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Volume 30 Issue 5
May  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(5): 908-916
Jianlin Sun, Boyuan Huang, Jiaqi He, Erchao Meng, and Qianhao Chang, Achieving oxidation protection effect for strips hot rolling via Al2O3 nanofluid lubrication, Int. J. Miner. Metall. Mater., 30(2023), No. 5, pp. 908-916. https://doi.org/10.1007/s12613-022-2493-5
Cite this article as:
Jianlin Sun, Boyuan Huang, Jiaqi He, Erchao Meng, and Qianhao Chang, Achieving oxidation protection effect for strips hot rolling via Al2O3 nanofluid lubrication, Int. J. Miner. Metall. Mater., 30(2023), No. 5, pp. 908-916. https://doi.org/10.1007/s12613-022-2493-5
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研究论文

通过Al2O3纳米流体润滑实现板带钢热轧过程的防氧化

  • 北京科技大学材料科学与工程学院，北京 100083，中国

  • 通讯作者:

    贺佳琪    E-mail: ustbhjq@163.com

文章亮点

  • (1) 创造性地采用Al2O3纳米流体润滑剂同步实现了板带钢热轧工艺润滑和表面防氧化。
  • (2) 借助分子动力学模拟系统地研究了氧化性气体分子在热轧钢板表面的扩散行为。
  • (3) 总结并阐明了Al2O3纳米流体对热轧带钢表面的氧化抑制作用机理。
  • 板带钢热轧过程的氧化损失造成了极高的能源和材料损耗，是近年来的研究热点。而本文研究发现，将Al2O3纳米流体应用于板带钢热轧过程，能够在起到润滑作用的同时同步实现对带钢表面的氧化抑制作用，进一步通过板带钢热轧实验和分子动力学（MD）模拟研究了其作用机理。首先，Al2O3纳米粒子的加入显著提高了润滑剂的润滑性能，使轧后带钢的表面形貌最佳、粗糙度最低、表面缺陷最少。此外，钢板表面生成的氧化皮也变薄，铁氧化物中Fe2O3的比例显著变低。同时，轧后带钢表面有纳米粒子沉积，形成了厚度约193 nm的保护层。保护层主要由Al2O3和烧结的有机分子组成，阻止了钢板基体与空气的直接接触，从而实现了氧化抑制作用。分子动力学模拟结果表明，Al2O3层可以同时通过物理吸附和穿透阻隔效应阻挡了O2和H2O分子向金属基体的扩散。
    • Research Article

    Achieving oxidation protection effect for strips hot rolling via Al2O3 nanofluid lubrication

    + Author Affiliations
      Abstract
    • It was discovered the application of Al2O3 nanofluid as lubricant for steel hot rolling could synchronously achieve oxidation protection of strips surface. The underlying mechanism was investigated through hot rolling tests and molecular dynamics (MD) simulations. The employment of Al2O3 nanoparticles contributed to significant enhancement in the lubrication performance of lubricant. The rolled strip exhibited the best surface topography that the roughness reached lowest with the sparsest surface defects. Besides, the oxide scale generated on steel surface was also thinner, and the ratio of Fe2O3 among various iron oxides became lower. It was revealed the above oxidation protection effect of Al2O3 nanofluid was attributed to the deposition of nanoparticles on metal surface during hot rolling. A protective layer in the thickness of about 193 nm was formed to prevent the direct contact between steel matrix and atmosphere, which was mainly composed of Al2O3 and sintered organic molecules. MD simulations confirmed the diffusion of O2 and H2O could be blocked by the Al2O3 layer through physical absorption and penetration barrier effect.
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