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Fe-based amorphous coating prepared using high-velocity oxygen fuel and its corrosion behavior in static lead–bismuth eutectic alloy

Xiangyang Peng, Yuhai Tang, Xiangbin Ding, Zhichao Lu, Shuo Hou, Jianming Zhou, Shuyin Han, Zhaoping Lü, Guangyao Lu, Yuan Wu

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Xiangyang Peng, Yuhai Tang, Xiangbin Ding, Zhichao Lu, Shuo Hou, Jianming Zhou, Shuyin Han, Zhaoping Lü, Guangyao Lu, and Yuan Wu, Fe-based amorphous coating prepared using high-velocity oxygen fuel and its corrosion behavior in static lead–bismuth eutectic alloy, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp.2032-2040. https://dx.doi.org/10.1007/s12613-022-2420-9
Xiangyang Peng, Yuhai Tang, Xiangbin Ding, Zhichao Lu, Shuo Hou, Jianming Zhou, Shuyin Han, Zhaoping Lü, Guangyao Lu, and Yuan Wu, Fe-based amorphous coating prepared using high-velocity oxygen fuel and its corrosion behavior in static lead–bismuth eutectic alloy, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp.2032-2040. https://dx.doi.org/10.1007/s12613-022-2420-9
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研究论文

铁基非晶涂层的制备及静态铅铋腐蚀行为研究

文章亮点

(1)采用超音速火焰喷涂技术在T91基体表面制备了性能良好的Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2.4铁基非晶涂层。 (2)对比了铁基非晶涂层和T91钢静态铅铋腐蚀行为的差异。 (3)提出了非晶涂层在静态铅铋环境中的腐蚀机制模型。
铅铋共晶合金(LBE)由于具有低熔点、高沸点、热导率高、化学惰性好和中子辐照损伤小等一系列的优异性能,被选为ADS系统散裂靶兼冷却剂的重点材料。然而传统结构材料在高温液态LBE环境中存在严重的腐蚀问题,提升结构材料与LBE的相容性,降低结构材料的腐蚀速率仍然是核工程应用过程中亟需解决的问题。在本研究中,我们采用超音速火焰喷涂技术(HOVF)在T91钢基体表面制备了Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2非晶涂层,对比研究了T91钢及非晶涂层在400℃、饱和氧条件下的静态铅铋腐蚀行为。结果表明,在经过500 h的铅铋腐蚀后,T91基板腐蚀严重,与LBE接触的界面上生成了6–10 μm厚均匀分布的双氧化层,其中内层主要成分是(Fe,Cr)3O4,外层成分是Fe3O4。相同条件下,非晶涂层展现出良好的热稳定性和耐铅铋腐蚀性能。涂层在铅铋腐蚀后,虽然表面有少量Fe3O4、Cr2O3和PbO生成,但并未观察到明显的LBE渗透现象,涂层的非晶含量和与基体的结合特性也基本保持不变。本研究表明,非晶涂层在铅铋环境下具有优异的抗腐蚀性能,未来作为铅铋环境下结构材料的保护涂层具有良好应用前景。

 

Research Article

Fe-based amorphous coating prepared using high-velocity oxygen fuel and its corrosion behavior in static lead–bismuth eutectic alloy

Author Affilications

    *These authors contributed equally to this work.

    Corresponding author:

