留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 30 Issue 1
Jan.  2023
Turn off MathJax
目录

图(7)  / 表(2)

数据统计

分享

计量
  • 文章访问数:  994
  • HTML全文浏览量:  389
  • PDF下载量:  45
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(1): 54-62
Nuo Xu, Zirui Yuan, Zhihong Ma, Xinli Guo, Yunfeng Zhu, Yongjin Zou,  and Yao Zhang, Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 54-62. https://doi.org/10.1007/s12613-022-2510-8
Cite this article as:
Nuo Xu, Zirui Yuan, Zhihong Ma, Xinli Guo, Yunfeng Zhu, Yongjin Zou,  and Yao Zhang, Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 54-62. https://doi.org/10.1007/s12613-022-2510-8
shu
引用本文 PDF XML SpringerLink
研究论文

高分散性Ni纳米颗粒催化MgH2储氢性能研究

  • 1)

    东南大学材料科学与工程学院，南京 211189，中国

  • 2)

    百色学院材料科学与工程学院，百色 533000，中国

  • 3)

    南京工业大学材料科学与工程学院，南京 211189，中国

  • 4)

    桂林电子科技大学广西信息材料重点实验室，桂林 541004，中国

    • * 共同第一作者
  • 通讯作者:

    张耀    E-mail: zhangyao@seu.edu.cn

文章亮点

  • (1) 成功合成平均粒径仅为2.14 nm的Ni颗粒。
  • (2) 10wt%的Ni纳米颗粒的加入即可有效降低MgH2的脱氢焓。
  • (3) 纳米镍成为参与脱氢反应–催化脱氢反应的双功能添加剂，显著改善了MgH2的热力学和动力学性能。
  • 氢能是一种清洁高效的二次能源，有希望从根本上解决人类面临的生态环境危机以及化石能源枯竭问题。在固态储氢材料中，MgH2因其重量轻、储量丰富、无毒、储氢容量大而备受关注，是一种很有前途的储氢材料。但是，它也存在着热稳定性高和动力学迟缓的问题。本文采用多元醇还原法制备了平均尺寸为2.14 nm的高度分散的Ni纳米颗粒，系统的研究了Ni纳米颗粒对MgH2体系的影响，以及Ni纳米颗粒对MgH2体系的催化机理。研究表明Ni纳米颗粒可以显著提高MgH2体系的储氢性能。样品MgH2–10wt% nano-Ni可以在温度达到497 K时开始释放H2，在温度为583 K时完全脱氢，脱氢量为6.2wt%；此外，该样品在温度为482 K，氢压3 MPa的条件下，1000 s内可逆吸附容量达到5.3wt%。通过室温至673 K的原位XRD测试发现脱氢反应中出现了Mg2Ni和Ni相；而在吸氢样品的透镜图中，发现了Mg2NiH4与Ni相。此外金属Ni纳米颗粒同时会作为催化剂诱导MgH2的分解与吸附。Ni纳米颗粒会导致MgH2体系的降稳，此现象可通过PCI曲线和范特霍夫方程式计算验证。本文这一发现表明Ni纳米颗粒作为一种双功能的添加剂能够显著改善MgH2体系的动力学和热力学性能。
    • Research Article

    Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2

    + Author Affiliations
      Abstract
    • MgH2 with a large hydrogen capacity is regarded as a promising hydrogen storage material. However, it still suffers from high thermal stability and sluggish kinetics. In this paper, highly dispersed nano-Ni has been successfully prepared by using the polyol reduction method with an average size of 2.14 nm, which significantly improves the de/rehydrogenation properties of MgH2. The MgH2–10wt% nano-Ni sample starts releasing H2 at 497 K, and roughly 6.2wt% H2 has been liberated at 583 K. The rehydrogenation kinetics of the sample are also greatly improved, and the adsorption capacity reaches 5.3wt% H2 in 1000 s at 482 K and under 3 MPa hydrogen pressure. Moreover, the activation energies of de/rehydrogenation of the MgH2–10wt% nano-Ni sample are reduced to (88 ± 2) and (87 ± 1) kJ·mol−1, respectively. In addition, the thermal stability of the MgH2–10wt% nano-Ni system is reduced by 5.5 kJ per mol H2 from that of pristine MgH2. This finding indicates that nano-Ni significantly improves both the thermodynamic and kinetic performances of the de/rehydrogenation of MgH2, serving as a bi-functional additive of both reagent and catalyst.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(55)
    • [1]
      X.L. Yang, J.Q. Zhang, Q.H. Hou, X.T. Guo, and G.Z. Xu, Improvement of Mg-based hydrogen storage materials by metal catalysts: Review and summary, ChemistrySelect, 6(2021), No. 33, p. 8809. doi: 10.1002/slct.202102475
      [2]
      T. He, H.J. Cao, and P. Chen, Complex hydrides for energy storage, conversion, and utilization, Adv. Mater., 31(2019), No. 50, art. No. 1902757. doi: 10.1002/adma.201902757
      [3]
      Y.R. Wang, X.W. Chen, H.Y. Zhang, G.L. Xia, D.L. Sun, and X.B. Yu, Heterostructures built in metal hydrides for advanced hydrogen storage reversibility, Adv. Mater., 32(2020), No. 31, art. No. 2002647. doi: 10.1002/adma.202002647
      [4]
      X. Zhao, S.M. Han, Y. Li, X.C. Chen, and D.D. Ke, Effect of CeH2.29 on the microstructures and hydrogen properties of LiBH4–Mg2NiH4 composites, Int. J. Miner. Metall. Mater., 22(2015), No. 4, p. 423. doi: 10.1007/s12613-015-1089-8
      [5]
      Q. Li, X. Lin, Q. Luo, et al., Kinetics of the hydrogen absorption and desorption processes of hydrogen storage alloys: A review, Int. J. Miner. Metall. Mater., 29(2022), No. 1, p. 32. doi: 10.1007/s12613-021-2337-8
      [6]
      X.B. Yu, Z.W. Tang, D.L. Sun, L.Z. Ouyang, and M. Zhu, Recent advances and remaining challenges of nanostructured materials for hydrogen storage applications, Prog. Mater. Sci., 88(2017), p. 1. doi: 10.1016/j.pmatsci.2017.03.001
      [7]
      M.D. Allendorf, Z. Hulvey, T. Gennett, et al., An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage, Energy Environ. Sci., 11(2018), No. 10, p. 2784. doi: 10.1039/C8EE01085D
      [8]
      B. Sakintuna, F. Lamari-Darkrim, and M. Hirscher, Metal hydride materials for solid hydrogen storage: A review, Int. J. Hydrogen Energy, 32(2007), No. 9, p. 1121. doi: 10.1016/j.ijhydene.2006.11.022
      [9]
      I. Sreedhar, K.M. Kamani, B.M. Kamani, B.M. Reddy, and A. Venugopal, A Bird's Eye view on process and engineering aspects of hydrogen storage, Renewable Sustainable Energy Rev., 91(2018), p. 838. doi: 10.1016/j.rser.2018.04.028
      [10]
      J.Z. Song, Z.Y. Zhao, X. Zhao, R.D. Fu, and S.M. Han, Hydrogen storage properties of MgH2 co-catalyzed by LaH3 and NbH, Int. J. Miner. Metall. Mater., 24(2017), No. 10, p. 1183. doi: 10.1007/s12613-017-1509-z
      [11]
