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Volume 30 Issue 4
Apr.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(4): 689-696
Dongpeng Wang, Guang Chen, Anding Wang, Yuxin Wang, Yanxin Qiao, Zhenguang Liu, Zhixiang Qi, and Chain Tsuan Liu, Corrosion behavior of single- and poly-crystalline dual-phase TiAl–Ti3Al alloy in NaCl solution, Int. J. Miner. Metall. Mater., 30(2023), No. 4, pp. 689-696. https://doi.org/10.1007/s12613-022-2513-5
Cite this article as:
Dongpeng Wang, Guang Chen, Anding Wang, Yuxin Wang, Yanxin Qiao, Zhenguang Liu, Zhixiang Qi, and Chain Tsuan Liu, Corrosion behavior of single- and poly-crystalline dual-phase TiAl–Ti3Al alloy in NaCl solution, Int. J. Miner. Metall. Mater., 30(2023), No. 4, pp. 689-696. https://doi.org/10.1007/s12613-022-2513-5
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研究论文

单晶和多晶TiAl–Ti3Al双相合金在NaCl溶液中腐蚀行为的研究

  • 1)

    江苏科技大学材料科学与工程学院，镇江 212100，中国

  • 2)

    香港城市大学机械与生物力学工程系，香港 999077，中国

  • 3)

    南京理工大学材料评价与设计教育部工程研究中心，南京 210094，中国

  • 4)

    东莞理工学院材料科学与工程学院，东莞 523808，中国

  • 通讯作者:

    王冬朋    E-mail: dpwang@just.edu.cn

    王宇鑫    E-mail: ywan943@163.com

文章亮点

  • (1) 使用定向凝固方法制备了单晶TiAl-Ti3Al双相合金。
  • (2) 单晶TiAl–Ti3Al双相合金比多晶合金具有更高的耐蚀性能。
  • (3) 单晶合金中Nb元素的均匀分布提高了钝化膜的防护性能。
  • 钛合金由于具有优异的力学和耐腐蚀性能，使得其在航空航天等领域具有重要应用价值。然而，单晶结构对钛合金腐蚀行为的影响及其机制并不明确。为了阐明高强度TiAl合金中单晶结构与其腐蚀性能的关联性，使用电化学和表面表征等方法，本文深入探究了Ti–45Al–8Nb双相单晶及其多晶合金在NaCl溶液中腐蚀性能的差异。动电位极化曲线显示，双相单晶合金的腐蚀速率较低，相比于多晶合金，点蚀电位高出约280 mV。电化学阻抗谱和恒电位极化图显示单晶合金表面钝化膜的电荷转移电阻更高，这是因为其钝化膜中Nb元素含量较高。本文的结果表明，由于单晶合金微观结构和成分分布更加均匀，与多晶合金相比，双相Ti–45Al–8Nb单晶合金在NaCl溶液中具有更高的耐蚀性。
    • Research Article

    Corrosion behavior of single- and poly-crystalline dual-phase TiAl–Ti3Al alloy in NaCl solution

    + Author Affiliations
      Abstract
    • To clarify the correlation of single-crystalline structure with corrosion performance in high-strength TiAl alloys, electrochemical and surface characterization was performed by comparing Ti–45Al–8Nb dual-phase single crystals with their polycrystalline counterparts in NaCl solution. Polarization curves show a lower corrosion rate and a higher pitting potential of ~280 mV for the dual-phase single crystals. Electrochemical impedance spectroscopy and potentiostatic polarization plots revealed a higher impedance of the charge transfer through the compact passive film. Surface composition analysis indicated a compact film with more content of Nb, as twice as that in the film on the polycrystals. Our results reflect that the dual-phase Ti–45Al–8Nb single crystals possess a higher corrosion resistance in NaCl solution, compared with their polycrystalline counterpart, arising from a more homogeneous microstructure and composition distribution.
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