    Guangyao Lu      E-mail: Luguangyao@cgnpc.com.cn

    Yuan Wu      E-mail: wuyuan@ustb.edu.cn

  • Received: 27 September 2021; Revised: 26 December 2021; Accepted: 16 January 2022; Available online: 17 January 2022
The Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2 amorphous coating was deposited on T91 steel substrate by using the high-velocity oxygen fuel (HVOF) spray technique to enhance the corrosion resistance of T91 stainless steel in liquid lead–bismuth eutectic (LBE). The corrosion behavior of the T91 steel and coating exposed to oxygen-saturated LBE at 400°C for 500 h was investigated. Results showed that the T91 substrate was severely corroded and covered by a homogeneously distributed dual-layer oxide on the interface contacted to LBE, consisting of an outer magnetite layer and an inner Fe–Cr spinel layer. Meanwhile, the amorphous coating with a high glass transition temperature (Tg = 550°C) and crystallization temperature (Tx = 600°C) exhibited dramatically enhanced thermal stability and corrosion resistance. No visible LBE penetration was observed, although small amounts of Fe3O4, Cr2O3, and PbO were found on the coating surface. In addition, the amorphicity and interface bonding of the coating layer remained unchanged after the LBE corrosion. The Fe-based amorphous coating can act as a stable barrier layer in liquid LBE and have great application potential for long-term service in LBE-cooled fast reactors.

 

  • Lead–bismuth eutectic (LBE) is a promising candidate material for core coolants in accelerator-driven sub-critical systems because of its excellent thermal-physical properties and high neutron economy [1]. However, the application of LBE is limited by its compatibility with structural materials, especially at high temperatures [24]. During operation, structural materials suffer severe oxidation corrosion or elemental dissolution [5]. As a result, the surface morphology, microstructure, and structure of the materials are vulnerable to being changed, which consequently deteriorates the mechanical properties of structural materials and eventually causes material failure under working conditions [616].

    Several approaches have been proposed to form protective coatings on the surface of structural materials, such as T91 and 316L steels, to alleviate LBE corrosion. A typical method is to form protective nitride and carbide films on the steel surface by adding alloying elements, such as Zr or Ti, into the LBE liquids to form insoluble films of ZrN, TiN, or TiC and then enhance protection to a certain degree [1720]. Another means is to control the dissolved oxygen content in LBE to obtain stable oxide layers on the surface of structural materials [2124]. Although some favorable results have been achieved by using the above methods, protective films are difficult to control because they are affected by many factors, such as flow velocity, temperature, and oxygen concentration. Therefore, other effective protection methods that can directly modify the surface of structural materials are urgently required.

    Preparation of protective coatings on the surface of structural materials is an effective measure to alleviate LBE corrosion. Several coating materials, including refractory metal coatings (Mo, Nb, and W) [25], alloy coatings (FeCrAl, FeAlTi, and FeAl) [2628], ceramic coatings (TiN, CrN, Al2O3, SiC, and Ti3SiC2) [19,25,29], and composite coatings (SiC/SiC and sol–gel composites) [3031], have already been developed. Although these coatings exhibit good corrosion resistance, issues such as the easily formed grain defects promote the permeation of LBE along the grain boundary, causing material failure during long-term experiments. The complex preparation process also increases the cost of practical applications. Therefore, it remains challenging to develop coating materials that can endure aggressive corrosion and possess the potential for industrial applications in advanced nuclear reactors.

    Amorphous alloys have a long-range disordered atomic packing structure and contain no crystalline defects, such as grain boundaries, which are prone to corrosion as in crystalline materials. Therefore, they have a unique combination of favorable properties, such as high hardness, excellent wear, and good corrosion resistance [32]. In specific, Fe-based amorphous coatings (Fe-AC) are extremely practical candidates of surface protective barriers in LBE owing to their high crystallization temperature, predominant corrosion resistance, and relatively low fabrication cost [3335]. Among various fabrication techniques, HVOF (high-velocity oxygen fuel) is an economical and frequently used approach to develop surface coatings because of its high cooling rate (107–1010 K·s−1) and favorable properties, such as low porosity, high hardness, lower oxide content, and high adhesion strength [3639]. However, the corrosion behavior of Fe-AC in LBE liquids remains unclear.

    In this study, the Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2 amorphous coating was deposited on T91 steel substrate through HVOF, and the microstructure, glass-forming ability, and thermal stability of the coating were investigated. The corrosion behavior of the T91 substrate and Fe-AC in static oxygen-saturated LBE at 400°C was observed, which suggests that the current Fe-based amorphous coating exhibits excellent corrosion resistance in liquid LBE and has great potential to be utilized as a corrosion-resistant coating in accelerator-driven systems and advanced nuclear reactors.