      M. Hirscher, V.A. Yartys, M. Baricco, et al., Materials for hydrogen-based energy storage –Past, recent progress and future outlook, J. Alloys Compd., 827(2020), art. No. 153548. doi: 10.1016/j.jallcom.2019.153548
      [12]
      L.Z. Ouyang, X.S. Yang, M. Zhu, et al., Enhanced hydrogen storage kinetics and stability by synergistic effects of in situ formed CeH2.73 and Ni in CeH2.73–MgH2–Ni nanocomposites, J. Phys. Chem. C, 118(2014), No. 15, p. 7808. doi: 10.1021/jp500439n
      [13]
      J.O. Abe, A.P.I. Popoola, E. Ajenifuja, and O.M. Popoola, Hydrogen energy, economy and storage: Review and recommendation, Int. J. Hydrogen Energy, 44(2019), No. 29, p. 15072. doi: 10.1016/j.ijhydene.2019.04.068
      [14]
      I.P. Jain, C. Lal, and A. Jain, Hydrogen storage in Mg: A most promising material, Int. J. Hydrogen Energy, 35(2010), No. 10, p. 5133. doi: 10.1016/j.ijhydene.2009.08.088
      [15]
      J.F. Zhang, Z.N. Li, Y.F. Wu, et al., Recent advances on the thermal destabilization of Mg-based hydrogen storage materials, RSC Adv., 9(2019), No. 1, p. 408. doi: 10.1039/C8RA05596C
      [16]
      F. Dawood, M. Anda, and G.M. Shafiullah, Hydrogen production for energy: An overview, Int. J. Hydrogen Energy, 45(2020), No. 7, p. 3847. doi: 10.1016/j.ijhydene.2019.12.059
      [17]
      Q. Luo, J.D. Li, B. Li, B. Liu, H.Y. Shao, and Q. Li, Kinetics in Mg-based hydrogen storage materials: Enhancement and mechanism, J. Magnes. Alloys, 7(2019), No. 1, p. 58. doi: 10.1016/j.jma.2018.12.001
      [18]
      X.B. Xie, C.X. Hou, C.G. Chen, et al., First-principles studies in Mg-based hydrogen storage materials: A review, Energy, 211(2020), art. No. 118959. doi: 10.1016/j.energy.2020.118959
      [19]
      C.S. Zhou, Z.Z. Fang, and P. Sun, An experimental survey of additives for improving dehydrogenation properties of magnesium hydride, J. Power Sources, 278(2015), p. 38. doi: 10.1016/j.jpowsour.2014.12.039
      [20]
      Z. Abdin, A. Zafaranloo, A. Rafiee, W. Mérida, W. Lipiński, and K.R. Khalilpour, Hydrogen as an energy vector, Renewable Sustainable Energy Rev., 120(2020), art. No. 109620. doi: 10.1016/j.rser.2019.109620
      [21]
      L.Z. Ouyang, K. Chen, J. Jiang, X.S. Yang, and M. Zhu, Hydrogen storage in light-metal based systems: A review, J. Alloys Compd., 829(2020), art. No. 154597. doi: 10.1016/j.jallcom.2020.154597
      [22]
      F. Li, X. Jiang, J.J. Zhao, and S.B. Zhang, Graphene oxide: A promising nanomaterial for energy and environmental applications, Nano Energy, 16(2015), p. 488. doi: 10.1016/j.nanoen.2015.07.014
      [23]
      P. Rizo-Acosta, F. Cuevas, and M. Latroche, Hydrides of early transition metals as catalysts and grain growth inhibitors for enhanced reversible hydrogen storage in nanostructured magnesium, J. Mater. Chem. A, 7(2019), No. 40, p. 23064. doi: 10.1039/C9TA05440E
      [24]
      L.Z. Ouyang, F. Liu, H. Wang, et al., Magnesium-based hydrogen storage compounds: A review, J. Alloys Compd., 832(2020), art. No. 154865. doi: 10.1016/j.jallcom.2020.154865
      [25]
      E. Boateng and A.C. Chen, Recent advances in nanomaterial-based solid-state hydrogen storage, Mater. Today Adv., 6(2020), art. No. 100022. doi: 10.1016/j.mtadv.2019.100022
      [26]
      X. Zhang, Y.F. Liu, Z.H. Ren, et al., Realizing 6.7 wt.% reversible storage of hydrogen at ambient temperature with non-confined ultrafine magnesium hydrides, Energy Environ. Sci., 14(2021), No. 4, p. 2302. doi: 10.1039/D0EE03160G
      [27]
      J.C. Crivello, B. Dam, R.V. Denys, et al., Review of magnesium hydride-based materials: Development and optimisation, Appl. Phys. A, 122(2016), No. 2, art. No. 97. doi: 10.1007/s00339-016-9602-0
