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Volume 30 Issue 3
Mar.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(3): 515-524
Yuanyuan Zhou, Zhongyi Bai, Xiangyang Yang, Wei Liu, Bingbing Fan, Zhikai Yan, and Xiaoqin Guo, In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 515-524. https://doi.org/10.1007/s12613-022-2496-2
Cite this article as:
Yuanyuan Zhou, Zhongyi Bai, Xiangyang Yang, Wei Liu, Bingbing Fan, Zhikai Yan, and Xiaoqin Guo, In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 515-524. https://doi.org/10.1007/s12613-022-2496-2
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研究论文

原位生长NiCo双金属增强多孔秸秆衍生生物碳复合材料的微波吸收性能

  • 1)

    郑州航空大学材料科学与工程学院河南省航空材料与应用技术重点实验室, 郑州 450046, 中国

  • 2)

    中国矿业大学 (北京)化学与环境工程学院,, 北京 100083, 中国

  • 3)

    郑州大学材料科学与工程学院, 郑州 450001, 中国

  • 通讯作者:

    范冰冰    E-mail: fanbingbing@zzu.edu.cn

    郭晓琴    E-mail: guoxq@zua.edu.cn

文章亮点

  • (1) 原位生长NiCo双金属增强多孔秸秆衍生生物碳复合材料可能成为有前途的微波吸收器。
  • (2) 通过水热法和退火工艺制备了具有出色的介电损耗和磁损耗的生物碳/镍钴复合材料。
  • (3) 生物碳/NiCo复合材料的最小反射损耗值在2.2 mm厚度下可达−27.0 dB，对应的吸收带宽(RL≤−10 dB)可达4.4 GHz (11.7~16.1 GHz)。
  • 目前，人们对电磁污染的保护意识逐渐增强，并且具有可再生性和环境友好性的吸收材料也引起人们的广泛关注。在这项工作中，通过高温碳化和水热反应的方法，我们成功制备了由秸秆衍生的生物碳与双金属NiCo组成的复合材料。通过改变镍钴合金的含量可以改变多孔生物碳/镍钴合金复合材料的电磁参数，改善其微波吸收性能。另外，其微波吸收性能的提高主要归功于电磁特性的协同效应，其中包括介电损耗（界面极化、偶极子极化）和磁损耗。值得注意的是，生物碳/NiCo复合材料的最小反射损耗值在2.2 mm厚度下可达−27.0 dB，对应的吸收带宽(RL≤−10 dB)可达4.4 GHz (11.7~16.1 GHz)。这些结果表明，多孔生物碳/镍钴复合材料具有密度低、重量轻、导电性好、吸收能力强、阻抗匹配良好等特点，因此，这种复合材料可以作为新一代的吸波材料。
    • Research Article

    In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties

    + Author Affiliations
      Abstract
    • With the gradually increasing protection awareness about electromagnetic pollution, the demand for absorbing materials with renewability and environmental friendliness has attracted widespread attention. In this work, composites consisting of straw-derived biochar combined with NiCo alloy were successfully fabricated through high-temperature carbonization and subsequent hydrothermal reaction. The electromagnetic parameters of the porous biocarbon/NiCo composites can be effectively modified by altering their NiCo content, and their improved absorbing performance can be attributed to the synergy effect of magnetic–dielectric characteristics. An exceptional reflection loss of −27.0 dB at 2.2 mm thickness and an effective absorption bandwidth of 4.4 GHz (11.7–16.1 GHz) were achieved. These results revealed that the porous biocarbon/NiCo composites could be used as a new generation absorbing material because of their low density, light weight, excellent conductivity, and strong absorption.
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