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Volume 29 Issue 12
Dec.  2022

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Shanjing Liu, Xiaohan Wan, Yue Sun, Shiqi Li, Xingmei Guo, Ming Li, Rui Yin, Qinghong Kong, Jing Kong, and Junhao Zhang, Cobalt-based multicomponent nanoparticles supported on N-doped graphene as advanced cathodic catalyst for zinc–air batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 12, pp. 2212-2220. https://doi.org/10.1007/s12613-022-2498-0
Cite this article as:
Shanjing Liu, Xiaohan Wan, Yue Sun, Shiqi Li, Xingmei Guo, Ming Li, Rui Yin, Qinghong Kong, Jing Kong, and Junhao Zhang, Cobalt-based multicomponent nanoparticles supported on N-doped graphene as advanced cathodic catalyst for zinc–air batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 12, pp. 2212-2220. https://doi.org/10.1007/s12613-022-2498-0
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研究论文

氮掺杂石墨烯负载钴基多组分纳米粒子作为锌空气电池的先进阴极催化剂


  • 通讯作者:

    郭兴梅    E-mail: guoxm@just.edu.cn

    张俊豪    E-mail: jhzhang6@just.edu.cn

文章亮点

  • (1) 采用吸附-络合-煅烧方法制备出钴基多组分纳米颗粒负载在N掺杂石墨烯上。
  • (2) 丰富的活性位点和高效的二维结构使材料展现出优异的氧气还原电催化活性。
  • (3) 所组装的锌空气电池具有高比容量、高稳定性和高倍率性能。
  • 为了提高锌空气电池 (ZABs) 中阴极氧气还原反应 (ORR) 的效率,本文提出了一种吸附–络合–煅烧方法,在石墨烯纳米片上形成包含 Co、Co3O4 和 CoN 的多组分钴基纳米粒子及大量N掺杂原子,获得 Co/Co3O4/CoN/NG复合材料。尺寸小于50 nm的Co/Co3O4/CoN 纳米粒子均匀分散在 N 掺杂石墨烯 (NG) 基底上,极大地改善了ORR的电催化行为。测试结果表明,所制备材料催化ORR的半波电位高达0.80 V vs. RHE,极限电流密度为4.60 mA∙cm−2,与市售的铂/碳 (Pt/C) 催化剂接近。作为ZABs的阴极催化剂,该电池的比容量和开路电压分别为 843.0 mAh∙g1和1.41 V。优异的性能归因于高度分散的Co/Co3O4/CoN纳米颗粒和掺杂氮原子提供了大量的催化活性位点,以及石墨烯二维结构提供了高表面积及快速的电子传输通道。
  • Research Article

    Cobalt-based multicomponent nanoparticles supported on N-doped graphene as advanced cathodic catalyst for zinc–air batteries

