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Volume 29 Issue 4
Apr.  2022

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Jia Song, Yuvraj Y. Birdja, Deepak Pant, Zhiyuan Chen, and Jan Vaes, Recent progress in the structure optimization and development of proton-conducting electrolyte materials for low-temperature solid oxide cells, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 848-869. https://doi.org/10.1007/s12613-022-2447-y
Cite this article as:
Jia Song, Yuvraj Y. Birdja, Deepak Pant, Zhiyuan Chen, and Jan Vaes, Recent progress in the structure optimization and development of proton-conducting electrolyte materials for low-temperature solid oxide cells, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 848-869. https://doi.org/10.1007/s12613-022-2447-y
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特约综述

低温固体氧化物电池结构优化和质子导电电解质材料研究进展

  • 通讯作者:

    陈志远    E-mail: zhiyuan.chen@vito.be

    Jan Vaes    E-mail: jan.vaes@vito.be

文章亮点

  • (1) 总结了固体氧化物电池低温化发展的措施。
  • (2) 总结并展望纳米技术在优化低温固体氧化物电池结构方面的进展。
  • (3) 系统总结了以BaCeO3 和BaZrO3基材料为代表的质子导电电解质的研究进展。
  • 低温固体氧化物电池 (low-temperature solid oxide cells, LT-SOC) 的工作温度低于500°C,而这一温度到200°C区间在现有阶段是燃料电池和电解池的性能洼地。较低的工作温度可以提供比传统中高温电池更具成本效益的替代方案,并可以扩展SOC的应用场景。将SOC的工作温度降低到500°C以下有两个重要途径。第一条途径是通过电池结构优化提高电池性能。电池结构优化主要在于纳米技术的应用与优化,其中包括发展纳米镀层技术将电解质薄膜的厚度减薄到纳米级,以及探索可以有效降低极化电阻的纳米电极结构。本文总结了相关技术概况并展望了发展前景。另一条途径是开发新型质子传导电解质材料,这也是电池材料研究的前沿与热点技术。本文阐述了质子传导的基本原理和常用电解质材料的设计原理,总结了用于LT-SOC的最广泛研究的电解质材料,即钙钛矿型BaCeO3和BaZrO3基氧化物的研究概况,并讨论了氧化物掺杂对电解质材料物理化学性质的影响。
  • Invited Review

    Recent progress in the structure optimization and development of proton-conducting electrolyte materials for low-temperature solid oxide cells

    + Author Affiliations
    • This work reviews technologies that can be used to develop low-temperature solid oxide cells (LT-SOCs) and can be applied in fuel cells and electrolyzers operating at temperatures below 500°C, thus providing a more cost-effective alternative than conventional high-temperature SOCs. Two routes showing potential to reduce the operating temperature of SOCs to below 500°C are discussed. The first route is the principal way to enhance cell performance, namely, structure optimization. This technique includes the reduction of electrolyte thickness to the nanometer scale and the exploration of electrode structure with low polarization resistance. The other route is the development of novel proton-conducting electrolyte materials, which is in the frontier of SOCs study. The fundamentals of proton conduction and the design principles of commonly used electrolyte materials are briefly explained. The most widely studied electrolyte materials for LT-SOCs, namely, perovskite-type BaCeO3- and BaZrO3-based oxides, and the effect of doping on the physical–chemical properties of these oxide materials are summarized.
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