      [28]
      H. Wang, H.J. Lin, W.T. Cai, L.Z. Ouyang, and M. Zhu, Tuning kinetics and thermodynamics of hydrogen storage in light metal element based systems – A review of recent progress, J. Alloys Compd., 658(2016), p. 280. doi: 10.1016/j.jallcom.2015.10.090
      [29]
      H.Y. Shao, L.Q. He, H.J. Lin, and H.W. Li, Progress and trends in magnesium-based materials for energy-storage research: A review, Energy Technol., 6(2018), No. 3, p. 445. doi: 10.1002/ente.201700401
      [30]
      Y. Wang and Y.J. Wang, Recent advances in additive-enhanced magnesium hydride for hydrogen storage, Prog. Nat. Sci. Mater. Int., 27(2017), No. 1, p. 41. doi: 10.1016/j.pnsc.2016.12.016
      [31]
      M.E. Khatabi, M. Bhihi, S. Naji, et al., Study of doping effects with 3d and 4d-transition metals on the hydrogen storage properties of MgH2, Int. J. Hydrogen Energy, 41(2016), No. 8, p. 4712. doi: 10.1016/j.ijhydene.2016.01.001
      [32]
      S. Chakrabarti and K. Biswas, Effect on de-hydrogenation efficiency on doping of rare earth elements (Pr, Nd, Gd, Dy) in MgH2 – A density functional theory study, Int. J. Hydrogen Energy, 42(2017), No. 2, p. 1012. doi: 10.1016/j.ijhydene.2016.08.152
      [33]
      X.L. Zhang, Y.F. Liu, X. Zhang, J.J. Hu, M.X. Gao, and H.G. Pan, Empowering hydrogen storage performance of MgH2 by nanoengineering and nanocatalysis, Mater. Today Nano, 9(2020), art. No. 100064. doi: 10.1016/j.mtnano.2019.100064
      [34]
      V.A. Yartys, M.V. Lototskyy, E. Akiba, et al., Magnesium based materials for hydrogen based energy storage: Past, present and future, Int. J. Hydrogen Energy, 44(2019), No. 15, p. 7809. doi: 10.1016/j.ijhydene.2018.12.212
      [35]
      Z. Sun, X. Lu, F.M. Nyahuma, et al., Enhancing hydrogen storage properties of MgH2 by transition metals and carbon materials: A brief review, Front. Chem., 8(2020), art. No. 552. doi: 10.3389/fchem.2020.00552
      [36]
      N. Hanada, T. Ichikawa, and H. Fujii, Catalytic effect of nanoparticle 3d-transition metals on hydrogen storage properties in magnesium hydride MgH2 prepared by mechanical milling, J. Phys. Chem. B, 109(2005), No. 15, p. 7188. doi: 10.1021/jp044576c
      [37]
      M. Lakhal, M. Bhihi, A. Benyoussef, A.E. Kenz, M. Loulidi, and S. Naji, The hydrogen ab/desorption kinetic properties of doped magnesium hydride MgH2 systems by first principles calculations and kinetic Monte Carlo simulations, Int. J. Hydrogen Energy, 40(2015), No. 18, p. 6137. doi: 10.1016/j.ijhydene.2015.02.137
      [38]
      H. Yu, S. Bennici, and A. Auroux, Hydrogen storage and release: Kinetic and thermodynamic studies of MgH2 activated by transition metal nanoparticles, Int. J. Hydrogen Energy, 39(2014), No. 22, p. 11633. doi: 10.1016/j.ijhydene.2014.05.069
      [39]
      L.S. Xie, J.S. Li, T.B. Zhang, and H.C. Kou, Understanding the dehydrogenation process of MgH2 from the recombination of hydrogen atoms, Int. J. Hydrogen Energy, 41(2016), No. 13, p. 5716. doi: 10.1016/j.ijhydene.2016.02.059
      [40]
      M. Chen, X.Z. Xiao, M. Zhang, et al., Excellent synergistic catalytic mechanism of in-situ formed nanosized Mg2Ni and multiple valence titanium for improved hydrogen desorption properties of magnesium hydride, Int. J. Hydrogen Energy, 44(2019), No. 3, p. 1750. doi: 10.1016/j.ijhydene.2018.11.118
      [41]
      H.X. Shao, Y.K. Huang, H.N. Guo, Y.F. Liu, Y.S. Guo, and Y.J. Wang, Thermally stable Ni MOF catalyzed MgH2 for hydrogen storage, Int. J. Hydrogen Energy, 46(2021), No. 76, p. 37977. doi: 10.1016/j.ijhydene.2021.09.045
      [42]