    + Author Affiliations
    • To improve the efficiency of cathodic oxygen reduction reaction (ORR) in zinc–air batteries (ZABs), an adsorption–complexation–calcination method was proposed to generate cobalt-based multicomponent nanoparticles comprising Co, Co3O4 and CoN, as well as numerous N heteroatoms, on graphene nanosheets (Co/Co3O4/CoN/NG). The Co/Co3O4/CoN nanoparticles with the size of less than 50 nm are homogeneously dispersed on N-doped graphene (NG) substrate, which greatly improve the catalytic behaviors for ORR. The results show that the half-wave potential is as high as 0.80 V vs. RHE and the limiting current density is 4.60 mA∙cm−2, which are close to those of commercially available platinum/carbon (Pt/C) catalysts. Applying as cathodic catalyst for ZABs, the battery shows large specific capacity and open circuit voltage of 843.0 mAh∙g−1 and 1.41 V, respectively. The excellent performance is attributed to the efficient two-dimensional structure with high accessible surface area and the numerous multiple active sites provided by highly scattered Co/Co3O4/CoN particles and doped nitrogen on the carbon matrix.
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    • 2498-Supplementary Informations.docx
    • [1]
      M. Huang, B.J. Xi, N.X. Shi, et al., Quantum-matter Bi/TiO2 heterostructure embedded in N-doped porous carbon nanosheets for enhanced sodium storage, Small Struct., 2(2021), No. 4, art. No. 2000085. doi: 10.1002/sstr.202000085
      [2]
      Z.J. Liu, F.F. Zheng, W.W. Xiong, X.G. Li, A.H. Yuan, and H. Pang, Strategies to improve electrochemical performances of pristine metal-organic frameworks-based electrodes for lithium/sodium-ion batteries, SmartMat, 2(2021), No. 4, p. 488. doi: 10.1002/smm2.1064
      [3]
      D.W. Wang and D.S. Su, Heterogeneous nanocarbon materials for oxygen reduction reaction, Energy Environ. Sci., 7(2014), No. 2, p. 576. doi: 10.1039/c3ee43463j
      [4]
      X.J. Zheng, X.C. Cao, K. Zeng, et al., A self-jet vapor-phase growth of 3D FeNi@NCNT clusters as efficient oxygen electrocatalysts for zinc–air batteries, Small, 17(2021), No. 4, art. No. e2006183. doi: 10.1002/smll.202006183
      [5]
      P.Q. Chen, Y.X. Tai, H. Wu, Y.F. Gao, J.Y. Chen, and J.G. Cheng, Novel confinement combustion method of nanosized WC/C for efficient electrocatalytic oxygen reduction, Int. J. Miner. Metall. Mater., 29(2022), No. 8, p. 1627. doi: 10.1007/s12613-021-2265-7
      [6]
      J. Shi, X.M. Guo, S.J. Liu, et al., An altered nanoemulsion assembly strategy for in-situ synthesis of Co2P/NP-C nanospheres as advanced oxygen reduction electrocatalyst for zinc–air batteries, Composites Part B, 231(2022), p. 109589. doi: 10.1016/j.compositesb.2021.109589
      [7]
      X.M. Guo, C. Qian, R.H. Shi, et al., Biomorphic Co–N–C/CoOx composite derived from natural chloroplasts as efficient electrocatalyst for oxygen reduction reaction, Small, 15(2019), p. 1804855. doi: 10.1002/smll.201804855
      [8]
      J. Wang, X.P. Cheng, Z.L. Li, et al., Perovskite Sr0.9Y0.1CoO3–δ nanorods modified with CoO nanoparticles as a bifunctional catalyst for rechargeable Li−O2 batteries, ACS Appl. Energy Mater., 1(2018), No. 10, p. 5557.
      [9]
      J.J. Bian, X.P. Cheng, X.Y. Meng, et al., Nitrogen-doped NiCo2O4 microsphere as an efficient catalyst for flexible rechargeable zinc–air batteries and self-charging power system, ACS Appl. Energy Mater., 2(2019), No. 3, p. 2296. doi: 10.1021/acsaem.9b00120
      [10]
      Y. Wang, J. Li, and Z.D. Wei, Transition-metal-oxide-based catalysts for the oxygen reduction reaction, J. Mater. Chem. A, 6(2018), No. 18, p. 8194. doi: 10.1039/C8TA01321G
      [11]
      C. Qian, X.M. Guo, W. Zhang, et al., Co3O4 nanoparticles on porous bio-carbon substrate as catalyst for oxygen reduction reaction, Microporous Mesoporous Mater., 277(2019), p. 45. doi: 10.1016/j.micromeso.2018.10.020
      [12]
