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Volume 30 Issue 6
Jun.  2023

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Roghaye Samadianfard, Davod Seifzadeh,  and Burak Dikici, Application of g-C3N4/sol–gel nanocomposite on AM60B magnesium alloy and investigation of its properties, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1113-1127. https://doi.org/10.1007/s12613-022-2581-6
Cite this article as:
Roghaye Samadianfard, Davod Seifzadeh,  and Burak Dikici, Application of g-C3N4/sol–gel nanocomposite on AM60B magnesium alloy and investigation of its properties, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1113-1127. https://doi.org/10.1007/s12613-022-2581-6
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研究论文

g-C3N4/溶胶–凝胶纳米复合材料在AM60B镁合金上的应用及性能研究

  • 通讯作者:

    Davod Seifzadeh    E-mail: seifzadeh@uma.ac.ir

  • 含有羟基化g-C3N4纳米板的溶胶–凝胶涂层常被用来增强AM60B镁合金的抗腐蚀性能。通过X射线光电子能谱(XPS)分析了羟基化的g-C3N4纳米板的化学组成,发现羟基化过程对g-C3N4纳米板的晶体尺寸、比表面积、孔体积、平均孔径和热稳定性不产生影响。在加入原始和羟基化的g-C3N4纳米板后,获得了致密的溶胶–凝胶涂层。透射电子显微镜(TEM)表明改性的g-C3N4在涂层中均匀分布,并且加入改性纳米板后,由于聚集趋势降低,涂层的平均粗糙度也降低。进一步模拟酸雨中的电化学阻抗谱(EIS)检测表明,由于涂层与纳米板之间的化学键合,添加改性g-C3N4后,溶胶–凝胶膜的防腐性能得到显著改善。
  • Research Article

    Application of g-C3N4/sol–gel nanocomposite on AM60B magnesium alloy and investigation of its properties

    + Author Affiliations
    • To protect the AM60B magnesium alloy from corrosion, a sol–gel coating containing hydroxylated g-C3N4 nanoplates was applied. The chemical composition of the hydroxylated g-C3N4 nanoplates was investigated using X-ray photoelectron spectroscopy (XPS). The hydroxylation process did not affect the crystal size, specific surface area, pore volume, average pore diameter, and thermal stability of the g-C3N4 nanoplates. After incorporating pristine and hydroxylated g-C3N4 nanoplates, dense sol–gel coatings were obtained. Transmission electron microscopy (TEM) revealed the uniform distribution of the modified g-C3N4 in the coating. The average roughness of the coating was also reduced after adding the modified nanoplates due to the decreased aggregation tendency. Electrochemical impedance spectroscopy (EIS) examinations in simulated acid rain revealed a significant improvement in the anticorrosion properties of the sol–gel film after the addition of the modified g-C3N4 due to the chemical bonding of the coating to the nanoplates.
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