用于稳定的高容量铝–碲电池的改性铝负极

张雪峰; 焦树强

doi:10.1007/s12613-022-2410-y

Volume 29 Issue 4

Apr. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(4): 896-904

Xuefeng Zhang and Shuqiang Jiao, Modified Al negative electrode for stable high-capacity Al–Te batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 896-904. https://doi.org/10.1007/s12613-022-2410-y

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Xuefeng Zhang and Shuqiang Jiao, Modified Al negative electrode for stable high-capacity Al–Te batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 896-904. https://doi.org/10.1007/s12613-022-2410-y

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研究论文

用于稳定的高容量铝–碲电池的改性铝负极

北京科技大学钢铁冶金新技术国家重点实验室, 北京100083, 中国

通讯作者:
焦树强 E-mail: sjiao@ustb.edu.cn

中文摘要

金属铝电池（MABs）具有高能量密度、资源丰富、成本低、安全和环境友好等特点，被认为是极具潜力的大规模储能设备，而Te被认为是MABs的潜在正极材料。然而，由于碲的化学和电化学溶解以及其溶解产物在铝负极上的化学沉淀所引起的关键问题，导致了Al–Te电池循环稳定性差和放电容量低。本文提出了一种高效的基于TiB₂的改性层（Al/TB）来解决金属铝电极的关键问题,从而实现了Al/TB负极的低电压迟滞和长循环寿命。基于Al/TB负极的Al–Te电池的电化学性能得到了极大的改善。此外，还引入了改性的隔膜技术以与设计中的Al/TB负极相匹配。因此，Al–Te电池达到了创纪录的长达500个循环的长期循环稳定性。这一简单的策略也为其他高能量密度的电池系统，如Al–S和Al–Se电池，开辟了一条潜在的路线。

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Research Article

Modified Al negative electrode for stable high-capacity Al–Te batteries

Xuefeng Zhang and
Shuqiang Jiao

+ Author Affiliations

Abstract

Abstract

Metal aluminum batteries (MABs) are considered potential large-scale energy storage devices because of their high energy density, resource abundance, low cost, safety, and environmental friendliness. Given their high electrical conductivity, high theoretical specific capacity, and high discharge potential, Te is considered a potential positive electrode material for MABs. Nonetheless, the critical issues induced by the chemical and electrochemical dissolution of tellurium and subsequent chemical precipitation on bare Al negative electrodes result in poor cycle stability and low discharge capacity of Al–Te batteries. Here an efficient TiB₂-based modified layer has been proposed to address bare Al electrodes (Al/TB). Consequently, the low-voltage hysteresis and long cycle life of the Al/TB negative electrode have been achieved. In addition, the electrochemical performance of the Al–Te battery based on the Al/TB negative electrode is dramatically improved. Furthermore, the modified separator technology is introduced to match with the as-designed Al/TB negative electrode. Therefore, the record-setting long-term cycle stability of up to 500 cycles has been achieved in the Al–Te battery. The facile strategy also opens a potential route for other high-energy density battery systems, such as Al–S and Al–Se batteries.
- metal aluminum battery;
- negative electrode;
- electrochemically inert TiB₂;
- tellurium

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