    The Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 (at%) alloy ingot was prepared by the induction melting of Fe (99.9wt%), Cr (99.5wt%), Mn (99.9wt%), Mo (99.9wt%), W (99.9wt%), C (99.9wt%), and Fe–B (B 23wt%, Fe 74wt%, Si 2wt%) in an argon atmosphere. From the master alloy, ribbon samples were produced by a single-roller melt-spinning technique for calculating the amorphous content of the coatings. Amorphous powders with the same composition were prepared by high-pressure Ar gas atomization, and then as-atomized powders with sizes in the range of 30–50 μm were sieved following conventional sieve analysis. The T91 substrates were degreased by acetone, dried in air, grit-blasted with a mean surface roughness (Ra) of approximately 4 μm, and then preheated at 120°C before spraying. For the HVOF process, the ZB-2000 HVOF spraying system (Beijing Zhen Bang Aerospace Precision Machinery Co., Ltd., China) was adopted with the following parameters: kerosene flow of 30–32 L/min, oxygen flow of 52 L/min, powder-feed rate of 75 g/min, and barrel length of 380 mm.

    The microstructure of the powders and coatings was characterized using scanning electron microscopy (SEM; SUPRA55, Carl Zeiss Jena, Germany) equipped with energy dispersive spectroscopy (EDS). X-ray diffraction (XRD; X’pert APD, Philips, Holland) and transmission electron microscopy (TEM; JEM-2100, JEOL, Japan) were performed to analyze the structure of the substrate and the coating. Glass transition temperatures and crystallization enthalpy of the powder, coating, and ribbon were characterized using differential scanning calorimetry (DSC; STA499-C, NETZSCH Co., Germany) at a heating rate of 20°C/min under Ar atmosphere. The crystallized volume fraction of the as-atomized powders and Fe-AC was estimated by normalizing them with the crystallization enthalpy of the ribbons. In addition, the porosity of Fe-AC was calculated using Image-Pro in accordance with ASTM E2109–01, and ten images were selected to obtain accurate results. The bond strength between the coating and the substrate was measured using a universal testing machine (WDW-100E, Panasonic, Japan) with a tensile speed of 1 mm/min in accordance with GB/T 8642–2002. The final value was obtained after averaging at least two measurements.

    Vickers hardness (HV) of the substrate and amorphous coating before and after corrosion was measured at a load of 200 g and a loading time of 15 s by using a Vickers hardness testing system (Hmicro-Vickers indenter, Wolpert-401MVD, Buehler Ltd., American).

    In this study, static LBE corrosion tests were carried out in a tubular furnace under an oxygen-saturated atmosphere, which could simulate the serving environment in the nuclear industry. The temperature of the LBE liquid was set at 400°C, and the immersion period for the specimens (the coated T91 and the bare T91 for reference) was set for 500 h. After the LBE corrosion testing, the samples were rinsed in a solution containing hydrogen peroxide, acetic acid, and ethyl alcohol with a volume ratio of 1:1:1 to remove LBE stuck from the sample surface. Inevitably, adherent LBE liquid was left on a few parts of the sample surface. The cross-section and the surface of the coated T91 substrate were observed using SEM with EDS. The surface valence state of Fe-AC after LBE corrosion was characterized using X-ray photoelectron spectroscopy (XPS, AXIS-ULTRA-DLD, Kratos).