      Y.K. Huang, C.H. An, Q.Y. Zhang, et al., Cost-effective mechanochemical synthesis of highly dispersed supported transition metal catalysts for hydrogen storage, Nano Energy, 80(2021), art. No. 105535. doi: 10.1016/j.nanoen.2020.105535
      [43]
      Q.Y. Zhang, L. Zang, Y.K. Huang, et al., Improved hydrogen storage properties of MgH2 with Ni-based compounds, Int. J. Hydrogen Energy, 42(2017), No. 38, p. 24247. doi: 10.1016/j.ijhydene.2017.07.220
      [44]
      M.S. El-Eskandarany, E. Shaban, N. Ali, F. Aldakheel, and A. Alkandary, In-situ catalyzation approach for enhancing the hydrogenation/dehydrogenation kinetics of MgH2 powders with Ni particles, Sci. Rep., 6(2016), art. No. 37335. doi: 10.1038/srep37335
      [45]
      T.Z. Si, X.Y. Zhang, J.J. Feng, X.L. Ding, and Y.T. Li, Enhancing hydrogen sorption in MgH2 by controlling particle size and contact of Ni catalysts, Rare Met., 40(2021), No. 4, p. 995. doi: 10.1007/s12598-018-1087-x
      [46]
      H.G. Gao, R. Shi, J.L. Zhu, et al., Interface effect in sandwich like Ni/Ti3C2 catalysts on hydrogen storage performance of MgH2, Appl. Surf. Sci., 564(2021), art. No. 150302. doi: 10.1016/j.apsusc.2021.150302
      [47]
      J. Chen, G.L. Xia, Z.P. Guo, Z.G. Huang, H.K. Liu, and X.B. Yu, Porous Ni nanofibers with enhanced catalytic effect on the hydrogen storage performance of MgH2, J. Mater. Chem. A, 3(2015), No. 31, p. 15843. doi: 10.1039/C5TA03721B
      [48]
      W. Zhu, S. Panda, C. Lu, et al., Using a self-assembled two-dimensional MXene-based catalyst (2D-Ni@Ti3C2) to enhance hydrogen storage properties of MgH2, ACS Appl. Mater. Interfaces, 12(2020), No. 45, p. 50333. doi: 10.1021/acsami.0c12767
      [49]
      D. Rahmalina, R.A. Rahman, A. Suwandi, and Ismail, The recent development on MgH2 system by 16 wt.% nickel addition and particle size reduction through ball milling: A noticeable hydrogen capacity up to 5 wt.% at low temperature and pressure, Int. J. Hydrogen Energy, 45(2020), No. 53, p. 29046. doi: 10.1016/j.ijhydene.2020.07.209
      [50]
      G. Chen, Y. Zhang, J. Chen, X.L. Guo, Y.F. Zhu, and L.Q. Li, Enhancing hydrogen storage performances of MgH2 by Ni nano-particles over mesoporous carbon CMK-3, Nanotechnology, 29(2018), No. 26, art. No. 265705. doi: 10.1088/1361-6528/aabcf3
      [51]
      H.H. Cheng, G. Chen, Y. Zhang, Y.F. Zhu, and L.Q. Li, Boosting low-temperature de/re-hydrogenation performances of MgH2 with Pd–Ni bimetallic nanoparticles supported by mesoporous carbon, Int. J. Hydrogen Energy, 44(2019), No. 21, p. 10777. doi: 10.1016/j.ijhydene.2019.02.218
      [52]
      P. Plerdsranoy, S. Thiangviriya, P. Dansirima, et al., Synergistic effects of transition metal halides and activated carbon nanofibers on kinetics and reversibility of MgH2, J. Phys. Chem. Solids, 124(2019), p. 81. doi: 10.1016/j.jpcs.2018.09.001
      [53]
      T.P. Huang, J.X. Zou, H.B. Liu, and W.J. Ding, Effect of different transition metal fluorides TMFx (TM=Nb, Co, Ti) on hydrogen storage properties of the 3NaBH4–GdF3 system, J. Alloys Compd., 823(2020), art. No. 153716. doi: 10.1016/j.jallcom.2020.153716
      [54]
      F.H. Wang, Y.F. Liu, M.X. Gao, K. Luo, H.G. Pan, and Q.D. Wang, Formation reactions and the thermodynamics and kinetics of dehydrogenation reaction of mixed alanate Na2LiAlH6, J. Phys. Chem. C, 113(2009), No. 18, p. 7978. doi: 10.1021/jp9011697
      [55]
      N. Patelli, M. Calizzi, A. Migliori, V. Morandi, and L. Pasquini, Hydrogen desorption below 150°C in MgH2–TiH2 composite nanoparticles: Equilibrium and kinetic properties, J. Phys. Chem. C, 121(2017), No. 21, p. 11166. doi: 10.1021/acs.jpcc.7b03169
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计