131-143
Hui Liu, Yanhui Zhao, Chuanshi Sui, Yi Li, Muhammad Ali Siddiqui, Susu Li, Tong Li, Shuyuan Zhang, Hai Wang, Tao Jin, Ling Ren, Ke Yang,  and Ning Zhang, Effect of N2 partial pressure on comprehensive properties of antibacterial TiN/Cu nanocomposite coating, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 131-143. https://doi.org/10.1007/s12613-021-2387-y
Cite this article as:
Hui Liu, Yanhui Zhao, Chuanshi Sui, Yi Li, Muhammad Ali Siddiqui, Susu Li, Tong Li, Shuyuan Zhang, Hai Wang, Tao Jin, Ling Ren, Ke Yang,  and Ning Zhang, Effect of N2 partial pressure on comprehensive properties of antibacterial TiN/Cu nanocomposite coating, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 131-143. https://doi.org/10.1007/s12613-021-2387-y
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研究论文

N2分压对抗菌TiN/Cu纳米复合涂层的综合性能影响

  • 1)

    中国科学技术大学材料科学与工程学院，合肥 230026，中国

  • 2)

    中国科学院金属研究所师昌绪先进材料创新中心，沈阳 110016，中国

  • 3)

    沈阳化工研究院有限公司，沈阳 110000，中国

  • 4)

    Department of Metallurgical Engineering, NED University of Engineering and Technology, Karachi 75270, Pakistan

  • 5)

    沈阳市胸科医院肾内科，沈阳 110002，中国

  • 6)

    中国医科大学附属口腔医院，沈阳 110002，中国

    • * 共同第一作者
  • 通讯作者:

    张宁    E-mail: Zhangning_513@sohu.com

文章亮点

  • (1) 系统地研究了N2分压对TiN/Cu纳米复合涂层的围观组织的影响。
  • (2) 开发了耐磨性、耐蚀性、抗菌性、生物相容性能优异的TiN/Cu-1.5涂层。
  • (3) 总结并阐明了N2分压对TiN/Cu涂层的综合性能影响机制。
  • 人体组织对植入物磨损碎片和腐蚀产物产生的异物反应以及细菌感染是导致植入物失败的主要因素。为了解决这些问题，本文采用电弧离子镀系统通过不同N2分压的工艺参数设置，在304不锈钢上制备获得一系列抗菌TiN/Cu纳米复合涂层沉积，分别命名为TiN/Cu-x（x = 0.5，1.0，1.5 Pa）。X射线衍射分析、能量色散X射线光谱和扫描电镜分析结果表明，N2分压决定了TiN/Cu纳米复合涂层的Cu含量、表面缺陷和微晶尺寸，进一步影响了其综合能力。TiN/Cu涂层的硬度和耐磨性随着微晶尺寸的增加而增强。在表面缺陷、微晶尺寸和铜含量的协同作用下，TiN/Cu-1.0和TiN/Cu-1.5涂层具有优异的耐腐蚀性。此外，生物试验证明，所有TiN/Cu涂层均无细胞毒性，抗菌能力强。其中，TiN/Cu-1.5涂层显著促进了细胞增殖，有望成为一种新型抗菌、耐腐蚀、耐磨的医疗植入物表面涂层。
    • Research Article

    Effect of N2 partial pressure on comprehensive properties of antibacterial TiN/Cu nanocomposite coating

    + Author Affiliations
      Abstract
    • Foreign body reactions to the wear debris and corrosion products from the implants, and bacterial infections are the main factors leading to the implant failures. In order to resolve these problems, the antibacterial TiN/Cu nanocomposite coatings with various N2 partial pressures were deposited on 304 stainless steels (SS) using an arc ion plating (AIP) system, named TiN/Cu-x (x = 0.5, 1.0, 1.5 Pa). The results of X-ray diffraction analysis, energy-dispersive X-ray spectroscopy, and scanning electron microscopy showed that the N2 partial pressures determined the Cu contents, surface defects, and crystallite sizes of TiN/Cu nanocomposite coatings, which further influenced the comprehensive abilities. And the hardness and wear resistances of TiN/Cu coatings were enhanced with increase of the crystallite sizes. Under the co-actions of surface defects, crystallite sizes, and Cu content, TiN/Cu-1.0 and TiN/Cu-1.5 coatings possessed excellent corrosion resistance. Besides, the biological tests proved that all the TiN/Cu coatings showed no cytotoxicity with strong antibacterial ability. Among them, TiN/Cu-1.5 coating significantly promoted the cell proliferation, which is expected to be a novel antibacterial, corrosion-resistant, and wear-resistant coating on the surfaces of medical implants.
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