壳聚糖衍生的碳膜用于水系锌电池锌阳极的保护层

李海超; 魏增武; 夏雨; 韩峻山; 李星

doi:10.1007/s12613-022-2525-1

Volume 30 Issue 4

Apr. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(4): 621-629

Haichao Li, Zengwu Wei, Yu Xia, Junshan Han, and Xing Li, Chitosan derived carbon membranes as protective layers on zinc anodes for aqueous zinc batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 4, pp. 621-629. https://doi.org/10.1007/s12613-022-2525-1

Cite this article as:

Haichao Li, Zengwu Wei, Yu Xia, Junshan Han, and Xing Li, Chitosan derived carbon membranes as protective layers on zinc anodes for aqueous zinc batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 4, pp. 621-629. https://doi.org/10.1007/s12613-022-2525-1

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研究论文

壳聚糖衍生的碳膜用于水系锌电池锌阳极的保护层

宁波大学材料科学与化学工程学院，宁波 315211，中国

通讯作者:
韩峻山 E-mail: jshan10@163.com

李星 E-mail: lixing@nbu.edu.cn

文章亮点

(1) 系统研究了不同烧结温度对碳膜微观结构的影响。

(2) 开发出了能保持较长循环使用寿命和较好稳定性的水性锌电池。

(3) 制备的碳膜能有效诱导锌离子的均匀沉积和抑制枝晶生长。

中文摘要

水系锌电池(ZBs)具有成本低、安全性高等优点，被认为是最有前景的储能装置。然而，在放电和充电的过程中，负极上的异常生长的锌枝晶导致其较差的循环稳定性和低库伦效率低。壳聚糖是一种天然的富含氮和碳的氨基多糖。当高温烧结时，形成的碳膜具有优异的导电性和石墨化程度，碳膜可以增强锌离子均匀沉积的性能。本文以壳聚糖为原料，通过烧结制备了一种碳膜，并将其作为水系锌电池电极的保护层材料。结果表明，当采用800°C的烧结温度时，样品可以保持更光滑的表面，组装的电池在0.25 mA·cm⁻²的电流密度下可以循环使用达到700 h左右，远大于没有碳膜保护层的同类电池。

关键词:

碳膜;
枝晶;
壳聚糖;
烧结;
锌电池

Research Article

Chitosan derived carbon membranes as protective layers on zinc anodes for aqueous zinc batteries

+ Author Affiliations

Abstract

Abstract

Aqueous zinc batteries with low cost and inherent safety are considered to be the most promising energy storage devices. However, they suffer from poor cycling stability and low coulombic efficiencies caused by the adverse zinc dendrites on the anodes during the discharging/charging processes. Chitosan is a kind of natural amino polysaccharide, which is rich in nitrogen and carbon. When sintered at high temperatures, carbon membranes have been achieved with excellent conductivity and graphitization degree, which could enhance the ability to induce zinc ion uniform deposition to some extent. In this work, a type of carbon membrane using chitosan as raw materials has been fabricated by sintering, and then assembled as the protect layers in aqueous zinc batteries. The results show that the samples could retain smoother surfaces when adopting the sintering temperature of 800°C, and the assembled batteries are able to achieve about 700 h at a current density of 0.25 mA·cm⁻², which is far longer than those of the similar batteries without any carbon membranes.
- carbon membrane;
- dendrites;
- chitosan;
- sintering process;
- zinc batteries

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