    The microstructure of the as-atomized powders is shown in Fig. 1(a). Most of the particles are spherical or near-spherical in shape despite some satellite-shaped powders. The majority of the powders exhibit smooth surfaces, indicating good fluidity during the spraying process. The particle size distribution of the atomized powders shown in Fig. 1(b) follows a typical Gaussian distribution, and the size of most particles is between 30 and 50 μm. XRD patterns of the atomized powders and Fe-AC are shown in Fig. 1(c). The single broad halo imposed with several small crystalline peaks hump reveals that the as-atomized powders have an amorphous structure with the co-existence of a few Fe23(C,B)6 particles. The crystallization peaks are pronounced in the as-sprayed coatings, which can be attributed to the crystallization during the HVOF process. The DSC traces of the amorphous powder, ribbon, and the as-spayed coating are shown in Fig.1(d). All the specimens show a similar crystallization process with three exothermic peaks. The glass transition temperature (Tg) and the onset crystallization temperature (Tx) of the coating are approximately 550 and 600°C, respectively, which are higher than the serving environment in the nuclear industry. The volume fraction (vol%) of the amorphous phase in the powders and coatings was estimated by comparing their heat of crystallization (ΔH) value with that of the ribbon reference sample. The amorphous contents of the powder and the coating are approximately 94% and 87%, respectively, which are consistent with the XRD results.

    Figure  1.  Powder morphology (a) and particle size distribution (b) of the as-atomized Fe-AC powders. (c) XRD patterns of the atomized powders and the as-sprayed coating. (d) DSC curves of the power, melt-spun ribbon, and as-sprayed coating.
    Volumefraction=ΔHPowder/coatingΔHRibbon (1)

    A cross-sectional examination of the coating was carried out using SEM (Fig. 2(a)). The amorphous coating formed a good bonding with the T91 steel substrate, and the coating itself showed a dense and uniform structure with a mean thickness of 340 μm and a porosity of 0.984%, as observed in Fig. 2(b). The average tensile bond strength between the Fe-AC powders and T91 substrate was measured to be 53 MPa. EDS line scanning diagram (Fig. 2(c)) and EDS maps (Fig. 2(d)) show that the elements in the coating are distributed uniformly, except for slight fluctuations in Fe and O, which may be caused by crystallization and oxidation during coating preparation. The coating surface is unevenly concave with a large number of particles staggered and stacked together (Fig. 3(a)), and some pores and micro-cracks still exist after polishing (Fig. 3(b)), which are typical for an HVOF-sprayed coating.

    Figure  2.  (a) Cross-sectional SEM images of the amorphous coating prepared by HVOF, (b) a close-up in the rectangular region in (a), (c) EDS line scan along the red line in (a), and (d) EDS mapping of the coating corresponding to (b).
    Figure  3.  Surface morphology of Fe-AC: (a) as-sprayed and (b) after polishing.

    TEM characterization was applied to acquire detailed structural information of the specimens. Good metallurgical bonding between the coating and the T91 substrate can be observed in Fig. 4. The inset diffused halo ring of the selected area diffraction (SAED) pattern (position #I) in the upper right corner shows that the matrix still retains its crystal structure, whereas the SAED pattern (position #II) on the left bottom verifies that the coating is mainly composed of the amorphous phase. Regarding the left side of position II, it is also the as-prepared coating, which is far from the substrate and the interface. As shown in the TEM image, the atoms in the left region pack in a disordered manner, indicating that the coating has a good amorphous structure.

    Figure  4.  Bright-field TEM image of the coated T91; SAED patterns of the T91 substrate (position #I) and the interface between the coating and substrate (position #II)

    The bare T91 steel substrate was also immersed in the same LBE corrosion conditions for comparison to elucidate the LBE corrosion resistance of the amorphous coating. As shown in Figs. 5 and 6, the surface of the T91 specimen after the experiment is covered by a homogeneously distributed oxide layer with a thickness ranging from 6 to 10 μm, indicating that severe oxidation corrosion occurred within the uncoated steel. The elemental distributions in the oxide films in Fig. 6(b) reveal that the Cr content in the inner oxide film is higher than that in the outer one, while the Fe element has an opposite trend. Therefore, the oxide layer consists of two zones with different Cr contents. Previous studies [4,40] showed that the inner oxide film with a compact structure is mainly composed of (Fe,Cr)3O4, whereas the porous outer oxide film is mainly composed of Fe3O4. The formation mechanism of the duplex oxide layer is not fully elucidated at present, and the diffusion coefficient difference in the alloy may contribute to the occurrence of this phenomenon. Experimental results [41] demonstrated that the diffusion coefficient of Fe is much higher than that of Cr in the Fe–Cr spinel oxide layer. The amount of Cr diffused to the steel surface is insufficient to form more spinel, and Fe3O4 emerges because of the high oxygen concentration within the LBE medium. The growth of the outer Fe3O4 is associated with the transfer of the Fe element outward, whereas the inner Fe–Cr spinel film develops with the movement of oxide through the oxide film [42]. The oxidation process is controlled by the outer layer growth, and the inner spinel film occupies the space caused by consuming the original steel constituents.