      Y.N. Hou, Z. Zhao, H. Zhang, et al., Designed synthesis of cobalt nanoparticles embedded carbon nanocages as bifunctional electrocatalysts for oxygen evolution and reduction, Carbon, 144(2019), p. 492. doi: 10.1016/j.carbon.2018.12.053
      [13]
      I. A, L. Xiaobo, Z.H. pu, et al., From 3D ZIF nanocrystals to Co–Nx/C nanorod array electrocatalysts for ORR, OER and Zn–air batteries, Adv. Funct. Mater., 28(2018), No. 5, art. No. 1704638. doi: 10.1002/adfm.201704638
      [14]
      H.B. Tang, X.L. Tian, J.M. Luo, et al., A Co-doped porous niobium nitride nanogrid as an effective oxygen reduction catalyst, J. Mater. Chem. A, 5(2017), No. 27, p. 14278. doi: 10.1039/C7TA03677A
      [15]
      P. Wei, X.G. Li, Z.M. He, et al., Porous N, B Co-doped carbon nanotubes as efficient metal-free electrocatalysts for ORR and Zn–air batteries, Chem. Eng. J., 422(2021), art. No. 130134. doi: 10.1016/j.cej.2021.130134
      [16]
      X.M. Guo, W. Zhang, J. Shi, et al., A channel-confined strategy for synthesizing CoN–CoOx/C as efficient oxygen reduction electrocatalyst for advanced zinc–air batteries, Nano Res., 15(2022), No. 3, p. 2092. doi: 10.1007/s12274-021-3835-8
      [17]
      X.H. Wan, X.M. Guo, M.T. Duan, et al., Ultrafine CoO nanoparticles and Co–N–C lamellae supported on mesoporous carbon for efficient electrocatalysis of oxygen reduction in zinc–air batteries, Electrochim. Acta, 394(2021), art. No. 139135. doi: 10.1016/j.electacta.2021.139135
      [18]
      Z.K. Yang, C.M. Zhao, Y.T. Qu, et al., Trifunctional self-supporting cobalt-embedded carbon nanotube films for ORR, OER, and HER triggered by solid diffusion from bulk metal, Adv. Mater., 31(2019), No. 12, art. No. e1808043. doi: 10.1002/adma.201808043
      [19]
      T.T. Gao, C.X. Zhou, Y.J. Zhang, Z.Y. Jin, H.Y. Yuan, and D. Xiao, Ultra-fast pyrolysis of ferrocene to form Fe/C heterostructures as robust oxygen evolution electrocatalysts, J. Mater. Chem. A, 6(2018), No. 43, p. 21577. doi: 10.1039/C8TA05733H
      [20]
      E.Y. Choi, D.E. Kim, S.Y. Lee, and C.K. Kim, Electrocatalytic activity of nitrogen-doped holey carbon nanotubes in oxygen reduction and evolution reactions and their application in rechargeable zinc–air batteries, Carbon, 166(2020), p. 245. doi: 10.1016/j.carbon.2020.05.034
      [21]
      W.M. Zhang, X.Y. Yao, S.N. Zhou, et al., ZIF-8/ZIF-67-derived Co-Nx-embedded 1D porous carbon nanofibers with graphitic carbon-encased Co nanoparticles as an efficient bifunctional electrocatalyst, Small, 14(2018), No. 24, p. 1800423. doi: 10.1002/smll.201800423
      [22]
      X. Wang, X.Y. Li, C.B. Ouyang, et al, Nonporous MOF-derived dopant-free mesoporous carbon as an efficient metal-free electrocatalyst for the oxygen reduction reaction, J. Mater. Chem. A, 4(2016), No. 24, p. 9370. doi: 10.1039/C6TA03015G
      [23]
      J. Lim, J.W. Jung, N.Y. Kim, et al., N2-dopant of graphene with electrochemically switchable bifunctional ORR/OER catalysis for Zn–air battery, Energy Storage Mater., 32(2020), p. 517. doi: 10.1016/j.ensm.2020.06.034
      [24]
      C.Z. Zhu and S.J. Dong, Recent progress in graphene-based nanomaterials as advanced electrocatalysts towards oxygen reduction reaction, Nanoscale, 5(2013), No. 5, p. 1753. doi: 10.1039/c2nr33839d
      [25]
      X.W. Wang, G.Z. Sun, P. Routh, D.H. Kim, W. Huang, and P. Chen, Heteroatom-doped graphene materials: Syntheses, properties and applications, Chem. Soc. Rev., 43(2014), No. 20, p. 7067. doi: 10.1039/C4CS00141A
      [26]
      W.H. Chen, G.C. Zhang, D. Li, S.G. Ma, B.D. Wang, and X. Jiang, Preparation of nitrogen-doped porous carbon from waste polyurethane foam by hydrothermal carbonization for H2S adsorption, Ind. Eng. Chem. Res., 59(2020), No. 16, p. 7447.
      [27]
      J.Q. Sun, S.E. Lowe, L.J. Zhang, et al., Ultrathin nitrogen-doped holey carbon@graphene bifunctional electrocatalyst for oxygen reduction and evolution reactions in alkaline and acidic media, Angew. Chem. Int. Ed., 130(2018), No. 50, p. 16749. doi: 10.1002/ange.201811573
      [28]
