面向海工装备耐磨部件的Ti–C–N复合薄膜不同环境条件的摩擦磨损性能

鞠洪博; 周锐; 栾静; Ch Sateesh Kumar; 喻利花; 许俊华; 杨俊峰; 张博威; Filipe Fernandes

doi:10.1007/s12613-022-2551-z

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(1): 144-155

Hongbo Ju, Rui Zhou, Jing Luan, Ch Sateesh Kumar, Lihua Yu, Junhua Xu, Junfeng Yang, Bowei Zhang, and Filipe Fernandes, Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 144-155. https://doi.org/10.1007/s12613-022-2551-z

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Hongbo Ju, Rui Zhou, Jing Luan, Ch Sateesh Kumar, Lihua Yu, Junhua Xu, Junfeng Yang, Bowei Zhang, and Filipe Fernandes, Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 144-155. https://doi.org/10.1007/s12613-022-2551-z

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研究论文

面向海工装备耐磨部件的Ti–C–N复合薄膜不同环境条件的摩擦磨损性能

1)
江苏科技大学材料科学与工程学院，镇江 212003，中国
2)
CEMMPRE—Centre for Mechanical Engineering Materials and Processes, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
3)
Center for Aeronautics Advanced Manufacturing, University of the Basque Country UPV/EHU, Bilbao 48170, Spain
4)
ISEP-School of Engineering, Polytechnic of Porto, Porto 4200-072, Portugal
5)
中国科学院合肥物理研究所固体物理研究所，合肥 230031，中国
6)
北京科技大学先进材料与技术研究所，北京 100083，中国

通讯作者:
鞠洪博    E-mail: hbju@just.edu.cn

许俊华    E-mail: jhxu@just.edu.cn

杨俊峰    E-mail: jfyang@issp.ac.cn

文章亮点

(1) 系统地研究了C含量对Ti–C–N复合薄膜微观组织的影响规律。

(2) 揭示了C对Ti–C–N复合薄膜空气和水环境下的减摩和耐磨行为的影响。

(3) 基于微电池理论获得了Ti–C–N复合薄膜海水环境耐磨损行为规律。

中文摘要

海洋对人类社会文明和进步产生着重大影响，而如何利用表面工程技术提升海工装备关键部件多环境条件下的高效、持续减摩和耐磨性能以满足近海绿色可替代能源开发、远洋捕捞以及深海资源钻探需求是近年来摩擦学领域的热点问题之一。本文利用多靶共聚焦反应磁控溅射技术设计并制备出了一系列不同碳（C）含量的Ti–C–N自润滑复合薄膜材料，研究了其在空气、水以及海水环境下的摩擦磨损行为，揭示了各环境条件下因薄膜各相交互作用而产生的润滑、耐磨规律。主要研究结果表明，C的添加诱发非晶相（amorphous, a）的产生，导致薄膜两相共存，为面心立方（face-centered cubic, fcc）TiN+a-C。复合薄膜(<19.1at% C)中具有优异润滑性能的a-C相显著提升了其在空气和水环境下的摩擦磨损性能，但C含量的进一步升高降低了薄膜的力学性能，最终导致薄膜摩擦磨损性能有所降低。海水摩擦环境下，因a-C于fcc-TiN间产生微区原电池而使TiN相优先腐蚀，大量磨蚀产物黏附在磨痕表层，从而极大提升了薄膜的耐磨损性能。

关键词:

Research Article

Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts

+ Author Affiliations

1)
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
2)
CEMMPRE—Centre for Mechanical Engineering Materials and Processes, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
3)
CFAA, University of the Basque Country UPV/EHU, Bilbao 48170, Spain
4)
ISEP-School of Engineering, Polytechnic of Porto, Porto 4200-072, Portugal
5)
Key Laboratory of Materials Physic, Institute of Solid State Physics, Hefei Institute of Physical Sciences, Chinese Academy of Sciences, Hefei 230031, China
6)
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

Corresponding authors:
Hongbo Ju    E-mail: hbju@just.edu.cn

Junhua Xu    E-mail: jhxu@just.edu.cn

Junfeng Yang    E-mail: jfyang@issp.ac.cn
Received: 26 July 2022; Revised: 3 September 2022; Accepted: 14 September 2022; Available online: 16 September 2022

Abstract

Abstract

The need for reducing the wear in mechanical parts used in the industry makes self-lubricant films one of the sustainable solutions to achieve long-term protection under different environmental conditions. The purpose of this work is to study the influence of C additions on the tribological behavior of a magnetron-sputtered TiN film in air, water, and seawater. The results show that the addition of C into the TiN binary film induced a new amorphous phase, and the films exhibited a dual phase of fcc (face-centered cubic)-TiN and amorphous carbon. The antifriction and wear-resistance properties were enhanced in air and water by adding 19.1at% C. However, a further increase in the C concentration improved anti-frictional properties but also led to higher wear rates. Although the amorphous phase induced microbatteries and accelerated the corrosion of TiN phases in seawater, the negative abrasion state was detected for all Ti–C–N films due to the adhesion of the tribocorrosion debris on the wear track.
- RF reactive magnetron sputtering;
- Ti–C–N films;
- microstructure;
- tribological properties in air/water/seawater

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