    Figure  5.  SEM cross-sectional image of T91 after exposure in static LBE at 400°C for 500 h.
    Figure  6.  (a) Cross-sectional SEM image of bare T91 after exposure to the LBE liquid at 400°C for 500 h. (b) EDS line scan and (c) EDS mapping of oxide layer along the red line in (a).

    Fig. 7(a) displays the cross-sectional image of the coated T91 after LBE corrosion. Clearly, the coating layer remained continuous and uniform, and neither obvious morphological changes nor thickness changes occurred. As shown in Fig. 7(b), the number of unmelted particles reduced, as compared with Fig. 3(a). The chemical composition of the protective layer after the corrosion tests was determined through EDS, as shown in Fig. 7(c). All elements were homogeneously distributed in the amorphous coating, and no significant chemical change was observed on the as-sprayed samples after corrosion. In addition, the oxide layer did not form on the surface appreciably, and no penetration of LBE liquid into the coating was detected. In Fig. 7(d), XRD spectra of the coating still shows a typical diffuse hump indicative of an amorphous structure. The low content of the crystalline phase remained low, and no precipitation of any other new crystalline phases was found inside the coating.

    Figure  7.  Cross-sectional SEM image of the as-prepared coating after exposure to the LBE liquid at 400°C for 500 h (a), surface morphology (b) and EDS mapping results (c) of the coating, and XRD patterns before and after corrosion (d)

    XPS tests were carried out on the surface of the samples after cleaning the residual LBE to determine the surface composition of the amorphous coating after static corrosion. In our test, the peak of C 1s from the experimental data was 284.7 eV. The high-resolution XPS spectra of the Fe-AC samples (Fe 2p, Cr 2p, Pb 4f, and O 1s) after corrosion are shown in Fig. 8. The XPS spectra of Fe 2p in Fig. 8(a) show that the Fe 2p3/2 spectrum could be fitted with two peaks, one at 710.7 eV corresponding to Fe2+ and another at 712.7 eV corresponding to Fe3+ [43]. The Cr 2p XPS spectrum in Fig. 8(b) displays double peaks at 576.9 and 586.8 eV, which are recognized as the peaks of Cr3+, indicating the formation of Cr2O3 [44]. The spectrum of Pb 4f proves the existence of the oxidation state of Pb, which has two peaks fitted at 138.0 and 142.9 eV, belonging to PbO [45]. In addition, analysis of the O 1s spectrum displayed two peaks situated at 530.3 and 531.6 eV, which correspond to Fe3O4 and PbO [4546]. The XPS analysis suggests that the oxide layer consisting of Fe3O4, Cr2O3, and PbO may form on the coating surface. The microscale oxide layer can improve the corrosion resistance of Fe-based amorphous coating [4748]. Therefore, no obvious LBE permeation and elemental dissolution were observed on the Fe-AC surface in Fig. 7(a).

    Figure  8.  XPS results about the surface of Fe-AC after exposure in static LBE: (a) Fe 2p analysis, (b) Cr 2p analysis, (c) Pb 4f analysis, and (d) O 1s analysis.

    Structural characterization of the amorphous coating and the interface between the coating and the substrate after the static LBE corrosion test was investigated by TEM (Fig. 9). Excellent metallurgical bonding still existed (position #III) between the T91 steel substrate and the amorphous coating after the LBE corrosion, and the coating still maintained a good amorphous structure, as indicated by the diffraction ring in Fig. 9(b). The SAED pattern (Fig. 9(c)) of the T91 matrix (position #II) still retained the crystal structure, although a small amount of amorphous structure appeared. This result can be ascribed to the selected area being close to the coating (not fully peeled off from the substrate). The results above prove that the amorphous coating can protect the matrix material for a long time in the LBE medium.

