纳米限域镁基储氢材料研究进展：小综述

张晶晶; 张冰; 解秀波; 倪翠; 侯传信; 孙学勤; 杨晓阳; 张玉平; 木村秀夫; 杜伟

doi:10.1007/s12613-022-2519-z

Volume 30 Issue 1

Jan. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(1): 14-24

Jingjing Zhang, Bing Zhang, Xiubo Xie, Cui Ni, Chuanxin Hou, Xueqin Sun, Xiaoyang Yang, Yuping Zhang, Hideo Kimura, and Wei Du, Recent advances in the nanoconfinement of Mg-related hydrogen storage materials: A minor review, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 14-24. https://doi.org/10.1007/s12613-022-2519-z

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Jingjing Zhang, Bing Zhang, Xiubo Xie, Cui Ni, Chuanxin Hou, Xueqin Sun, Xiaoyang Yang, Yuping Zhang, Hideo Kimura, and Wei Du, Recent advances in the nanoconfinement of Mg-related hydrogen storage materials: A minor review, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 14-24. https://doi.org/10.1007/s12613-022-2519-z

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特约综述

纳米限域镁基储氢材料研究进展：小综述

烟台大学环境与材料工程学院，烟台 264005，中国

通讯作者:
解秀波 E-mail: xiuboxie@ytu.edu.cn

杜伟 E-mail: duwei@ytu.edu.cn

文章亮点

(1) 系统综述了纳米限域不同方法的优缺点。

(2) 从不同纳米限域支撑材料的角度进行了综述。

(3) 阐明了通过纳米限域法从降低颗粒尺寸的角度极大的改善了镁基储氢的性能。

中文摘要

氢气因其高热值、来源丰富而被认为是一种理想的清洁能源。然而，要想以一种高密度、廉价和安全的方式储存氢是氢能蓬勃发展的主要限制。镁基储氢材料具有储氢容量大（7.6wt%）、性能好、成本低等优点，被认为是一种很有前途的固态储氢材料。但目前仍需要克服高热力学稳定性和缓慢动力学上的障碍。解决这些问题的方法大致分为添加催化剂和控制颗粒尺寸两种。而许多研究都表明镁颗粒可以很容易地进入到支撑模板的孔隙中，在这个过程中由于模板孔隙限制的原因可以有效的限制颗粒聚集从而达到控制材料尺寸的效果，这种方法我们把它称为纳米限域。本文综述了纳米限域对镁基储氢性能学的影响，总结了通过不同种类的限域材料原位氢化或熔融法等方式达到限域目的的研究，减低颗粒尺寸的同时可以显著改善储氢动力学性能。这项工作为利用纳米限域法设计高性能镁基材料的提供了应用前景。

关键词:

Invited Review

Recent advances in the nanoconfinement of Mg-related hydrogen storage materials: A minor review

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Abstract

Abstract

Hydrogen is an ideal clean energy because of its high calorific value and abundance of sources. However, storing hydrogen in a compact, inexpensive, and safe manner is the main restriction on the extensive utilization of hydrogen energy. Magnesium (Mg)-based hydrogen storage material is considered a reliable solid hydrogen storage material with the advantages of high hydrogen storage capacity (7.6wt%), good performance, and low cost. However, the high thermodynamic stability and slow kinetics of Mg-based hydrogen storage materials have to be overcome. In this paper, we will review the recent advances in the nanoconfinement of Mg-related hydrogen storage materials by loading Mg particles on different supporting materials, including carbons, metal–organic frameworks, and other materials. Perspectives are also provided for designing high-performance Mg-based materials using nanoconfinement.
- magnesium-based materials;
- hydrogen storage;
- nanoconfinement;
- carbon materials

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