锂离子电容器用MOF衍生硒化钼修饰的Ti3C2Tx负极材料性能研究

钟健健; 秦禄; 李建玲; 杨哲; 杨凯; 张明杰

doi:10.1007/s12613-022-2469-5

Volume 29 Issue 5

Apr. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(5): 1061-1072

Jianjian Zhong, Lu Qin, Jianling Li, Zhe Yang, Kai Yang, and Mingjie Zhang, MOF-derived molybdenum selenide on Ti₃C₂T_x with superior capacitive performance for lithium-ion capacitors, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1061-1072. https://doi.org/10.1007/s12613-022-2469-5

Cite this article as:

Jianjian Zhong, Lu Qin, Jianling Li, Zhe Yang, Kai Yang, and Mingjie Zhang, MOF-derived molybdenum selenide on Ti3C2Tx with superior capacitive performance for lithium-ion capacitors, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1061-1072. https://doi.org/10.1007/s12613-022-2469-5

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研究论文

锂离子电容器用MOF衍生硒化钼修饰的Ti₃C₂T_x负极材料性能研究

1)
北京科技大学钢铁冶金新技术国家重点实验室, 北京 100083, 中国
2)
中国电力科学研究院有限公司新能源与储能运行控制国家重点实验室, 北京 100192, 中国

通讯作者:
李建玲 E-mail: lijianling@ustb.edu.cn

文章亮点

(1) 原位生长于Ti₃C₂T_x材料的MOF衍生MoSe₂颗粒起支柱作用并提供赝电容贡献。

(2) 快速锂离子扩散和优异导电性赋予材料卓越的电化学反应动力学和高容量性能。

(3) 快速的电极动力学促使材料在2.0 mV·s^–1大扫速下表现出86.0%的优异电容贡献率。

中文摘要

二维碳化钛Ti₃C₂T_x材料由于其独特的层状结构、优异的电子电导率和高比表面积，在锂离子电容器中表现出优异的倍率性能和循环性能。然而，作为类石墨烯材料，在电化学长循环过程中氢键作用和范德华力作用引起Ti₃C₂T_x材料的重堆叠效应，导致材料比表面积减小，增加了材料层间的电解质离子扩散距离，恶化了材料的电化学反应动力学。因此，本文采用溶剂热法成功将MOF结构衍生的过渡金属硒化物MoSe₂原位引入Ti₃C₂T_x材料结构中，以改善材料的电化学性能。MoSe₂材料具有特殊的三层原子层堆叠结构，其快速的锂离子扩散能力、在材料层间的支柱作用以及Ti₃C₂T_x材料自身的杰出导电性相互协同作用，赋予材料优异的电化学反应动力学特性和高容量。Ti₃C₂T_x@MoSe₂复合材料在150 mA·g^–1电流密度下比容量超过300 mAh·g^–1，并表现出优异的倍率特性，在1500 mA·g^–1电流密度下具有150 mAh·g^–1的比容量。同时，快速的电化学反应使Ti₃C₂T_x@MoSe₂复合材料在2.0 mV·s^–1扫速下表现出86.0%的优异电容贡献率。以复合材料作为负极构建的Ti₃C₂T_x@MoSe₂//AC锂离子电容器也表现出优异的循环稳定性。

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Research Article

MOF-derived molybdenum selenide on Ti₃C₂T_x with superior capacitive performance for lithium-ion capacitors

+ Author Affiliations

Abstract

Abstract

Two-dimensional Ti₃C₂T_x exhibits outstanding rate property and cycle performance in lithium-ion capacitors (LICs) due to its unique layered structure, excellent electronic conductivity, and high specific surface area. However, like graphene, Ti₃C₂T_x restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces, leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the material. Here, a transition metal selenide MoSe₂ with a special three-stacked atomic layered structure, derived from metal–organic framework (MOF), is introduced into the Ti₃C₂T_x structure through a solvothermal method. The synergic effects of rapid Li⁺ diffusion and pillaring effect from the MoSe₂ and excellent conductivity from the Ti₃C₂T_x sheets endow the material with excellent electrochemical reaction kinetics and capacity. The composite Ti₃C₂T_x@MoSe₂ material exhibits a high capacity over 300 mAh·g⁻¹ at 150 mA·g⁻¹ and excellent rate property with a specific capacity of 150 mAh·g⁻¹ at 1500 mA·g⁻¹. Additionally, the material shows a superior capacitive contribution of 86.0% at 2.0 mV·s⁻¹ due to the fast electrochemical reactions. A Ti₃C₂T_x@MoSe₂//AC LIC device is also fabricated and exhibits stable cycle performance.
- two-dimensional titanium carbide;
- molybdenum selenide;
- solvothermal method;
- electrochemical kinetics

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锂离子电容器用MOF衍生硒化钼修饰的Ti₃C₂T_x负极材料性能研究

文章亮点

中文摘要

MOF-derived molybdenum selenide on Ti₃C₂T_x with superior capacitive performance for lithium-ion capacitors

Abstract

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