工业固废−水泥混合物的制备及其水化：综述

张骞; 刘波; 肖葵; Christian Ekberg; 张深根

doi:10.1007/s12613-022-2538-9

Volume 29 Issue 12

Dec. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(12): 2106-2116

Qian Zhang, Bo Liu, Kui Xiao, Christian Ekberg, and Shengen Zhang, Preparation and hydration of industrial solid waste–cement blends: A review, Int. J. Miner. Metall. Mater., 29(2022), No. 12, pp. 2106-2116. https://doi.org/10.1007/s12613-022-2538-9

Cite this article as:

Qian Zhang, Bo Liu, Kui Xiao, Christian Ekberg, and Shengen Zhang, Preparation and hydration of industrial solid waste–cement blends: A review, Int. J. Miner. Metall. Mater., 29(2022), No. 12, pp. 2106-2116. https://doi.org/10.1007/s12613-022-2538-9

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特约综述

工业固废−水泥混合物的制备及其水化：综述

1)
北京科技大学新材料技术研究院, 北京 100083, 中国
2)
Nuclear Chemistry and Industrial Material Recycling, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg 41296, Sweden
3)
新疆有色金属研究所, 乌鲁木齐 830009, 中国

通讯作者:
刘波 E-mail: liubo@ustb.edu.cn

张深根 E-mail: zhangshengen@mater.ustb.edu.cn

中文摘要

工业固废−水泥混合物具有低碳、低能耗、低污染等优点，然而低碳水泥中工业固废利用率普遍较低。为了应对这一挑战，本文综述了工业固废−水泥混合物研究的最新进展和发展趋势，重点关注工业固废的活化、工业固废−水泥混合物的形成及其相关的水化机制。工业固废经机械活化其平均尺寸通常降至10 µm以下，比表面积增至350 m²/kg以上。热活化可以增加工业固废的玻璃相含量及反应性，其中煤矸石活化温度通常设定为400−1000°C。工业固废在混合物水化中的作用分为物理作用和化学作用。工业固废的物理作用通常作用于混合物水化的早期阶段，随后，工业固废会在水泥水化提供的碱性环境中发生反应，生成C−(A)−S−H凝胶等产物。此外，碱活化会影响工业固废−水泥混合物的水化动力学并改变凝胶产物的比例。最后，讨论了工业固废−水泥混合物的环境影响和成本，以指导利益相关者选择可持续的工业固废。

关键词:

Invited Review

Preparation and hydration of industrial solid waste–cement blends: A review

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Abstract

Abstract

Industrial solid waste (ISW)–cement blends have the advantages of low carbon, low energy consumption, and low pollution, but their clinker replacement level in low carbon cement is generally low. To address this challenge, this study considers the latest progress and development trends in the ISW–cement blend research, focusing on the activation of ISWs, the formation of ISW–cement blends, and their associated hydration mechanisms. After the mechanical activation of ISWs, the D₅₀ (average size) typically drops below 10 µm, and the specific surface area increases above 350 m²/kg. Thermal activation can increase the glassy-phase content and reactivity of ISWs, where the coal gangue activation temperature is usually set at 400–1000°C. Furthermore, the roles of ISWs in the hydration of ISW–cement blends are divided into physical and chemical roles. The physical action of ISWs usually acts in the early stage of the hydration of ISW–cement blends. Subsequently, ISWs participate in the hydration reaction of ISW–cement blends to generate products, such as C–(A)–S–H gels. Moreover, alkali activation affects the hydration kinetics of ISW–cement blends and modifies the proportion of gels. Environmental impacts and costs of ISW–cement blends have also been discussed to guide stakeholders in selecting sustainable ISWs.
- industrial solid waste–cement blend;
- activation technology;
- hydration mechanism;
- carbon emission reduction

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工业固废−水泥混合物的制备及其水化：综述

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Preparation and hydration of industrial solid waste–cement blends: A review

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