石墨烯量子点与锌插层氧化锰电极材料的协同耦合用于高性能水性锌离子二次电池

施敏杰; 朱航天; 陈聪; 蒋锦天; 赵丽萍; 晏超

doi:10.1007/s12613-022-2441-4

Volume 30 Issue 1

Jan. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(1): 25-32

Minjie Shi, Hangtian Zhu, Cong Chen, Jintian Jiang, Liping Zhao, and Chao Yan, Synergistically coupling of graphene quantum dots with Zn-intercalated MnO₂ cathode for high-performance aqueous Zn-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 25-32. https://doi.org/10.1007/s12613-022-2441-4

Cite this article as:

Minjie Shi, Hangtian Zhu, Cong Chen, Jintian Jiang, Liping Zhao, and Chao Yan, Synergistically coupling of graphene quantum dots with Zn-intercalated MnO2 cathode for high-performance aqueous Zn-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 25-32. https://doi.org/10.1007/s12613-022-2441-4

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研究论文

石墨烯量子点与锌插层氧化锰电极材料的协同耦合用于高性能水性锌离子二次电池

1)
江苏科技大学材料科学与工程学院，镇江 212003，中国
2)
上海交通大学材料科学与工程学院金属基复合材料国家重点实验室，上海 200240，中国
3)
浙江化工研究院有限公司，杭州 310012，中国

通讯作者:
施敏杰 E-mail: shiminjie@just.edu.cn

晏超 E-mail: chaoyan@just.edu.cn

文章亮点

(1) 提出了一种新颖的石墨烯量子点与锌插层氧化锰电极材料的耦合机制。

(2) 原位拉曼证实了石墨烯量子点与锌插层协同配合对于氧化锰的重要作用。

(3) 该复合电极材料展现出高比容量、优异电荷传输能力、以及高循环稳定性。

(4) 实现了水系锌离子二次电池的高能量/功率密度与长续航特性。

中文摘要

具有低成本、高安全性、以及高性能可充电水系电池近些年引起了越来越多的关注，其中水系锌离子电池在这方面显示出最有潜力的应用前景。作为水系锌离子电池的正极材料，二氧化锰被研究的最为广泛，但这种正极材料的缺点是电荷转移能力慢和循环性能差。本文提出了一种新颖的石墨烯量子点与锌插层氧化锰电极材料的耦合机制。实验结果表明：石墨烯量子点修饰与锌插层的协同配合提供了丰富的活性位点和导电介质以促进电解液离子扩散与电子电荷传输，确保了电极材料具有优异的电荷传输能力和高电化学可逆性。原位拉曼测试证实了复合电极材料在充放电过程中可逆的相变过程。因此，该电极材料展现出高比容量（403.6 mAh⋅g⁻¹），优异的电化学动力学和良好的结构稳定性。基于这种新型的复合电极材料，我们成功组装了一种高性能的水系锌离子二次电池，该储能器件具有高能量密度(226.8 Wh⋅kg⁻¹), 显著的功率密度(650 W⋅kg⁻¹)，以及长期循环性能，揭示了其在低成本、高安全性、高性能能源技术领域中的应用潜能。

关键词:

Research Article

Synergistically coupling of graphene quantum dots with Zn-intercalated MnO₂ cathode for high-performance aqueous Zn-ion batteries

+ Author Affiliations

Abstract

Abstract

Cost-effective, safe, and highly performing energy storage devices require rechargeable batteries, and among various options, aqueous zinc-ion batteries (ZIBs) have shown high promise in this regard. As a cathode material for the aqueous ZIBs, manganese dioxide (MnO₂) has been found to be promising, but certain drawbacks of this cathode material are slow charge-transfer capability and poor cycling performance. Herein, a novel design of graphene quantum dots (GQDs) integrated with Zn-intercalated MnO₂ nanosheets is put forward to construct a 3D nanoflower-like GQDs@Zn_xMnO₂ composite cathode for aqueous ZIBs. The synergistic coupling of GQDs modification with Zn intercalation provides abundant active sites and conductive medium to facilitate the ion/electron transmission, as well as ensure the GQDs@Zn_xMnO₂ composite cathode with enhanced charge-transfer capability and high electrochemical reversibility, which are elucidated by experiment results and in-situ Raman investigation. These impressive properties endow the GQDs@Zn_xMnO₂ composite cathode with superior aqueous Zn²⁺ storage capacity (~403.6 mAh·g⁻¹), excellent electrochemical kinetics, and good structural stability. For actual applications, the fabricated aqueous ZIBs can deliver a substantial energy density (226.8 W·h·kg⁻¹), a remarkable power density (650 W·kg⁻¹), and long-term cycle performance, further stimulating their potential application as efficient electrochemical storage devices for various energy-related fields.
- synergistically coupling;
- intercalation engineering;
- graphene quantum dots;
- manganese oxides;
- aqueous batteries

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石墨烯量子点与锌插层氧化锰电极材料的协同耦合用于高性能水性锌离子二次电池

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Synergistically coupling of graphene quantum dots with Zn-intercalated MnO₂ cathode for high-performance aqueous Zn-ion batteries

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