    Figure  9.  (a) Cross-sectional TEM images of the amorphous coating corroded at 400°C for 500 h, (b) diffraction pattern of coating (position #I), and (c) diffraction pattern of the T91 (position #II).

    The observed beneficial effects can be attributed to the specific composition and unique atomic structure of the amorphous coating. From the standpoint of structure, Fe-AC was prepared through the rapidly cooling method so that no grain boundaries, dislocations, or other physical imperfections existed in the amorphous phase, reducing the probability of alloy elements being dissolved or replaced at these crystalline defects and the chance of intergranular corrosion. Grain boundaries are a fast channel of oxidation corrosion. The long-range disordering structure of the amorphous coating can alleviate or even avoid oxidation corrosion, which contributes to the fact that no oxide layer formed appreciably on the coating surface. As mentioned earlier, slight corrosion occurred in the amorphous coating, which was mainly due to the damage in the continuity of the microstructure resulting from the existence of the crystalline phases. Therefore, enhancing the glass formation ability and surface quality of the amorphous coating may further improve the protection capability of the amorphous coating.

    The possible corrosion mechanism of Fe-AC in LBE at 400°C for 500 h is shown in Fig. 10. A very thin corrosion layer emerged because of the low diffusion rate of the elements in the coating (caused by the long-range disordering structure) and the short corrosion time. When Fe-AC was immersed in high-temperature LBE, O atoms in LBE diffused rapidly into the coating surface, and the Fe and Cr atoms in Fe-AC diffused outward. First, the O atoms reacted with Fe to generate an outer Fe3O4 because of the high diffusion rate of Fe atoms. As the oxygen atoms continued to diffuse, Cr2O3 nodules formed underneath the Fe3O4 oxide layer. Then, the Cr-rich nodules grew inward and gradually connected to generate a continuous Cr-rich layer, which restrained the diffusion of oxygen and metal elements.

    Figure  10.  Corrosion mechanism of Fe-AC in LBE at 400°C for 500 h.

    The hardness of the substrate and the coating was measured to investigate the evolution of mechanical behavior of Fe-AC. Vickers hardness images of the amorphous coating before and after corrosion in static LBE are shown in Fig. 11. The hardness of the amorphous coating (HV0.2 983 on average) was significantly higher than that of the bare T91 (HV0.2 170). This result can be ascribed to the effect of melted particles carried by argon on the T91 substrate with extremely high kinetic energy and heat, resulting in severe shape deformation of powder particles and the interface between the coating and the substrate, thereby increasing the hardness of the coating. After the LBE corrosion testing, the hardness of the coating (HV0.2 773 on average) decreased slightly, but it was still much higher than the hardness of the substrate, which also proved that no visible corrosion product was generated on the surface and further verified the good corrosion resistance of Fe-AC in the LBE medium.

    Figure  11.  Vickers hardness images of the amorphous coating: (a–c) as-sprayed and (d–f) after LBE corrosion test.

    In this work, the Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 amorphous coating as a barrier against LBE corrosion was successfully prepared using the HVOF method. The as-sprayed amorphous coating presents a dense and homogeneous structure with high hardness and good interface adhesion. Fe-AC exhibits good anti-LBE corrosion resistance with much lower consumption of the coating as compared with the bare T91 steel under the same corrosive conditions. The long-range disordered structure in Fe-AC may contribute to the high LBE corrosion resistance. The amorphicity and interface bonding remain unchanged after the static LBE corrosion, indicating that the amorphous coating has great potential for long-term service in LBE-cooled fast reactors.

    The work was financially supported by the National Natural Science Foundation of China (Nos. 52061135207, 51871016, 51921001, 5197011039, 5197011018, and U20b200318) and the China Nuclear Power Technology Research Institute Co., Ltd.

    The authors declare that they have no conflicts of interest in this work.

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