      J. Oh, S. Park, D. Jang, Y. Shin, D. Lim, and S. Park, Metal-free N-doped carbon blacks as excellent electrocatalysts for oxygen reduction reactions, Carbon, 145(2019), p. 481. doi: 10.1016/j.carbon.2019.01.056
      [29]
      J.P. Wang, G.K. Han, L.G. Wang, et al., ZIF-8 with ferrocene encapsulated: A promising precursor to single-atom Fe embedded nitrogen-doped carbon as highly efficient catalyst for oxygen electroreduction, Small, 14(2018), No. 15, art. No. 1704282. doi: 10.1002/smll.201704282
      [30]
      D. Wang, X.N. Pan, P.X. Yang, et al., Transition metal and nitrogen co-doped carbon-based electrocatalysts for the oxygen reduction reaction: From active site insights to the rational design of precursors and structures, ChemSusChem, 14(2021), No. 1, p. 33. doi: 10.1002/cssc.202002137
      [31]
      M.R. Wu, M.Y. Gao, S.Y. Zhang, et al., High-performance lithium-sulfur battery based on porous N-rich g-C3N4 nanotubes via a self-template method, Int. J. Miner. Metall. Mater., 28(2021), No. 10, p. 1656. doi: 10.1007/s12613-021-2319-x
      [32]
      M.T. Duan, M.R. Wu, K. Xue, et al., Preparation of Co/SnO2@NC/S composites as high-stability cathode material for lithium-sulfur batteries, Int. J. Miner. Metall. Mater., 28(2021), No. 10, p. 1647. doi: 10.1007/s12613-021-2315-1
      [33]
      J.L. Chen, X.M. Guo, M.Y. Gao, et al., Free-supporting dual-confined porous Si@c-ZIF@carbon nanofibersfor high-performance lithium-ion batteries, Chem. Commun., 57(2021), p. 10580. doi: 10.1039/D1CC04172J
      [34]
      C. Cai, M.Y. Wang, S.B. Han, et al., Ultrahigh oxygen evolution reaction activity achieved using Ir single atoms on amorphous CoOx nanosheets, ACS Catal., 11(2021), No. 1, p. 123. doi: 10.1021/acscatal.0c04656
      [35]
      J.Y. Qin, Z.W. Liu, D.Y. Wu, and J. Yang, Optimizing the electronic structure of cobalt via synergized oxygen vacancy and Co–N–C to boost reversible oxygen electrocatalysis for rechargeable Zn–air batteries, Appl. Catal. B, 278(2020), art. No. 119300. doi: 10.1016/j.apcatb.2020.119300
      [36]
      J.T. Jin, X.G. Fu, Q. Liu, and J.Y. Zhang, A highly active and stable electrocatalyst for the oxygen reduction reaction based on a graphene-supported g-C3N4@cobalt oxide core-shell hybrid in alkaline solution, J. Mater. Chem. A, 1(2013), No. 35, p. 10538. doi: 10.1039/c3ta11144j
      [37]
      D.W. Chen, C.L. Dong, Y.Q. Zou, et al., In situ evolution of highly dispersed amorphous CoOx clusters for oxygen evolution reaction, Nanoscale, 9(2017), No. 33, p. 11969. doi: 10.1039/C7NR04381C
      [38]
      W.Q. Kong, K.K. Yao, X.D. Duan, Z.G. Liu, and J.W. Hu, Holey Co, N-codoped graphene aerogel with in-plane pores and multiple active sites for efficient oxygen reduction, Electrochim. Acta., 269(2018), p. 544.
      [39]
      S.W. Liu, H.M. Zhang, Q. Zhao, et al., Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions, Carbon, 106(2016), p. 74. doi: 10.1016/j.carbon.2016.05.021
      [40]
      T.T. Li, Y.X. Lu, S.S. Zhao, Z.D. Gao, and Y.Y. Song, Co3O4-doped Co/CoFe nanoparticles encapsulated in carbon shells as bifunctional electrocatalysts for rechargeable Zn–air batteries, J. Mater. Chem. A, 6(2018), No. 8, p. 3730. doi: 10.1039/C7TA11171A
      [41]
      S. Mao, Z.H. Wen, T.Z. Huang, Y. Hou, and J.H. Chen, High-performance bi-functional electrocatalysts of 3D crumpled graphene–cobalt oxide nanohybrids for oxygen reduction and evolution reactions, Energy Environ. Sci., 7(2014), No. 2, p. 609. doi: 10.1039/C3EE42696C
      [42]
      Z.Y. Guo, F.M. Wang, Y. Xia, et al., In situ encapsulation of core-shell-structured Co@Co3O4 into nitrogen-doped carbon polyhedra as a bifunctional catalyst for rechargeable Zn–air batteries, J. Mater. Chem. A, 6(2018), No. 4, p. 1443. doi: 10.1039/C7TA09958D
      [43]
      P. Yu, L. Wang, F.F. Sun, et al., Co nanoislands rooted on Co–N–C nanosheets as efficient oxygen electrocatalyst for Zn–air batteries, Adv. Mater., 31(2019), No. 30, art. No. 1901666.

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